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Characterization and electrochemical behaviors of honeycomb-patterned poly(N-vinylcarbazole)/polystyrene composite films

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Abstract

Poly(N-vinylcarbazole)/polystyrene composites were prepared through simple radical polymerization of N-vinylcarbazole in the presence of polystyrene. Honeycomb-patterned composite thin films were fabricated by casting the composite solutions under humid conditions. The scanning electron microscopy (SEM) images of the resulting honeycomb pattern on the composites show a higher regular structure compared to those of films prepared from the poly(N-vinylcarbazole) homopolymer. The pressure-area isotherms and photoelectrochemical behaviors of the patterned films were also observed. The photoconductivity of the patterned thin films increased with increasing poly(N-vinylcarbazole) concentration. This enhancement is attributed to the effects of the honeycomb structures and the charge transfer across the donor/acceptor hybrid interface in the composite films.

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Acknowledgment

This research was supported by the National Research Foundation of Korea (NRF) (2011-0025853).

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Authors and Affiliations

  1. Department of Chemistry and Institute of Basic Science, Inje University, Kimhae, Kyungnam, 621-749, South Korea

    Phung Xuan Thinh, C. Basavaraja, D. G. Kim & Do Sung Huh

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  1. Phung Xuan Thinh
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  2. C. Basavaraja
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  3. D. G. Kim
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  4. Do Sung Huh
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Correspondence to Do Sung Huh.

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Thinh, P.X., Basavaraja, C., Kim, D.G. et al. Characterization and electrochemical behaviors of honeycomb-patterned poly(N-vinylcarbazole)/polystyrene composite films. Polym. Bull. 69, 81–94 (2012). https://doi.org/10.1007/s00289-012-0727-9

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  • DOI: https://doi.org/10.1007/s00289-012-0727-9

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