Summary
Well-defined water-soluble poly(styrenesulfonate)-b-poly(ethylene glycol)-b- poly(styrenesulfonate) (PSS-b-PEG-b-PSS) triblock copolymers with narrow molecular weight distribution (1.29 < Mw/Mn < 1.36) were synthesized in aqueous solution at 70 oC via reversible addition-fragmentation chain transfer (RAFT) polymerization. The complex formed by the PSS-b-PEG-b-PSS triblock copolymer coordinated with aluminum ion was investigated with turbidimetry, dynamic light scattering (DSL), zeta-potential, and transmission electron microscopy (TEM). The aggregation formation was based on the neutralization of the SO3- groups in the PSS blocks with Al3+ ions. The appearance, size and stability of the PSS-b-PEG-b-PSS/Al3+ aggregates were controlled by varying the PSS block length and degree of neutralization (DN). At DN = 0.33, where the PSS-b-PEG-b-PSS copolymer was completely neutralized with Al3+, the aggregate size increased with increasing PSS block length. The transition from the shrinking coil of small size to the interchain aggregates of large size was found at DN of about 0.33.
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Alvarez-Lorenzo C, Barreiro-Iglesias R, Concheiro A, Iourtchenko L, Alakhov V, Bromberg L, Temchenko M, Deshmukh S, Hatton TA (2005) Langmuir 21:5142
Kabanov AV, Kabanov VA (1998) Adv Drug Delivery Rev 30:49
Rungsardthong U, Deshpande M, Bailey L, Vamvakaki M, Armes SP, Garnett MC, Stolnik S (2001) J Control Release 73:359
Auguste DT, Armes SP, Brzezinska KR, Deming TJ, Kohn J, Prud’homme RK (2006) Biomaterials 27:259
Giacomelli C, Schmidt V, Borsali R (2007) Macromolecules 40:2148
Karanikolopoulos N, Pitsikalis M, Hadjichristidis N, Georgikopoulou K, Calogeropoulou T, Dunlap JR (2007) Langmuir 23:4214
Cölfen H, Antonietti M (1998) Langmuir 14:582
Cölfen H, Qi LM (2001) Chem Eur J 7:106
Guo XH, Yu SH (2007) Cryst Growth Des 7:354
Qi LM, Li J, Ma JM (2002) Adv Mater 14:300
Yu SH, Cölfen H, Antonietti M (2003) J Phys Chem B 107:7396
Guillemet B, Faatz M, Grohn F, Wegner G, Gnanou Y (2006) Langmuir 22:1875
Qi LM, Cölfen H, Antonietti M (2001) Nano Letters 1:61
Bronstein LM, Sidorov SN, Gourkova AY, Valetsky PM, Hartmann J, Breulmann M, Cölfen H, Antonietti M (1998) Inorg Chim Acta 280:348
Cölfen H (2001) Macromol Rapid Comm 22:219
Li Y, Gong YK, Nakashima K, Murata Y (2002) Langmuir 18:6727
Li Y, Ikeda S, Nakashima K, Nakamura H (2003) Colloid Polym Sci 281:562
Nishiyama N, Yokoyama M, Aoyagi T, Okano T, Sakurai Y, Kataoka K (1999) Langmuir 15:377
Yokoyama M, Okano T, Sakurai Y, Suwa S, Kataoka K (1996) J Control Release 39:351
Harada A, Kataoka K (1998) Macromolecules 31:288
Harada A, Kataoka K (1999) Langmuir 15:4208
Harada A, Kataoka K (1999) J Am Chem Soc 121:9241
Narh KA, Keller A (1993) J Polym Sci Part B: Polym Phys 31:231
Jan JS, Breedveld V (2008) Macromolecules 41:6517
Dubois E, Boué F (2001) Macromolecules 34:3684
Peng ZP, Wang D, Liu XX, Tong Z (2007) J Polym Sci Part A: Polym Chem 45:3698
Ohtaki H, Radnai T (1993) Chem Rev 93:1157
Ikeda T, Hirata M, Kimura T (2003) J Chem Phys 119:12386
Michaeli I (1960) J Polym Sci 48:291
Ikegami A, Imai N (1962) J Polym Sci 56:133
Schweins R, Huber K (2001) Eur Phys J E 5:117
Peng S, Wu C (1999) Macromolecules 32:585
Ikeda Y, Beer M, Schmidt M, Huber K (1998) Macromolecules 31:728
Yang YY, Zeng F, Tong Z, Liu XX, Wu SZ (2001) J Polym Sci Part B: Polym Phys 39:901
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Peng, Z., Liu, X. & Tong, Z. Synthesis and aggregate formation of poly(styrenesulfonate)-b-poly(ethylene glycol)-b-poly(styrenesulfonate) triblock copolymers in aqueous solution induced by binding with aluminum ions. Polym. Bull. 61, 725–736 (2008). https://doi.org/10.1007/s00289-008-1004-9
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DOI: https://doi.org/10.1007/s00289-008-1004-9