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Comparison of modification of electronic properties of single-walled carbon nanotubes filled with metal halogenide, chalcogenide, and pure metal

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Abstract

In present work, thulium chloride, gallium selenide, bismuth telluride, and silver were encapsulated into the channels of single-walled carbon nanotubes (SWCNTs). The structural properties of obtained nanostructures were studied by high-resolution transmission electron microscopy, and the modification of electronic properties of nanotubes as result of filling their channels with chosen substances was investigated by Raman spectroscopy and X-ray photoelectron spectroscopy. It was shown that the electronic properties of filled SWCNTs depend on the chemical nature of incorporated materials. The encapsulation of TmCl3 and GaSe into the carbon nanotube channels leads to acceptor doping of the SWCNTs, and this effect is more prominent for thulium chloride. The incorporation of bismuth telluride into the nanotube cavities does not result in any modification of their electronic properties. The filling of the nanotube channels with silver leads to donor doping of the single-walled carbon nanotubes.

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References

  1. S. Iijima, Nature 354, 56 (1991)

    Article  ADS  Google Scholar 

  2. T.W. Odom, J.L. Huang, P. Kim, C.M. Lieber, Nature 391, 62 (1998)

    Article  ADS  Google Scholar 

  3. R.R. He, H.Z. Jin, J. Zhu, Y.J. Yan, X.H. Chen, Chem. Phys. Lett. 298, 170 (1998)

    Article  ADS  Google Scholar 

  4. P. Chen, X. Wu, X. Sun, J. Lin, W. Ji, K.L. Tan, Phys. Rev. Lett. 82, 2548 (1999)

    Article  ADS  Google Scholar 

  5. M.M.J. Treacy, T.W. Ebbesen, J.M. Gibson, Nature 381, 678 (1996)

    Article  ADS  Google Scholar 

  6. A.A. Eliseev, M.V. Kharlamova, M.V. Chernysheva, A.V. Lukashin, Yu.D. Tretyakov, A.S. Kumskov, N.A. Kiselev, Russ. Chem. Rev. 78, 833 (2009)

    Article  ADS  Google Scholar 

  7. A.A. Eliseev, L.V. Yashina, M.M. Brzhezinskaya, M.V. Chernysheva, M.V. Kharlamova, N.I. Verbitsky, A.V. Lukashin, N.A. Kiselev, A.S. Kumskov, R.M. Zakalyuhin, J.L. Hutchison, B. Freitag, A.S. Vinogradov, Carbon 48, 2708 (2010)

    Article  Google Scholar 

  8. A.A. Eliseev, L.V. Yashina, N.I. Verbitskiy, M.M. Brzhezinskaya, M.V. Kharlamova, M.V. Chernysheva, A.V. Lukashin, N.A. Kiselev, A.S. Kumskov, B. Freitag, A.V. Generalov, A.S. Vinogradov, Y.V. Zubavichus, E. Kleimenov, M. Nachtegaal, Carbon 50, 4021 (2012)

    Article  Google Scholar 

  9. M. Monthioux, E. Flahaut, J.P. Cleuziou, J. Mater. Res. 21, 2774 (2006)

    Article  ADS  Google Scholar 

  10. J. Sloan, J. Hammer, M. Zwiefka-Sibley, M.L.H. Green, Chem. Commun. 3, 347 (1998)

    Article  Google Scholar 

  11. A. Govindaraj, B.C. Satishkumar, M. Nath, C.N.R. Rao, Chem. Mater. 12, 202 (2000)

    Article  Google Scholar 

  12. P. Corio, A.P. Santos, P.S. Santos, M.L.A. Temperini, V.W. Brar, M.A. Pimenta, M.S. Dresselhaus, Chem. Phys. Lett. 383, 475 (2004)

