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Electrodeposition fabrication of Co-based superhydrophobic powder coatings in non-aqueous electrolyte

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Abstract

A rapid, facile, one-step process was developed to fabricate Co-based superhydrophobic powder coatings on the stainless steel surfaces with a nonaqueous electrolyte by the electrodeposition method. The structure and composition of the superhydrophobic surfaces were characterized by means of scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and contact angle measurement. The results show that the special hierarchical structures along with the low surface energy lead to the high superhydrophobicity of the substrate surface. The shortest process of constructing the superhydrophobic surface is only 30 seconds, the high contact angle is greater than 160°, and the rolling angle is less than 2°. The method can be used to fabricate the superhydrophobic powder coatings at any conductive cathodic surface, and the as-prepared superhydrophobic powder coatings have advantages of transferability, repairability, and durability. It is expected that this facile method will accelerate the large-scale production of superhydrophobic material.

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References

  1. W. Barthlott, C. Neinhuis, Planta 202, 1 (1997)

    Article  Google Scholar 

  2. C.R. Crick, I.P. Parkin, Chem. Eur. J. 16, 3568 (2010)

    Article  Google Scholar 

  3. Z.G. Guo, W.M. Liu, B.L. Su, J. Colloid Interface Sci. 353, 335 (2011)

    Article  Google Scholar 

  4. N. Saleema, D.K. Sarkar, R.W. Paynter, X.G. Chen, ACS Appl. Mater. Interfaces 2, 2500 (2010)

    Article  Google Scholar 

  5. M.L. Zhang, K.Q. Peng, X. Fan, J.S. Jie, R.Q. Zhang, S.T. Lee, N.B. Wong, J. Phys. Chem. C 112, 4444 (2008)

    Article  Google Scholar 

  6. H. Budunoglu, A. Yildirim, M.O. Guler, M. Bayindir, ACS Appl. Mater. Interfaces 3, 539 (2011)

    Article  Google Scholar 

  7. T. Ishizaki, J. Hieda, N. Saito, N. Saito, O. Takai, Electrochim. Acta 55, 7094 (2010)

    Article  Google Scholar 

  8. J. Bekesi, J.J.J. Kaakkunen, W. Michaeli, F. Klaiber, M. Schoengart, J. Ihlemann, P. Simon, Appl. Phys. A 99, 691 (2010)

    Article  ADS  Google Scholar 

  9. S.H. He, M.J. Zheng, L.J. Yao, X.L. Yuan, M. Li, L. Ma, W.Z. Shen, Appl. Surf. Sci. 256, 2557 (2010)

    Article  ADS  Google Scholar 

  10. W.C. Wu, X.L. Wang, X.J. Liu, F. Zhou, ACS Appl. Mater. Interfaces 1, 1656 (2009)

    Article  Google Scholar 

  11. W. Simka, D. Puszczyk, G. Nawrat, Electrochim. Acta 54, 5307 (2009)

    Article  Google Scholar 

  12. N.K. Allam, C.A. Grimes, Mater. Lett. 65, 1949 (2011)

    Article  Google Scholar 

  13. X.P. Sun, Y.L. Luo, F. Liao, W.B. Lu, G.H. Chang, Electrochim. Acta 56, 2832 (2011)

    Article  Google Scholar 

  14. R. Qiu, P. Wang, D. Zhang, J.J. Wu, Colloids Surf. A 377, 144 (2011)

    Article  Google Scholar 

  15. J.M. Xi, L. Feng, L. Jiang, Appl. Phys. Lett. 92, 053102 (2008)

    Article  ADS  Google Scholar 

  16. Z. Chen, L.M. Hao, A.Q. Chen, Q.J. Song, C.L. Chen, A rapid one-step process for fabrication of superhydrophobic surface by electrodeposition method. Electrochim. Acta 59, 168 (2012)

    Article  Google Scholar 

  17. A.B.D. Cassie, S. Baxter, Trans. Faraday Soc. 40, 546 (1944)

    Article  Google Scholar 

  18. Z.G. Guo, W.M. Liu, Plant Sci. 172, 1103 (2007)

    Article  Google Scholar 

  19. S.Y. Gao, Z.D. Li, S.X. Yang, K. Jiang, Y. Li, H.B. Zeng, L. Li, H.Q. Wang, Transferrable superhydrophobic surface constructed by a hexagonal CuI powder without modification by low-free-energy materials. ACS Appl. Mater. Interfaces 1, 2080 (2009)

    Article  Google Scholar 

  20. G.T. Gu, Y.P. Tian, Z.T. Li, D.F. Lu, Electrostatic powder spraying process for the fabrication of stable superhydrophobic surfaces. Appl. Surf. Sci. 257, 4586 (2011)

    Article  ADS  Google Scholar 

  21. I.A. Larmour, G.C. Saunders, S.E.J. Bell, Compressed metal powders that remain superhydrophobic after abrasion. ACS Appl. Mater. Interfaces 1, 2703 (2010)

    Article  Google Scholar 

  22. T. Liu, S.G. Chen, S. Cheng, J.T. Tian, X.T. Chang, Y.S. Yin, Electrochim. Acta 52, 8003 (2007)

    Article  Google Scholar 

  23. J. Yang, Z.Z. Zhang, X.H. Men, X.H. Xu, X.T. Zhu, Colloids Surf., A, Physicochem. Eng. Asp. 367, 60 (2010)

    Article  Google Scholar 

  24. J.P. Zhang, S. Seeger, Angew. Chem., Int. Ed. Engl. 50, 1 (2011)

    Article  MATH  Google Scholar 

  25. R. Jafari, M. Farzaneh, Appl. Phys. A 102, 195 (2011)

    Article  ADS  Google Scholar 

  26. P.R. Chiarot, T.B. Jones, Exp. Fluids 49, 1109 (2010)

    Article  Google Scholar 

  27. L. Boinovich, A.M. Emelyanenko, A.S. Pashinin, ACS Appl. Mater. Interfaces 2, 1754 (2010)

    Article  Google Scholar 

  28. T. Ishizaki, Y. Masuda, M. Sakamoto, Langmuir 27, 4780 (2011)

    Article  Google Scholar 

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No.11102164), the Fundamental Research Fund of Northwestern Polytechnical University, China (Nos. JC201267, JC200919), and the Scientific Research Program Funded by Shaanxi Provincial Education Department (No. 12JK0966).

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Correspondence to Zhi Chen.

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Chen, Z., Hao, L., Duan, M. et al. Electrodeposition fabrication of Co-based superhydrophobic powder coatings in non-aqueous electrolyte. Appl. Phys. A 111, 581–585 (2013). https://doi.org/10.1007/s00339-012-7263-1

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  • DOI: https://doi.org/10.1007/s00339-012-7263-1

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