Skip to main content
SpringerLink
Log in

Synthesis, crystal structure, high-temperature behavior and magnetic properties of CoBiO(AsO4), a Co analogue of paganoite

  • Original Paper
  • Published:
Physics and Chemistry of Minerals Aims and scope Submit manuscript

Abstract

Single crystals and powder samples of Co analogue of paganoite CoBiO(AsO4) have been obtained by high-temperature solid-state reactions. Crystal structure [triclinic, \(P\bar{ 1 }\), a = 5.2380(3), b = 6.8286(4), c = 7.6150(4) Å, α = 111.631(2), β = 108.376(2), γ = 108.388(2)°, V = 209.55(2) Å3] has been refined to R 1 = 0.018 on the basis of 1524 unique observed reflections. CoBiO(AsO4) is isotypic to paganoite, NiBiO(AsO4). The crystal structure can be described as based upon [OCoBi]3+ chains of edge-sharing (OBi2Co2) tetrahedra linked via (AsO4) groups. Differential thermal analysis reveals no phase decomposition till 850 °C, when the compound starts to melt. A small endothermic peak is observed near 330 °C. Thermal expansion has been studied by high-temperature powder X-ray diffraction. Thermal expansion coefficients (α a  = 10.1 × 10−6, α b  = 12.6 × 10−6, α c  = 10.5 × 10−6 K−1) indicate a relatively isotropic behavior with the less intense expansion direction parallel to the direction of the chains of oxocentered tetrahedra. Magnetic susceptibility of CoBiO(AsO4) reveals the presence of an antiferromagnetic ordering at T N = 15.4 K.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  • Abraham F, Ketatni M (1995) Crystal structure of a new bismuth nickel oxophosphate: BiNiOPO4. Eur J Solid State Inorg Chem 32:429–437

    Google Scholar 

  • Abraham F, Ketatni M, Mairesse G, Mernari B (1994) Crystal structure of a new bismuth copper oxyphosphate: BiCu2PO6. Eur J Solid State Inorg Chem 31:313–323

    Google Scholar 

  • Benmokhtar S, El Jazouli A, Chaminade JP, Gravereau P, Guillen F, de Waal D (2004) Synthesis, crystal structure and optical properties of BiMgVO5. J Solid State Chem 177:4175–4182

    Article  Google Scholar 

  • Boje J, Mueller-Buschbaum H (1993) Synthese und Kristallstruktur von CaBiVO5. Z Anorg Allg Chem 619:521–524

    Article  Google Scholar 

  • Brown ID, Altermatt D (1985) Bond-valence parameters obtained from a systematic analysis of the inorganic crystal structure database. Acta Crystallogr B 41:244–247

    Article  Google Scholar 

  • Bruker (2005) APEX2, SAINT-Plus and XPREP. Bruker AXS Inc., Madison

    Google Scholar 

  • Chukanov NV, Möhn G, Pekov IV, Belakovskiy DI, Bychkova YV, Gurzhiy VV, Lorenz JA (2014) Okruschite, Ca2Mn5 2+Be4(AsO4)6‧6H2O, a new roscherite-group mineral from Sailauf, Bavaria, Germany. Eur J Mineral 26:589–595

    Google Scholar 

  • Elliott P, Kolitsch U, Willis AC, Libowitzky E (2013) Description and crystal structure of domerockite, Cu4(AsO4)(AsO3OH)(OH)3·H2O, a new mineral from the Dome Rock Mine, South Australia. Mineral Mag 77:509–522

    Article  Google Scholar 

  • Giraud S, Mizrahi A, Drachea M, Conflant P, Wignacourt JP, Steinfink H (2001) A new family of compounds with tetrahedral anions: PbnBiOn(XO4), X = V, P, As, n = 1,2,4. A comparison with lead oxysulfates PbnPbOn(SO4). Solid State Sci 3:593–602

    Article  Google Scholar 

  • Goodenough JB (1963) Magnetism and the chemical bond. Wiley, New York

    Google Scholar 

  • Hawthorne FC (2014) The structure hierarchy hypothesis. Mineral Mag 78:957–1027

