Abstract
Low-temperature laser sintering has been successfully demonstrated to improve the overall conversion efficiency of dye-sensitized solar cells. Mesoporous TiO2 electrodes were prepared from a colloidal solution of TiO2 nanopowders by a laser direct-write technique and then sintered by a quasi-continuous-wave UV laser (λ=355 nm) for the fabrication of dye-sensitized solar cells. The overall conversion efficiency of the cells based on the laser-sintered TiO2 electrodes was double that of the devices with non-laser-treated TiO2 electrodes. This enhancement is attributed to both the removal of organic additives and the improved inter-nanoparticle electrical contacts induced by the laser-sintering process, which led to an increase in porosity and dye-absorption sites in the TiO2 electrodes.
Similar content being viewed by others
References
O’Regan B, Grätzel M (1991) Nature 353:737
Nazeeruddin MK, Kay A, Rodicio I, Humphry-Baker R, Muller E, Liska P, Vlachopoulos N, Grätzel M (1993) J. Am. Chem. Soc. 115:6382
Barbe CJ, Arendse F, Comte P, Jirousek M, Lenzmann F, Shklover V, Grätzel M (1997) J. Am. Ceram. Soc. 80:3157
Nakada S, Matsuda M, Kambe S, Saito Y, Kitamura T, Sakata T, Wada Y, Mori H, Yanagida S (2002) J. Phys. Chem. B 106:10004
Kalyanasundaram K, Grätzel M (1998) Coord. Chem. Rev. 77:347
Pichot F, Pitts JR, Gregg BA (2000) Langmuir 16:5626
Lindström H, Holmberg A, Magnusson E, Lindquist S-E, Malmqvist L, Hagfeldt A (2001) Nano Lett. 1:97
Lindström H, Magnusson E, Holmberg A, Södergren S, Lindquist S-E, Hagfeldt A (2002) Sol. Energ. Mat. Sol. C. 73:91
Ito S, Takeuchi T, Katayama T, Sugiyama M, Matsuda M, Kitamura T, Wada Y, Yanagida S (2003) Chem. Mater. 15:2824
Kim H, Kushto GP, Arnold CB, Kafafi ZH, Piqué A (2004) Appl. Phys. Lett. 85:464
Zhang D, Yoshida T, Minoura H (2003) Adv. Mater. 15:814
Piqué A, Chrisey DB, Fitz-Gerald JM, McGill RA, Auyeung RCY, Wu HD, Lakeou S, Nguyen V, Chung R, Duignan M (2000) J. Mater. Res. 15:1872
Piqué A, Arnold CB, Kim H, Ollinger M, Sutto TE (2004) Appl. Phys. A 79:783
Arnold CB, Sutto T, Kim H, Pique A (2004) Laser Focus World 40:S9
Karunagaran B, Kumar RTR, Viswanathan C, Mangalaraj D, Narayandass SK, Rao GM (2003) Cryst. Res. Technol. 38:773
Eskandari H, Karkaragh GI (2003) Bull. Korean Chem. Soc. 24:1731
Herbst L, Kahlert H-J, Fechner B, Rebhan U, Osmanow R (2003) Proc. SPIE 5004:69
Author information
Authors and Affiliations
Corresponding author
Additional information
PACS
61.80.Ba; 61.46.+w; 73.22.-f; 84.60.Jt
Rights and permissions
About this article
Cite this article
Kim, H., Auyeung, R., Ollinger, M. et al. Laser-sintered mesoporous TiO2 electrodes for dye-sensitized solar cells. Appl. Phys. A 83, 73–76 (2006). https://doi.org/10.1007/s00339-005-3449-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-005-3449-0