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Dielectric response of water confined in metal–organic frameworks

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Abstract

Dielectric response of water confined in metal–organic frameworks was investigated in broad temperature range from 140 to 410 K and from 20 Hz to 1 MHz using a capacitance bridge. Several dispersion regions of characteristic shape were found, caused by freezing–melting of adsorbed water molecules, which disappear after a prolonged heating at 410 K. Temperature dependencies of relaxation time of confined water molecules were obtained and are compared to those of water confined in MCM-41 mesoporous molecular sieves.

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Authors and Affiliations

  1. Faculty of Physics, Vilnius University, Saulėtekio 9, 2040, Vilnius, Lithuania

    Juras Banys & Martynas Kinka

  2. Faculty of Physics and Geoscience, University of Leipzig, Linnéstr. 5, 04103, Leipzig, Germany

    Georg Völkel, Winfried Böhlmann & Andreas Pöppl

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  1. Juras Banys
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  2. Martynas Kinka
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  3. Georg Völkel
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  4. Winfried Böhlmann
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  5. Andreas Pöppl
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Correspondence to Juras Banys.

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Banys, J., Kinka, M., Völkel, G. et al. Dielectric response of water confined in metal–organic frameworks. Appl. Phys. A 96, 537–541 (2009). https://doi.org/10.1007/s00339-008-5052-7

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  • DOI: https://doi.org/10.1007/s00339-008-5052-7

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