Abstract
A spectroscopic study of ambient air plasma, initially at room temperature and pressures ranging from 32 to 101 kPa, produced by high-power transverse excitation atmospheric (TEA) CO2 laser (λ=9.621 and 10.591 μm; τ FWHM≈64 ns; power densities ranging from 0.29 to 6.31 GW cm−2) has been carried out in an attempt to clarify the processes involved in laser-induced breakdown (LIB) air plasma. The strong emission observed in the plasma region is mainly due to electronic relaxation of excited N, O and ionic fragments N+. The medium-weak emission is due to excited species O+, N2+, O2+, C, C+, C2+, H, Ar and molecular band systems of N \(_{2}^{+}(\) B \(^{2}\varSigma _{\mathrm{u}}^{+}\) –X \(^{2}\varSigma _{\mathrm{g}}^{+})\) , N2(C3 Π u–B3 Π g), N \(_{2}^{+}(\) D2 Π g–A2 Π u) and OH(A2 Σ +–X2 Π). Excitation temperatures of 23400±700 K and 26600±1400 K were estimated by means of N+ and O+ ionic lines, respectively. Electron number densities of the order of (0.5–2.4)×1017 cm−3 and (0.6–7.5)×1017 cm−3 were deduced from the Stark broadening of several ionic N+ and O+ lines, respectively. Estimates of vibrational and rotational temperatures of N \(_{2}^{+}\) electronically excited species are reported. The characteristics of the spectral emission intensities from different species have been investigated as functions of the air pressure and laser irradiance. Optical breakdown threshold intensities in air at 10.591 μm have been measured.
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J.S. Rigden, in Macmillan Encyclopedia of Physics (Simon & Schuster, New York, 1996), p. 353
P.D. Maker, R.W. Terhune, C.M. Savage, in Proc. 3rd Int. Conf. Quantum Electronics, vol. 2 (Dunod, Paris, 1963), p. 1559
Y.B. Zeldovich, Y.P. Raiser, Sov. Phys. JETP 21, 190 (1965)
H.B. Bebb, A. Gold, in Multiphoton Ionization of Hydrogen and Rare Gas Atoms, Physics of Quantum Electronics, ed. by P.L. Kelly et al. (McGraw-Hill, New York, 1966)
C. De Michelis, IEEE J. Quantum Electron. 5, 18 (1969)
N.R. Isenor, M.C. Richardson, Appl. Phys. Lett. 18, 224 (1971)
J.L. Lyman, R.J. Jensen, Chem. Phys. Lett. 13, 421 (1972)
C.G. Morgan, Rep. Prog. Phys. 38, 621 (1975)
D.I. Rosen, G. Weyl, J. Phys. D, Appl. Phys. 20, 1264 (1987)
J.L. Lyman, G.P. Quigley, O.P. Judo, in Multiple-Photon Excitation and Dissociation of Polyatomic Molecules, ed. by C.D. Cantrell (Springer, Berlin, 1980)
Y.E.E.-D. Gamal, J. Phys D, Appl. Phys. 21, 1117 (1988)
G. Bekefi G, Principles of Laser Plasma (Wiley, New York, 1976)
L.J. Radziemski, D. Cremers, Laser Induced Plasma and Applications (Dekker, New York, 1989)
F.-Y. Yueh, J.P. Singh, H. Zhang, in Encyclopedia of Analytical Chemistry (Laser-Induced Breakdown Spectroscopy, Elemental Analysis), ed. by R.A. Meyers (Wiley, Chichester, 2000)
D.A. Cremers, L.J. Radziemski, Handbook of Laser-Induced Breakdown Spectroscopy (Wiley, Chichester, 2006)
A.W. Miziolek, V. Palleschi, I. Schechter, Laser-Induced Breakdown Spectroscopy (Cambridge University Press, Cambridge, 2006)
C. Pasquini, J. Cortez, L.M.C. Silva, F.B. Gonzaga, J. Braz. Chem. Soc. 18, 463 (2007)
J.P. Singh, S.N. Thakur, Laser-Induced Breakdown Spectroscopy (Elsevier, New York, 2007)
J. Kasparian, J.M. Rodríguez, G. Menean, J. Yu, E. Salmon, H. Wille, R. Bourayou, S. Frey, Y.B. Andre, A. Mysyrowicz, R. Sauerbrey, J.P. Wolf, L. Woste, Science 301, 61 (2003)
R.G. Meyerand Jr., A.F. Haught, Phys. Rev. Lett. 11, 401 (1963)
B. Fontaine, F. Vidal, D. Comtois, C.Y. Chien, A. Desparois, T.W. Johnston, J.C. Kieffer, H.P. Mercure, H. Pepin, F.A.M. Rizk, IEEE Trans. Plasma Sci. 27, 688 (1999)
F. Vidal, D. Comtois, C.Y. Chien, A. Desparois, B. Fontaine, T.W. Johnston, J.C. Kieffer, H.P. Mercure, H. Pepin, F.A. Rizk, IEEE Trans. Plasma Sci. 28, 418 (2000)
H. Sobral, M. Villagran-Muniz, R. Navarro-González, A. Raga, Appl. Phys. Lett. 77, 3158 (2000)
