Skip to main content
SpringerLink
Log in

Structural, dielectric and vibrational studies of the new mixed solid solution of thallium potassium sulfate selenate tellurate

  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

The new mixed compound Tl1.89K0.11(SO4)0.9(SeO4)0.1Te(OH)6 which is crystallized in the monoclinic system with space group P21/c was analyzed at room temperature using X-ray diffractometer data. The unit cell parameters are a = 12.3308(7), b = 7.2011(4), c = 12.0298(8) Å, β = 110.755(4)°, V = 998.87(11) Å3 and Z = 4. The final refinement led to R = 0.035 and Rw = 0.038. The main feature of these atomic arrangements is the coexistence of three and different anions (SO4 2−, SeO4 2− and TeO6 6− groups) in the unit cell, connected by hydrogen bonds (O–H···O) which make the building of the crystal. The Tl+ and K+ cations, occupying the same positions, are located between these polyhedral. The crystals of Tl1.89K0.11(SO4)0.9(SeO4)0.1Te(OH)6 underwent three endothermic peaks at 377, 466 and 472 K. These transitions were detected by DSC and analyzed by dielectric measurements using the impedance and modulus spectroscopy techniques. The IR and Raman spectra recorded at room temperature in the frequency ranges (50–1200) and (400–4000) cm−1, respectively, have confirmed the presence of TeO6 6−, SO4 2− and SeO4 2− groups in the crystal.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  1. K. Jaoudi, N. Zouari, T. Mhiri, A. Daoud, M. Jannin, J. Alloy Compd. 413, 46–53 (2006)

    Article  Google Scholar 

  2. K. Jaoudi, N. Zouari, T. Mhiri, M. Giorgi, Phase Transit. 78, 627–638 (2005)

    Article  Google Scholar 

  3. H. Khemakhem, Ferroelectrics 234, 47–59 (1999)

    Article  Google Scholar 

  4. R. Zilber, A. Durif, M.T. Averbuch-Pouchot, Acta Crystallogr. B 36, 2743–2745 (1980)

    Article  Google Scholar 

  5. R. Zilber, A. Durif, M.T. Averbuch-Pouchot, Acta Crystallogr. B 37, 650–652 (1981)

    Article  Google Scholar 

  6. R. Zilber, A. Durif, M.T. Averbuch-Pouchot, Acta Crystallogr. B 38, 1554–1556 (1982)

    Article  Google Scholar 

  7. M. Dammak, H. Khemakhem, T. Mhiri, A.W. Kolsi, A. Daoud, J. Alloys Compd. 280, 107–113 (1998)

    Article  Google Scholar 

  8. M. Dammak, H. Khemakhem, T. Mhiri, J. Phys. Chem. Solids 62, 2069–2074 (2001)

    Article  ADS  Google Scholar 

  9. M. Abdelhedi, M. Dammak, A.W. Kolsi, A. Cousson, Anal. Sci. X-ray Struct. Anal. Online 24, 93–94 (2008)

    Article  Google Scholar 

  10. M. Abdelhedi, L. Ktari, M. Dammak, A. Cousson, A.W. Kolsi, Acta Crystallogr. E63, 153–154 (2007)

    Google Scholar 

  11. Nonius, in Kappa CCD Sever Software, ed. by B.V. Nonius (Delft, 1999)

  12. APEX2 version 1. 0–8, Bruker AXS (Madison, WI, 2003)

  13. D.J. Watkin, C.K. Prout, J.R. Carruthers, P.W. Betteridge, R.I. Cooper, Crystals Issue 11 (Chemical Crystallography Laboratory, Oxford, 2001)