    Article  ADS  Google Scholar 

  13. M.V. Kharlamova, J.J. Niu, JETP 115, 485 (2012)

    Article  ADS  Google Scholar 

  14. T.W. Chamberlain, T. Zoberbier, J. Biskupek, A. Botos, U. Kaiser, A.N. Khlobystov, Chem. Sci. 3, 1919 (2012)

    Article  Google Scholar 

  15. P.M.F.J. Costa, J. Sloan, T. Rutherford, M.L.H. Green, Chem. Mater. 17, 6579 (2005)

    Article  Google Scholar 

  16. M.V. Kharlamova, J.J. Niu, Appl. Phys. A 109, 25 (2012)

    Article  ADS  Google Scholar 

  17. T. Zoberbier, T.W. Chamberlain, J. Biskupek, N. Kuganathan, S. Eyhusen, E. Bichoutskaia, U. Kaiser, A.N. Khlobystov, J. Am. Chem. Soc. 134, 3073 (2012)

    Article  Google Scholar 

  18. M.V. Kharlamova, J.J. Niu, JETP Lett. 95, 314 (2012)

    Article  ADS  Google Scholar 

  19. R. Kitaura, R. Nakanishi, T. Saito, H. Yoshikawa, K. Awaga, H. Shinohara, Angew. Chem., Int. Ed. 48, 8298 (2009)

    Article  Google Scholar 

  20. J. Sloan, A.I. Kirkland, J.L. Hutchison, M.L.H. Green, Chem. Commun. 13, 1319 (2002)

    Article  Google Scholar 

  21. M.V. Kharlamova, L.V. Yashina, A.A. Volykhov, J.J. Niu, V.S. Neudachina, M.M. Brzhezinskaya, T.S. Zyubina, A.I. Belogorokhov, A.A. Eliseev, Eur. Phys. J. B 85, 34 (2012)

    Article  ADS  Google Scholar 

  22. J. Sloan, S. Friedrichs, R.R. Meyer, A.I. Kirkland, J.L. Hutchison, M.L.H. Green, Inorg. Chim. Acta 330, 1 (2002)

    Article  Google Scholar 

  23. M.V. Kharlamova, A.A. Eliseev, L.V. Yashina, D.I. Petukhov, C.-P. Liu, C.-Y. Wang, D.A. Semenenko, A.I. Belogorokhov, JETP Lett. 91, 196 (2010)

    Article  ADS  Google Scholar 

  24. J. Sloan, A.I. Kirkland, J.L. Hutchison, M.L.H. Green, C. R. Phys. 4, 1063 (2003)

    Article  ADS  Google Scholar 

  25. M.V. Kharlamova, L.V. Yashina, A.A. Eliseev, A.A. Volykhov, V.S. Neudachina, M.M. Brzhezinskaya, T.S. Zyubina, A.V. Lukashin, Yu.D. Tretyakov, Phys. Status Solidi B 249, 2328 (2012)

    Article  ADS  Google Scholar 

  26. E. Philp, J. Sloan, A.I. Kirkland, R.R. Meyer, S. Friedrichs, J.L. Hutchison, M.L.H. Green, Nat. Mater. 2, 788 (2003)

    Article  ADS  Google Scholar 

  27. M.V. Kharlamova, Appl. Phys. A 111, 725 (2013)

    Article  ADS  Google Scholar 

  28. Z.Y. Wang, H. Li, Z. Liu, Z.J. Shi, J. Lu, K. Suenaga, S.K. Joung, T. Okazaki, Z.N. Gu, J. Zhou, Z.X. Gao, G.P. Li, S. Sanvito, E.G. Wang, S. Iijima, J. Am. Chem. Soc. 132, 13840 (2010)

    Article  Google Scholar 

  29. R. Carter, J. Sloan, A.I. Kirkland, R.R. Meyer, P.J.D. Lindan, G. Lin, M.L.H. Green, A. Vlandas, J.L. Hutchison, J. Harding, Phys. Rev. Lett. 96, 215501 (2006)

    Article  ADS  Google Scholar 

  30. L.V. Yashina, A.A. Eliseev, M.V. Kharlamova, A.A. Volykhov, A.V. Egorov, S.V. Savilov, A.V. Lukashin, R. Püttner, A.I. Belogorokhov, J. Phys. Chem. C 115, 3578 (2011)

