Skip to main content
Log in

Dynamic mechanical, thermal, and morphological study of ABS/textile fiber composites

  • Original Paper
  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Abstract

In this work, acrylonitrile–butadiene–styrene ABS terpolymer was mixed with acrylic fiber, cotton fiber, and waste textile fiber (WTF) (50/50 wt% cotton/acrylic fiber) with 10 and 30 wt% of fiber content in a batch mixer. The composites with 30 wt% of acrylic fiber showed the highest stabilized torque, while the compositions with 30 wt% of cotton were situated at the lowest values in torque rheometry. The fiber addition up to 30 wt% did not have effect on the degradation behavior of ABS matrix. The composites with 30% textile fiber showed a higher degradation step, which is related to fiber degradation. The fiber content resulted in a considerable increase in stiffness at all temperatures as can be observed on the dynamic mechanical thermal properties (DMTA). The reinforcing effect was higher in the region above the glass transition temperature, T g, of the matrix, this is primarily due to the larger difference in mechanical properties between the filler and the matrix as it goes from the glassy to the rubbery state.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Habibi Y, El-Zawawy WK, Ibrahim MM, Dufresne A (2008) Processing and characterization of reinforced polyethylene composites made with lignocellulosic fibers from Egyptian agro-industrial residues. Compos Sci Technol 68:1877–1885

    Article  CAS  Google Scholar 

  2. Khonder AO, Ishiaku SU, Nakai A, Hamada H (2006) A novel processing technique for thermoplastic manufacturing of unidirectional composites reinforced with jute yarns. Composites A 37:2274–2284

    Article  Google Scholar 

  3. Mwaikamboa YL, Bisandab NTE (1999) The performance of cotton–kapok fabric polyester composites. Polym Test 18:181–198

    Article  Google Scholar 

  4. Amat T, Blanco TM, Palorno A (1994) Acrylic fibres as reinforcement for cement pastes. Cem Concr Compos 16:31–37

    Article  CAS  Google Scholar 

  5. Simitzis J, Terlemesian E, Mladenov I (1995) Utilization of waste PAN fibers as adsorbents by chemical and thermal modification. Eur Polym J 31:1261–1267

    Article  CAS  Google Scholar 

  6. Campisi RL, Bourbigot S, Bras LM, Delobel R (1996) Thermal behavior of cotton-modacrylic fibre blends: kinetic study using the invariant kinetic parameters method. Thermochim Acta 275:37–49

    Article  Google Scholar 

  7. Owen RS, Harper FJ (1999) Mechanical, microscopical and fire retardant studies of ABS Polymers. Polym Degrad Stab 64:449–455

    Article  CAS  Google Scholar 

  8. Modesti M, Besco S, Lorenzetti A, Causin V, Marega C, Gilman WJ, Fox MD, Trulove CP, De Long CH, Zammarano M (2007) ABS/clay nanocomposites obtained by a solution technique: influence of clay organic modifiers. Polym Degrad Stab 92:2206–2213

    Article  CAS  Google Scholar 

  9. Ozkoca G, Bayramb G, Bayramlic E (2004) Effects of polyamide 6 incorporation to the short glass fiber reinforced ABS composites: an interfacial approach. Polymer 45:8957–8966

    Article  Google Scholar 

  10. Mantovani LG, Canto BL, Junior HE, Pessan AL (2001) Toughening of PBT by ABS, SBS and HIPS systems and the effects of reactive functionalized copolymers. Macromol Symp 176:167–180

    Article  CAS  Google Scholar 

  11. Freire E, Bianchi O, Monteiro CEE, Nunes RCR, Forte CM (2009) Processability of PVDF/PMMA blends studied by torque rheometry. Mater Sci Eng C 29:657–661

    Article  CAS  Google Scholar 

  12. Martina CS, Liggata JJ, Snapeb CE (2001) In situ NMR investigation into the thermal degradation and stabilization of PAN. Polym Degrad Stab 74:407–412

    Article  Google Scholar 

  13. Bajaj P, Sreekumar VT, Sen K (2001) Thermal behavior of acrylonitrile copolymers having methacrylic and itaconic acid comonomers. Polymer 42:1707–1718

    Article  CAS  Google Scholar 

  14. Bajaj P, Padmanaban M (1985) Thermal behavior of copolymers of acrylonitrile with haloalkyl acrylates or methacrylates. Eur Polym J 21:93–96

    Article  CAS  Google Scholar 

  15. Cooney DJ, Day M, Wiles MD (1986) A kinetic study of the thermal degradation of polyester/cotton blends by thermogravimetric. Thermochim Acta 102:335–347

    Article  CAS  Google Scholar 

  16. Fornes DT, Paul RD (2003) Modeling properties of nylon 6/clay nanocomposites using composite theories. Polymer 44:4993–5013

    Article  CAS  Google Scholar 

  17. Castel Dal C, Bianchi O, Oviedo SAM, Liberman AS, Mauler SR, Oliveira BVR (2009) The influence of interfacial agents on the morphology and viscoelasticity of PP/MMT nanocomposites. Mater Sci Eng C 29:602–606

    Article  Google Scholar 

  18. Alcock B, Cabrera ON, Barkoula MN, Reynolds TC, Govaert EL, Peijs T (2007) The effect of temperature and strain rate on the mechanical properties of highly oriented polypropylene tapes and all-polypropylene composites. Comp Sci Technol 67:2061–2070

    Article  CAS  Google Scholar 

  19. Kim JS, Moon BJ, Kim HG, Ha SC (2008) Mechanical properties of polypropylene/natural fiber composites: comparison of wood fiber and cotton fiber. Polym Test 27:801–806

    Article  CAS  Google Scholar 

  20. Xu FX, Wang R, Tan YZ, Yang DH, Zhang YM, Zhang XH (2005) Effects of polybutadiene-g-SAN impact modifiers on the morphology and mechanical behaviors of ABS blends. Eur Polym J 41:1919–1926

    Article  CAS  Google Scholar 

  21. Wyzgoski GM (1980) Physical aging of poly(acrylonitrile-butadiene-styrene). I. Dynamic mechanical measurements. J Appl Polym Sci 25:1443–1453

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Johnny N. Martins.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Martins, J.N., Klohn, T.G., Bianchi, O. et al. Dynamic mechanical, thermal, and morphological study of ABS/textile fiber composites. Polym. Bull. 64, 497–510 (2010). https://doi.org/10.1007/s00289-009-0200-6

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00289-009-0200-6

Keywords

Navigation