Abstract
Hydrogen-terminated, atomically flat, 1×1 (un)reconstructed, (100)-oriented, silicon surfaces have been functionalized with 1-octyne and then studied via X-ray photoelectron spectroscopy. The C 1s signal shows that the addition of the hydrocarbon chain occurs through the formation of environmentally stable Si-C bonds, in agreement with hydrosilation as the major grafting route.
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M. Niwano, J. Kageyama, K. Kinashi, I. Takashi, N. Miyamoto: J. Appl. Phys. 76, 2157 (1994)
T. Aoyama, K. Goto, T. Yamazaki, T. Ito: J. Vac. Sci. Technol. A 14, 2909 (1996)
M. Morita, T. Ohmi, E. Hasegawa, M. Kawakami, M. Ohwada: J. Appl. Phys. 68, 1272 (1990)
K. Usuda, H. Kanaya, K. Yamada, T. Sato, T. Sueyoshi, M. Iwatsuki: Appl. Phys. Lett. 64, 3240 (1994)
G.F. Cerofolini, L. Meda, R. Falster: In Semiconductor Silicon 1994, ed. by H.R. Huff, W. Bergholz, K. Sumino (The Electrochemical Society, Pennington, NJ 1994) p. 379
G.F. Cerofolini, G. La Bruna, L. Meda: Appl. Surf. Sci. 93, 255 (1996)
G.F. Cerofolini: In Silicon for the Chemical Industry III, ed. by H.A. Oye, H.M. Rong, B. Ceccaroli, L. Nygaard, J.K. Tuset (Tapir, Trondheim 1996) p. 117
G. Cleland, B.R. Horrocks, A. Houlton: J. Chem. Soc. Faraday Trans. 91, 4001 (1995)
S.F. Bent: Surf. Sci. 500, 879 (2002)
J.M. Buriak: Chem. Rev. 102, 1271 (2002)
G.F. Cerofolini, C. Galati, S. Lorenti, L. Renna, O. Viscuso, C. Bongiorno, V. Raineri, C. Spinella, G.G. Condorelli, I.L. Fragalà, A. Terrasi: Appl. Phys. A, DOI 10.1007/s00339-002-1997-0
F.A. Cotton, G. Wilkinson: Advanced Inorganic Chemistry, 5th edn. (Wiley, New York, 1988) p. 1255
M.R. Linford, C.E.D. Chidsey: J. Am. Chem. Soc. 115, 12631 (1993)
M.R. Linford, P. Fenter, P.M. Eisenberger, C.E.D. Chidsey: J. Am. Chem. Soc. 117, 3145 (1995)
J. Terry, M.R. Linford, C. Wigren, R. Cao, P. Pianetta, C.E.D. Chidsey: Appl. Phys. Lett. 71, 1056 (1997)
A.B. Sieval, A.L. Demirel, J.W.M. Nissink, J.H. van der Maas, W.H. de Jeu, H. Zuilhof, E.J.R. Sudholter: Langmuir 14, 1759 (1998)
A.B. Sieval, V. Vleemimg, H. Zuilhof, E.J.R. Sudholter: Langmuir 15, 8288 (1999)
A.B. Sieval, R. Opitz, H.P.A. Maas, M.G. Schoeman, G. Meijer, F.J. Vergeldt, H. Zuilhof, E.J.R. Sudholter: Langmuir 16, 10359 (2000)
H. Ubara, T. Imura, A. Hiraki: Solid State Commun. 50, 673 (1984)
G.F. Cerofolini, C. Galati, L. Renna: Surf. Interface Anal. 34, 583 (2002)
Z.H. Lu, M.J. Graham, D.T. Jiang, K.H. Tan: Appl. Phys. Lett. 63, 2941 (1993)
F.J. Himpsel, F.R. McFeely, A. Taleb-Ibrahimi, J.A. Yarnoff, G. Hollinger: Phys. Rev. B 38, 6084 (1988)
G. Beamson, D. Briggs: High Resolution XPS of Organic Polymers (Wiley, Chichester 1992) Table A.3
G.F. Cerofolini, C. Galati, S. Reina, L. Renna: Mater. Sci. Eng. C 23, 253 (2003)
D. Briggs, J.C. Rivière: In Practical Surface Analysis, Vol. 1: Auger and X-ray Photoelectron Spectroscopy, 2nd edn., ed. by D. Briggs. M.P. Seah (Wiley, Chichester and Salle & Sauerländer, Aarau 1990) Sect. 3.5, p. 134
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82.65.+r; 68.39.-p; 73.20.-r; 79.60.Jv
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Cerofolini, G., Galati, C., Reina, S. et al. Grafting of 1-alkynes to hydrogen-terminated (100)silicon surfaces. Appl. Phys. A 80, 161–166 (2005). https://doi.org/10.1007/s00339-003-2256-8
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DOI: https://doi.org/10.1007/s00339-003-2256-8