    Google Scholar 

  14. K. Brandenburg, M. Berndt, DIAMOND Version 2.1.b, Crystal Impact, Gb R (Bonn, 1999)

  15. A. Novak, Hydrogen Bonding in Solids, vol. 18 (Springer, Berlin, 1974), pp. 177–216

    Google Scholar 

  16. J. Faby, J. Loub, L. Feltl, J. Therm. Anal. 24, 95–100 (1982)

    Article  Google Scholar 

  17. L. Ktari, M. Dammak, A.W. Kolsi, A. Cousson, J. Alloys Compd. 476, 54–59 (2009)

    Article  Google Scholar 

  18. H. Litaiem, M. Dammak, L. Ktari, S. Kammoun, T. Mhiri, Phase Transit. 77, 929–940 (2004)

    Article  Google Scholar 

  19. M. Djemel, M. Abdelhedi, L. Ktari, M. Dammak, J. Mol. Struct. 1047, 15–21 (2013)

    Article  ADS  Google Scholar 

  20. M. Abdelhedi, M. Dammak, A.W. Kolsi, J. Chem. Crystallogr. 45, 257–265 (2015)

    Article  Google Scholar 

  21. M. Dammak, H. Khemakhem, N. Zouari, A.W. Kolsi, T. Mhiri, J. Solid State Ion. 127, 125–132 (2000)

    Article  Google Scholar 

  22. A. Orilukas, A. Dindune, Z. Kanepe, J. Ronis, E. Kazakevicius, A. Kezionis, Solid State Ion. 157, 177–181 (2003)

    Article  Google Scholar 

  23. H. Kchaou, A.B. Rhaiem, K. Karoui, F. Jomni, K. Guidara, Appl. Phys. A 122, 82–89 (2016)

    Article  ADS  Google Scholar 

  24. N. Chabchoub, H. Khemakhem, M. Gargouri, J. Alloys Compd. 359, 84–90 (2003)

    Article  Google Scholar 

  25. S.G. Gauthier, J.C. Peuzin, M. Olivier, G. Rolland, Ferroelectrics 52, 293–306 (1984)

    Article  Google Scholar 

  26. H. Khemakhem, J. Ravez, A. Daoud, Ferroelectrics 188, 41–51 (1996)

    Article  Google Scholar 

  27. H. Khemakhem, R. Von der Muhll, J. Ravez, A. Daoud, Ferroelectrics 188, 85–93 (1996)

    Article  Google Scholar 

  28. M. Djemel, M. Abdelhedi, N. Zouari, M. Dammak, A.W. Kolsi, J. Solid State Chem. 196, 267–273 (2012)

    Article  ADS  Google Scholar 

  29. M. Dammak, H. Khemakhem, T. Mhiri, A.W. Kolsi, A. Daoud, J. Solid State Chem. 145, 612–618 (1999)

    Article  ADS  Google Scholar 

  30. M. Dammak, H. Litaiem, P. Gravereau, T. Mhiri, A.W. Kolsi, J. Alloys Compd. 442, 316–319 (2007)

    Article  Google Scholar 

  31. N. Zouari, M.B. Amor, T. Mhiri, A. Daoud, J.M. Réau, J. Alloys Compd. 240, 70–75 (1996)

    Article  Google Scholar 

  32. D.C. Sinclair, A.R. West, J. Appl. Phys. 66, 3850–3856 (1989)

    Article  ADS  Google Scholar 

  33. I.M. Hodge, M.D. Ingram, Q.A.R. West, J. Electroanal. Chem. Interfacial Electrochem. 74, 125–143 (1976)

    Article  Google Scholar 

  34. S. Sen, P. Pramanik, R.N.P. Choudhary, Appl. Phys. A Mater. Sci. Process. 82, 549–557 (2006)

    Article  ADS  Google Scholar 

  35. J.M. Reau, A. Simon, M. El Omari, J. Ravez, J. Eur. Ceram. Soc. 19, 777–779 (1999)

    Article  Google Scholar 

  36. F.S. Howell, R.A. Bose, P.B. Macedo, C.T. Moynihan, J. Phys. Chem. 78, 639–648 (1974)

    Article  Google Scholar 

  37. S.W. Martin, Appl. Phys. A 49, 239–247 (1989)

    Article  ADS  Google Scholar 

  38. H.K. Palet, S.W. Martin, Phys. Rev. B 45, 10292–10300 (1992)

    Article  ADS  Google Scholar 

  39. L. Ktari, M. Dammak, A. Hadrich, A. Cousson, M. Nierlich, F. Romain, T. Mhiri, J. Solid State Sci. 6, 1393–1401 (2004)

    Article  ADS  Google Scholar 

  40. R. Allman, W. Hasse, Inorg. Chem. 15, 804–807 (1976)

    Article  Google Scholar 

  41. G. Blasse, W. Hordijk, J. Solid State Chem. 15, 395–409 (1972)

    Article  ADS  Google Scholar 

  42. M. Gargouri, T. Mhiri, A. Daoud, J.M. Reau, Solid State Ion. 125, 193–202 (1999)

    Article  Google Scholar 

  43. K. Viswanathan, V.U. Nayar, G. Aruldhas, Infrared Phys. 26, 89–91 (1986)

    Article  ADS  Google Scholar 

  44. G. Sekar, K. Viswanathan, G. Aruldhas, Infrared Phys. 27, 253–256 (1987)

    Article  ADS  Google Scholar 

  45. G. Sekar, G. Aruldhas, Infrared Phys. 27, 371–374 (1987)

    Article  ADS  Google Scholar 

  46. K. Viswanathan, V.U. Nayar, G. Aruldhas, V. Ramakrishnan, J. Solid State Chem. 77, 394–400 (1988)

    Article  ADS  Google Scholar 

  47. M. Dammak, A. Hadrich, T. Mhiri, J. Alloys Compd. 428, 8–16 (2007)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratory of Inorganic Chemistry, UR 11ES73, University of Sfax, B. P. 1171, 3000, Sfax, Tunisia

    A. Elferjani, M. Abdelhedi, M. Dammak & A. W. Kolsi

Authors
  1. A. Elferjani
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Abdelhedi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Dammak
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. W. Kolsi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. Elferjani.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Elferjani, A., Abdelhedi, M., Dammak, M. et al. Structural, dielectric and vibrational studies of the new mixed solid solution of thallium potassium sulfate selenate tellurate. Appl. Phys. A 122, 742 (2016). https://doi.org/10.1007/s00339-016-0266-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s00339-016-0266-6

Keywords

Search

Navigation