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Non-invasive characterization of manufacturing techniques and corrosion of ancient Chinese bronzes and a later replica using synchrotron X-ray diffraction

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Abstract

Three bronze vessels from the ancient Chinese art collection at the Art Institute of Chicago (AIC) were examined—with the advanced non-invasive characterization capabilities of high-energy synchrotron X-ray diffraction performed at the Advanced Photon Source (APS) of Argonne National Laboratory (ANL)—to create a comprehensive overview of each object’s manufacture as well as subsequent corrosion processes. Findings were also complemented with traditional non-invasive characterization techniques, including optical imaging, X-ray radiographic imaging, and X-ray fluorescence (XRF) spectrometry. The results—obtained without sampling—allow a clear distinction between genuinely ancient Chinese bronzes from those with modern restorations and from “archaistic” objects made many centuries later, in emulation of ancient styles.

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References

  1. L. Robbiola, R. Portier, J. Cult. Her. 7, 1 (2006)

    Article  Google Scholar 

  2. D.A. Scott, L.S. Dodd, J. Cult. Her. 3, 333 (2002)

    Article  Google Scholar 

  3. A. Giumlia-Mair, Nucl. Instrum. Methods Phys. Res. B 239, 35 (2005)

    Article  ADS  Google Scholar 

  4. E. Pantos, W. Kockelmann, L.C. Chapon, L. Lutterotti, S.L. Bennet, M.J. Tobin, J.F.W. Mosselmans, T. Pradell, N. Salvado, S. Buti, R. Garner, A.J.N.W. Prag, Nucl. Instrum. Methods Phys. Res. B 239, 16 (2005)

    Article  ADS  Google Scholar 

  5. I. Constantinides, M. Gritsch, A. Adriaens, H. Hutter, F. Adams, Anal. Chim. Acta 440, 189 (2001)

    Article  Google Scholar 

  6. G. Harbottle, B.M. Gordon, K.W. Jones, Nucl. Instrum. Methods Phys. Res. B 14, 116 (1986)

    Article  ADS  Google Scholar 

  7. M.F. Araujo, T. Pinheiro, P. Valerio, A. Barreiros, A. Simionovici, S. Bohic, A. Melo, J. Phys. IV 104, 523 (2003)

    Google Scholar 

  8. A. De Ryck, A. Adriaens, E. Pantos, F. Adams, Analyst 128, 1104 (2003)

    Article  ADS  Google Scholar 

  9. D. Grolimund, M. Senn, M. Trottmann, M. Janousch, I. Bonhoure, A.M. Scheidegger, M. Marcus, Spectrochim Acta B 59, 1627 (2004)

    Article  ADS  Google Scholar 

  10. K. Janssens, G. Vittiglio, I. Deraedt, A. Aerts, B. Vekemans, L. Vincze, F. Wei, I. Deryck, O. Schalm, F. Adams, A. Rindby, A. Knochel, A. Simionovici, A. Snigirev, X-Ray Spectrom. 29, 73 (2000)

    Article  Google Scholar 

  11. B. Newbury, B. Stephenson, J.D. Almer, M. Notis, G.S. Cargill, G.B. Stephenson, D.R. Haeffner, Powder Diffr. 19, 1 (2004)

    Article  Google Scholar 

  12. M. Schreiner, B. Fruhmann, D. Jembrih-Simburger, R. Linke, Powder Diffr. 19, 3 (2003)

    Article  Google Scholar 

  13. G.B. Stephenson, B. Stephenson, D.R. Haeffner, MRS Bull. 26, 19 (2001)

    Google Scholar 

  14. E.S. Friedman, A.J. Brody, M.L. Young, J.D. Almer, C.U. Segre, S.M. Mini, J. Archaeol. Sci. 35, 1951 (2008)

    Article  Google Scholar 

  15. M.L. Young, F. Casadio, S. Schnepp, J.D. Almer, D.R. Haeffner, D.C. Dunand, Appl. Phys. A, Mater. 83, 163 (2006)

    Article  ADS  Google Scholar 

  16. B. Kanngießer, W. Malzer, I. Reiche, Nucl. Instrum. Methods Phys. Res. B 211, 259 (2003)

    Article  ADS  Google Scholar 

  17. B.D. Newbury, M.R. Notis, B. Stephenson, G.S. Cargill, G.B. Stephenson, Ann. Sci. 63, 201 (2006)

    Article  Google Scholar 

  18. W.T. Chase, Chinese Bronzes: Casting, Finishing, Patination, and Corrosion (Oxford University Press, Los Angeles, 1994)

    Google Scholar 

  19. S. Hargrove, Technical Observations and Analyses of Chinese Bronzes (St Louis Art Museum, St Louis, 1997)

    Google Scholar 

  20. D.A. Scott, Copper and Bronze in Art: Corrosion, Colorants, and Conservation (Getty, Los Angeles, 2002)

    Google Scholar 

  21. L. Robbiola, J.-M. Blengino, C. Fiaud, Corros. Sci. 40, 2083 (1998)

    Article  Google Scholar 

  22. K.M. Linduff, H. Rubin, S. Shuyun, The Beginnings of Metallurgy in China (Chinese Studies) (Edwin Mellen Press, Lewiston, 2000)

    Google Scholar 

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Correspondence to F. Casadio.

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Young, M.L., Casadio, F., Schnepp, S. et al. Non-invasive characterization of manufacturing techniques and corrosion of ancient Chinese bronzes and a later replica using synchrotron X-ray diffraction. Appl. Phys. A 100, 635–646 (2010). https://doi.org/10.1007/s00339-010-5646-8

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  • DOI: https://doi.org/10.1007/s00339-010-5646-8

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