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Synthesis and Properties of Novel Poly(p-phenylenevinylene)s Containing a Tricarbonyl(arene)chromium Unit in the Main Chain

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Summary

Novel π-conjugated polymers based on poly(p-phenylenevinylene)s (PPVs) containing a tricarbonyl(arene)chromium unit in the main chain were synthesized by Horner-Wadsworth-Emmons olefination. The structures of the polymers were supported by lH NMR and IR spectra. The polymers obtained were soluble in common solvents such as THF, CH2Cl2, CHCl3 and toluene. The molecular weights of the polymers were determined by GPC. Their thermal, optical, and electrochemical properties were investigated in detail.

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Authors and Affiliations

  1. Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan, e-mail: chujo@chujo.synchem.kyoto-u.ac.jp, , , , , , JP

    Yasuhiro Morisaki, Hui Chen & Yoshiki Chujo

Authors
  1. Yasuhiro Morisaki
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  2. Hui Chen
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  3. Yoshiki Chujo
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Additional information

Received: 18 November 2002/Revised version: 10 February 2003/ Accepted: 11 February 2003

Correspondence to Yoshiki Chujo

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Morisaki, Y., Chen, H. & Chujo, Y. Synthesis and Properties of Novel Poly(p-phenylenevinylene)s Containing a Tricarbonyl(arene)chromium Unit in the Main Chain. Polymer Bulletin 50, 39–46 (2003). https://doi.org/10.1007/s00289-003-0131-6

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  • DOI: https://doi.org/10.1007/s00289-003-0131-6

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