Abstract
Field emission with high current density at low operating voltage was found for the yarns obtained by solid state spinning process from forest of vertically aligned multiwall carbon nanotubes. The nanotube forest was produced catalytically by CVD method. It is found that only a small fraction of carbon nanotubes from their total amount in the yarn yields to electron emission from its free end. This led to resistive heating of the emitting tubes and limiting of the emission current. The field emission microscopy pictures of MWNT yarn in free-end geometry appears to be very different from that of the conventional non-yarn carbon nanotube-based cathodes described in all previous studies. The FEM patterns are found to consist of the set of line and arc segments rather than a set of spots. Possible explanation of this effect is presented and discussed. The field emission from the lateral side of the yarns showed the self-enhanced currents increasing with operation time. We assume that this current increase may be due to untwisting and unwrapping of yarns resulted of application of the electric field. The lowest threshold field of about 0.7 V/μm was obtained after a few cycles of applied field increase. The prototypes of cathodoluminescent lamps and alphanumerical indicators based on MWNT twist-yarn cold cathodes are demonstrated.
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Yu.V. Gulyaev, L.A. Chernozatonskii, Z.Ja. Kosakovskaya, N.I. Sinitsyn, G.V. Torgashov, Yu.F. Zakharchenko, Le Vide Les Chouches Minces (Suppl. 271) 322 (1994), In 7th Intern. Vacuum Microelectronics Conf. (France, 1994), J. Vac. Sci. Technol. B 13, 435 (1995)
L.A. Chernozatonskii, Yu.V. Gulyaev, Z.Ja. Kosakovskaya, N.I. Sinitsyn, G.V. Torgashov, Yu.F. Zakharchenko, In 8th Intern. Vacuum Microelectronics Conf. (Portland, USA, 1995), p. 363
L.A. Chernozatonskii, Yu.V. Gulyaev, Z.Ja. Kosakovskaya, N.I. Sinitsyn, G.V. Torgashov, Yu.F. Zakharchenko, E.A. Fedorov, V.P. Val’chuk, Chem. Phys. Lett. 233, 63 (1995)
J.-M. Bonard, J.-P. Salvetat, T. Stöckli, L. Forro, A. Châtelain, Appl. Phys. A 69, 245 (1999)
S. Fan, M.G. Chapline, N.R. Franklin, T.W. Tombler, A.M. Cassell, H. Dai, Science 283, 512 (1999)
M. Chhowalla, K.B.K. Teo, C. Ducati, N.L. Rupesinghe, G.A.J. Amaratunga, A.C. Ferrari, D. Roy, J. Robertson, W.I. Mine, J. Appl. Phys. 90, 5308 (2001)
A.A. Zakhidov, R. Nanjundaswamy, M. Zhang, S.B. Lee, A.N. Obraztsov, A. Cunningham, A.A. Zakhidov, J. Appl. Phys. 100, 044327 (2006)
M. Zhang, K.R. Atkinson, R.H. Baughman, Science 306, 1358 (2004)
R. Gomer, Field Emission and Field Ionization (Harvard University Press, Cambridge, MA, 1961), Chapt. 1–2
R. Saito, M. Fujita, G. Dresselhaus, M.S. Dresselhaus, Appl. Phys. Lett. 60, 2204 (1992)
N.Y. Huang, J.C. She, J. Chen, S.Z. Deng, N.S. Xu, H. Bishop, S.E. Huq, L. Wang, D.Y. Zhong, E.G. Wang, D.M. Chen, Phys. Rev. Lett. 93, 075501 (2004)
A. G .Rinzler, J.H. Hafner, P. Nikolaev, L. Lou, S.G. Kim, D. Tomanek, P. Nordlander, D.T. Colbert, R.E. Smalley, Science 269, 1550 (1995)
S.T. Purcell, P. Vincent, C. Journet, Vu Thien Binh, Phys. Rev. Lett. 88, 105502 (2002)
M. Sveningsson, R.E. Morjan, O. Nerushev, E.E.B. Campbell, Carbon 42, 1165 (2004)
P. Vincent, S.T. Purcell, C. Journet, Vu Thien Binh, Phys. Rev. B 66, 075406 (2002)
P. Gustafson, Carbon 24, 169 (1986)
as referenced by A.T. Dinsdale, SGTE Data for Pure Elements, CALPHAD 15, 317 (1991)
G. Fursey, Field Emission in Vacuum Microelectronics (Kluwer Academic/Plenum Publishers, New Work, 2005), pp. 39–44
Y. Saito, K. Hamaguchi, K. Hata, K. Uchida, Y. Tasaka, F. Ikazaki, M. Yumura, A. Kasuya, Y. Nishina, Nature 389, 554 (1997)
Y. Saito, K. Hata, A. Takakura, J. Yotani, S. Uemura, Physica B 323, 30 (2002)
N. de Jonge, Y. Lamy, K. Schoots, T.H. Oosterkamp, Nature 420, 393 (2002)
Y. Wei, D. Weng, Y. Yang, X. Zhang, K. Jiang, L. Liu, S. Fan, Appl. Phys. Lett. 89, 063101 (2006)
K.A. Dean, B.R. Chalamala, Appl. Phys. Lett. 75, 3017 (1999)
A.N. Obraztsov, A.P. Volkov, A.A. Zakhidov, D.A. Lyashenko, Yu.V. Petrushenko, O.P. Satanovskaya, Appl. Surf. Sci. 215, 214 (2003)
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Zakhidov, A., Nanjundaswamy, R., Obraztsov, A. et al. Field emission of electrons by carbon nanotube twist-yarns. Appl. Phys. A 88, 593–600 (2007). https://doi.org/10.1007/s00339-007-4009-6
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DOI: https://doi.org/10.1007/s00339-007-4009-6