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Preparation of cellulose-based ionic porous material compatibilized with polymeric ionic liquid

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Abstract

Cellulose-based ionic porous material compatibilized with polymeric ionic liquid was prepared by means of templating technique using oil/ionic liquid emulsion in the presence of sorbitane monooleate. In situ polymerization of a mixture of polymerizable ionic liquids, 1-(3-acryloyloxypropyl)-3-methylimidazolium and 1-(3-acryloyloxypropyl)-3-vinylimidazolium bromides was first performed in a solution of cellulose in a solvent of an ionic liquid, 1-butyl-3-methylimidazolium chloride. The sonication of the mixture coexisting with corn oil and sorbitan monooleate, followed by the successive treatment with methanol, acetone, and hexane gave the porous material. The material thus obtained was characterized by the FT-IR, TGA, XRD, and SEM measurements. The SEM images of the material showed the morphology of the porosity with the pore sizes of around 0.15–1.3 μm accompanied with the smaller sizes of 30–70 nm.

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Acknowledgment

K.·P. extends his gratitude to INOUE research foundation for science, Tokyo for providing a fellowship and CSIR, India for granting deputation.

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Authors and Affiliations

  1. Discipline of Marine Biotechnology and Ecology, Central Salt and Marine Chemicals Research Institute (Council of Scientific and Industrial Research), G. B. Marg, Bhavnagar, Gujarat, 364002, India

    Kamalesh Prasad

  2. Graduate School of Science and Engineering, Kagoshima University, 1-21-40 Korimoto, Kagoshima, 890-0065, Japan

    Shozaburo Mine, Yoshiro Kaneko & Jun-ichi Kadokawa

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  1. Kamalesh Prasad
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  2. Shozaburo Mine
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  3. Yoshiro Kaneko
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  4. Jun-ichi Kadokawa
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Correspondence to Jun-ichi Kadokawa.

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Prasad, K., Mine, S., Kaneko, Y. et al. Preparation of cellulose-based ionic porous material compatibilized with polymeric ionic liquid. Polym. Bull. 64, 341–349 (2010). https://doi.org/10.1007/s00289-009-0144-x

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  • DOI: https://doi.org/10.1007/s00289-009-0144-x

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