A.C. Raga, R. Navarro-González, M. Villagran-Muniz, Rev. Mex. Astr. Astrof. 36, 67 (2000) (English translation available from the NASA Astrophysics Data System website)
P. Montgolfier, P. Dumont, Y. Mille, J. Villermaux, J. Phys. Chem. 76, 31 (1972)
R.J. Nordstrom, Appl. Spectrosc. 49, 1490 (1995)
S. Yalcin, D.R. Crosley, G.P. Smith, G.W. Faris, Appl. Phys. B, Lasers Opt. 68, 121 (1999)
M.Z. Martin, M.D. Cheng, R.C. Martin, Aerosol Sci. Technol. 31, 409 (1999)
F. Martin, F. Mawassi, I. Vidal, D. Gallimberti, H. Comtois, H. Pepin, J.C. Kieffer, H.P. Mercure, Appl. Spectrosc. 56, 1444 (2002)
T.X. Phuoc, Opt. Commun. 175, 419 (2000)
N. Kawahara, J.L. Beduneu, T. Nakayama, E. Tomita, Y. Ikeda, Appl. Phys. B 86, 605 (2007)
Y.L. Chen, J.W.L. Lewis, C. Parigger, J. Quantum Spectrosc. Rad. Trans. 67, 91 (2000)
M. Milan, J.J. Laserna, Spectrochim. Acta B 56, 275 (2000)
J. Beduneau, Y. Ikeda, J. Quantum Spectrosc. Rad. Trans. 84, 123 (2003)
A.J. Alcock, K. Kato, M.C. Richardson, Opt. Commun. 6, 342 (1968)
A.F. Haught, R.G. Meyerand, D.C. Smith, in Physics of Quantum Electronics, ed. by P.L. Kelley, B. Lax, P.E. Tannenwald (McGraw-Hill, New York, 1966), p. 509
C. De Michelis, Opt. Commun. 2, 255 (1970)
C.L.M. Ireland, J. Phys. D, Appl. Phys. 7, L179 (1974)
C.L.M. Ireland, C.G. Morgan, J. Phys. D, Appl. Phys. 6, 720 (1973)
C.L.M. Ireland, C.G. Morgan, J. Phys. D, Appl. Phys. 7, L87 (1974)
C.M.L. Ireland, A. Yi, J.M. Aaron, C.G. Morgan, Appl. Phys. Lett. 24, 175 (1974)
J.M. Aaron, C.L.M. Ireland, C.G. Morgan, J. Phys. D, Appl. Phys. 7, 1907 (1974)
T.X. Phuoc, C.M. White, Opt. Commun. 175, 419 (2000)
R.G. Tomlinson, Phys. Rev. Lett. 14, 489 (1965)
R.G. Tomlinson, E.K. Damon, H.T. Buscher, in Physics of Quantum Electronics, ed. by P.L. Kelley, B. Lax, P.E. Tannenwald (McGraw-Hill, New York, 1966), p. 520
W.E. Williams, M.J. Soileau, E.W. Stryland, Appl. Phys. Lett. 43, 352 (1983)
C.H. Chan, C.D. Moody, W.K. McKnight, J. Appl. Phys. 44, 1179 (1973)
E.V. Zhuzhukalo, A.N. Kolomiski, A.F. Nastoyashchi, L.N. Plyashkevich, J. Quantum Electron. 11, 670 (1981)
J.J. Camacho, J.M.L. Poyato, L. Diaz, M. Santos, J. Phys. B, At. Mol. Opt. Phys. 40, 4573 (2007)
J.J. Camacho, M. Santos, L. Diaz, J.M.L. Poyato, Appl. Phys. A 94, 373 (2009)
J.J. Camacho, L. Diaz, M. Santos, D. Reyman, J.M.L. Poyato, J. Phys. D, Appl. Phys. 41, 105201 (2008)
J.J. Camacho, J.M.L. Poyato, L. Diaz, M. Santos, J. Appl. Phys. 102, 103302 (2007)
J.J. Camacho, M. Santos, L. Diaz, J.M.L. Poyato, J. Phys. D, Appl. Phys. 41, 215206 (2008)
NIST Atomic Spectra Database online at http://physics.nist.gov/PhysRefData/ASD/index.html
A. Lofthus, P.H. Krupenie, J. Phys. Chem. Ref. Data 6, 113 (1977)
G. Herzberg, Ergeb. Exakten Naturwiss. 10, 207 (1931)
W.C. Martin, R. Zalubas, J. Phys. Chem. Ref. Data 12, 323 (1983)
H.R. Griem, Spectral Line Broadening by Plasmas (Academic, New York, 1974)
H.R. Griem, Plasma Spectroscopy (McGraw-Hill, New York, 1964)
H.R. Griem, Principles of Plasma Spectroscopy (Cambridge University Press, Cambridge, 1977)
R.W.P. McWhirter, in Plasma Diagnostic Techniques, ed. by R.H. Huddlestone, S.L. Leonard (Academic, New York, 1965), Chap. 5
G. Herzberg, Spectra of Diatomic Molecules (Van Nostrand, New York, 1950)
A.D. MacDonald, Microwave Breakdown in Gases (Wiley, New York, 1966)
Y.P. Raizer, Gas Discharge Physics (Springer, Berlin, 1991)
T.L. Kopiczynski, M. Bogdan, A.W. Kalin, H.J. Schotwau, F.K. Kneubuhl, Appl. Phys. B, Photophys. Laser Chem. 54, 526 (1992)
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Camacho, J.J., Santos, M., Díaz, L. et al. Spectroscopy study of air plasma induced by IR CO2 laser pulses. Appl. Phys. A 99, 159–175 (2010). https://doi.org/10.1007/s00339-009-5466-x
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DOI: https://doi.org/10.1007/s00339-009-5466-x