Abstract
We report a new structure for CuInS2/In2S3 solar cell, in which both absorber and buffer layers were deposited using chemical spray pyrolysis (CSP) technique. The usual superstrate structure, having buffer layer just above ITO, was not functioning mainly due to diffusion of Cu into In2S3 layer as seen from X-ray photoelectron spectroscopy (XPS) results. However, when the configuration of the cell was ITO/CuInS2/In2S3/Ag, cell parameters obtained were Voc=0.45 V, Jsc=44.03 mA/cm2, fill factor (FF) = 29.5% and η=5.87%. Good results could be obtained by using indium sulfide thin films having maximum photosensitivity. The cell was characterized using X-ray diffraction, optical absorption, current–voltage and spectral response measurements.
Similar content being viewed by others
References
Abushama JAM, Johnston S, Moriarty T, Teeter G, Ramanathan K, Noufi R (2004) Prog. Photovoltaics: Res. Appl. 12:39
Powalla M, Dimmler B (2000) Thin Solid Films 361–362:540
Watanabe T, Matsui M (1999) Jpn. J. Appl. Phys. 38:L1379
Ramanathan K, Contreras MA, Perkins CL, Asher S, Hasoon FS, Keane J, Young D, Romero M, Metzger W, Noufi R, Ward J, Duda A (2003) Prog. Photovoltaics: Res. Appl. 11:225
Nakada T, Mizutani M, Hagiwara Y, Kunioka A (2001) Sol. Energ. Mat. Sol. C. 67:255
Ohtake Y, Kushiyal K, Ichikawa M, Yamada A, Konagai M (1998) Jpn. J. Appl. Phys. 37:3220
Gordillo G, Calderón C (2003) Sol. Energ. Mat. Sol. C. 77:163
Hariskos D, Ruckh M, Rühle U, Walter T, Schock HW, Hedström J, Stolt L (1996) Sol. Energ. Mat. Sol. C. 41/42:345
Spiering S, Hariskos D, Powalla M, Naghavi N, Loncot D (2003) Thin Solid Films 431–432:359
Engelhardt F, Bornemann L, Köntges M, Meyer T, Parisi J, Pschorr-Schoberer E, Hahn B, Gebhardt W, Riedl W, Rau U (1999) Prog. Photovoltaics: Res. Appl. 7:423
Herrero J, Ortega G (1990) Sol. Energ. Mat. 20:53
Gindle SP, Smith CW, Mittlem SD (1979) Appl. Phys. Lett. 35:24
Bihri H, Abd-Lefdil M (1999) Thin Solid Films 354:5
Krunks M, Kijatkina O, Rebane H, Oja I, Mikli V, Mere A (2002) Thin Solid Films 404:71
Ortega-López M, Morales-Acevedo A (1998) Thin Solid Films 330:96
Kazmerski LL, Sanborn GA (1977) J. Appl. Phys. 48:3178
Klaer J, Bruns J, Henninger R, Siemer K, Klenk R, Ellmer K, Bräunig D (1998) Semicond. Sci. Technol. 13:1456
Siemer K, Klaer J, Luck I, Bruns J, Klenk R, Bräunig D (2001) Sol. Energ. Mat. Sol. C. 67:159
Scheer R, Walter T, Schock HW, Fearheiley ML, Lewerenz HJ (1993) Appl. Phys. Lett. 63:3294
Ogawa Y, Jäger-Waldau A, Hashimoto Y, Ito K (1994) Jpn. J. Appl. Phys. 33:L1775
Braunger D, Hariskos D, Walter T, Schock HW (1996) Sol. Energ. Mat. Sol. C. 40:97
Mere A, Kijatkina O, Rebane H, Krustok J, Krunks M (2003) J. Phys. Chem. Solids 64:2025
John TT, Bini S, Kashiwaba Y, Abe T, Yasuhiro Y, Kartha CS, Vijayakumar KP (2003) Semicond. Sci. Technol. 18:491
Djessas K, Abatchou A, Massé G (2000) J. Appl. Phys. 88:5710
Pai RR, John TT, Kashiwaba Y, Abe T, Vijayakumar KP, Kartha CS (2004) J. Mater. Sci., DOI: KL1956-08/10437-03
John TT, Vijayakumar KP, Kartha CS, Kashiwaba Y, Abe T (2003) Proc. World Conference on Photovoltaic Energy Conversion (WCPEC-3), Osaka, Japan 1P-C3-24
John TT, Kartha CS, Vijayakumar KP, Abe T, Kashiwaba Y (2004) Proc. 12th International Conference on Solid Films and Surfaces (ICSFS-12) Hamamatsu, Japan 101
John TT, Wilson KC, Ratheesh Kumar PM, Kartha CS, Vijayakumar KP, Kashiwaba Y, Abe T, Yasuhiro Y (2004) Phys. Stat. Solidi A, DOI: 10.1002/pssa.200406875
El-Adawi MK, Al-Nuaim IA (2001) Vacuum 64:33
Igalson M, Platzer-Björkman C (2004) Sol. Energ. Mat. Sol. C. 84:93
Gloeckler M, Jenkins CR, Sites JR (2003) Mat. Res. Soc. Symp. Proc. 763:B5.20.1
Eisgruber IL, Granata JE, Sites JR, Hou J, Kessler J (1998) Sol. Energ. Mat. Sol. C. 53:367
Potlog T, Ghimpu L, Gashin P, Pudov A, Nagle T, Sites J (2003) Sol. Energ. Mat. Sol. C. 80:327
Naghavi N, Spiering S, Powalla M, Canava B, Lincot D (2003) Prog. Photovoltaics: Res. Appl. 11:437
Author information
Authors and Affiliations
Corresponding author
Additional information
PACS
81.15.Rs; 82.45.Mp; 84.60.Jt
Rights and permissions
About this article
Cite this article
John, T., Kartha, C., Vijayakumar, K. et al. Modification in cell structure for better performance of spray pyrolysed CuInS2/In2S3 thin film solar cell. Appl. Phys. A 82, 703–707 (2006). https://doi.org/10.1007/s00339-005-3385-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-005-3385-z