    Article  Google Scholar 

  31. B.W. Smith, M. Monthioux, D.E. Luzzi, Nature 396, 323 (1998)

    Article  ADS  Google Scholar 

  32. A.N. Khlobystov, D.A. Britz, G.A.D. Briggs, Acc. Chem. Res. 38, 901 (2005)

    Article  Google Scholar 

  33. A.N. Khlobystov, ACS Nano 5, 9306 (2011)

    Article  Google Scholar 

  34. H. Shiozawa, T. Pichler, A. Gruneis, R. Pfeiffer, H. Kuzmany, Z. Liu, K. Suenaga, H. Kataura, Adv. Mater. 20, 1443 (2008)

    Article  Google Scholar 

  35. H. Shiozawa, C. Kramberger, R. Pfeiffer, H. Kuzmany, T. Pichler, Z. Liu, K. Suenaga, H. Kataura, S.R.P. Silva, Adv. Mater. 22, 3685 (2010)

    Article  Google Scholar 

  36. T. Takenobu, T. Takano, M. Shiraishi, Y. Murakami, M. Ata, H. Kataura, Y. Achiba, Y. Iwasa, Nat. Mater. 2, 683 (2003)

    Article  ADS  Google Scholar 

  37. M. Hulman, H. Kuzmany, P.M.F.J. Costa, S. Friedrichs, M.L.H. Green, Appl. Phys. Lett. 85, 2068 (2004)

    Article  ADS  Google Scholar 

  38. N. Thamavaranukup, H.A. Hoppe, L. Ruiz-Gonzalez, P.M.F.J. Costa, J. Sloan, A. Kirkland, M.L.H. Green, Chem. Commun. 15, 1686 (2004)

    Article  Google Scholar 

  39. S. Friedrichs, R.R. Meyer, J. Sloan, A.I. Kirkland, J.L. Hutchison, M.L.H. Green, Chem. Commun. 10, 929 (2001)

    Article  Google Scholar 

  40. M. Monthioux, Carbon 40, 1809 (2002)

    Article  Google Scholar 

  41. A.V. Krestinin, M.B. Kislov, A.G. Ryabenko, in NATO Science series, II. Mathematics, Physics and Chemistry, vol. 169, ed. by S. Gucery, Y.G. Gogotsi, V. Kuznetsov (Kluwer Academic, Dordrecht, 2004), p. 107

    Google Scholar 

  42. A.V. Krestinin, N.A. Kiselev, A.V. Raevskii, A.G. Ryabenko, D.N. Zakharov, G.I. Zvereva, Eurasian Chem. Technol. J. 5, 7 (2003)

    Google Scholar 

  43. A. Eliseev, L. Yashina, M. Kharlamova, N. Kiselev, in Electronic Properties of Carbon Nanotubes, ed. by J.M. Marulanda (InTech, Rijeka, 2011), p. 127

    Google Scholar 

  44. H. Kataura, Y. Kumazawa, Y. Maniwa, I. Umezu, S. Suzuki, Y. Ohtsuka, Y. Achiba, Synth. Met. 103, 2555 (1999)

    Article  Google Scholar 

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Acknowledgements

SWCNTs were synthesized by Dr. A.V. Krestinin (Institute of Problems of Chemical Physics RAS, Chernogolovka, Russia). M.V. Kharlamova thanks Dr. J.J. Niu (Drexel University, USA) and Dr. A. Egorov (Lomonosov Moscow State University, Russia) for the HRTEM measurements.

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Authors and Affiliations

  1. Department of Materials Science, Moscow State University, Leninskie gory 1-3, 119991, Moscow, Russia

    M. V. Kharlamova & A. V. Lukashin

  2. Department of Chemistry, Moscow State University, Leninskie gory 1/3, 119991, Moscow, Russia

    L. V. Yashina

  3. Rare Metals Institute “GIREDMET”, B. Tolmachevsky lane 5, 119017, Moscow, Russia

    L. V. Yashina

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  1. M. V. Kharlamova
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  2. L. V. Yashina
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  3. A. V. Lukashin
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Correspondence to M. V. Kharlamova.

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Kharlamova, M.V., Yashina, L.V. & Lukashin, A.V. Comparison of modification of electronic properties of single-walled carbon nanotubes filled with metal halogenide, chalcogenide, and pure metal. Appl. Phys. A 112, 297–304 (2013). https://doi.org/10.1007/s00339-013-7808-y

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