Abstract
The copolymerization reactions of acrylamide and N,N’-methylenebis(acrylamide) were carried out in DMSO/water mixture (1:1 by volume) at various temperatures Tprep between -18 and 22 °C. Scanning electron microscopy analysis of the networks revealed the presence of porous morphologies. All the network samples formed at or below 0 °C have relatively small pores with sizes about 100 µm. In this range of Tprep, the pore size only slightly increases with the temperature. As the temperature is increased above 0 °C, both the average pore size and the degree of polydispersity of the pores rapidly increase. Between Tprep=0 and 13 °C, the microstructure gradually changes from networks having relatively small pores to those exhibiting regular assembly of polyhedral large pores of about 101 µm in sizes. The formation of the porous structure at or below 0 °C is as a result of the cooling-induced phase separation mechanism, while the large polyhedral pores in the networks prepared at higher temperatures form during the freeze-dry process of the hydrogels after preparation.
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Ozmen, M.M., Dinu, M.V. & Okay, O. Preparation of macroporous poly(acrylamide) hydrogels in DMSO/water mixture at subzero temperatures . Polym. Bull. 60, 169–180 (2008). https://doi.org/10.1007/s00289-007-0851-0
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DOI: https://doi.org/10.1007/s00289-007-0851-0