    Google Scholar 

  • Kampf AR, Mills SJ, Housley RM, Rossman GR, Nash BP, Dini M, Jenkins RA (2013) Joteite, Ca2CuAl[AsO4][AsO3(OH)]2(OH)2·5H2O, a new arsenate with a sheet structure and unconnected acid arsenate groups. Mineral Mag 77:2811–2823

    Article  Google Scholar 

  • Kampf AR, Mills SJ, Hatert F, Nash BP, Dini M, Molina Donoso AA (2014) Canutite, NaMn3[AsO4][AsO3(OH)]2, a new protonated alluaudite-group mineral from the Torrecillas mine, Iquique Province, Chile. Mineral Mag 78:787–795

    Google Scholar 

  • Ketani M, Abraham F, Mentré O (1999) Channel structure in the new BiCoPO5. Comparison with BiNiPO5. Crystal structure, lone pair localization and infrared characterization. Solid State Sci 1:449–460

    Article  Google Scholar 

  • Kolitsch U, Merlino S, Holtstam D (2012) Molybdophyllite: crystal chemistry, crystal structure, OD character and modular relationships with britvinite. Mineral Mag 76:493–516

    Article  Google Scholar 

  • Krivovichev SV (ed) (2008) Minerals as Advanced Materials I. Springer, Heidelberg

    Google Scholar 

  • Krivovichev SV (ed) (2012a) Minerals as Advanced Materials II. Springer, Heidelberg

    Google Scholar 

  • Krivovichev SV (2012b) Derivation of bond-valence parameters for some cation-oxygen pairs on the basis of empirical relationships between r 0 and b. Z Kristallogr 227:575–579

    Article  Google Scholar 

  • Krivovichev SV, Vergasova LP, Filatov SK, Rybin DS, Britvin SN, Ananiev VV (2013a) Hatertite, Na2(Ca, Na)(Fe3+, Cu)2(AsO4)3, a new alluaudite-group mineral from Tolbachik fumaroles, Kamchatka peninsula, Russia. Eur J Mineral 25:683–691

    Article  Google Scholar 

  • Krivovichev SV, Mentré O, Siidra OI, Colmont M, Filatov SK (2013b) Anion-centered tetrahedra in inorganic compounds. Chem Rev 113:6459–6535

    Article  Google Scholar 

  • Krivovichev SV, Filatov SK, Vergasova LP (2013c) The crystal structure of ilinskite, NaCu5O2(SeO3)2Cl3, and review of mixed-ligand CuOmCln coordination geometries in minerals and inorganic compounds. Mineral Petrol 107:235–242

    Article  Google Scholar 

  • Labidi O, Roussel P, Porcher F, Drache M, Vannier RN, Wignacourt JP (2008a) Polymorphism in BiOXO4 compounds (X = V, P, As). Part I: Crystal structures of alpha- and beta-PbBiOVO4. J Solid State Chem 181:2260–2267

    Article  Google Scholar 

  • Labidi O, Roussel P, Porcher F, Drache M, Vannier RN, Wignacourt JP (2008b) Polymorphism in BiOXO4 compounds (X = V, P, As). Part II. PbBiOAsO4 structures and characterization of related solid solutions. J Solid State Chem 181:2268–2273

    Article  Google Scholar 

  • Majzlan J, Drahota P, Filippi M (2014) Parageneses and crystal chemistry of arsenic minerals. Rev Mineral Geochem 79:17–184

    Article  Google Scholar 

  • Mathews E, Ranjith KM, Baenitz M, Nath R (2013) Field Induced magnetic transition in low-dimensional magnets Bi(Ni, Co)PO5. Solid State Comm 154:56–59

    Article  Google Scholar 

  • Mentré O, Ketatni EM, Colmont M, Huve M, Abraham F, Petricek V (2006) Structural features of the modulated BiCu2(P0.68V0.32)O6 solid solution; 4-D treatment of x = 0.87 compound and magnetic spin-gap to gapless transition in new Cu2+ two-leg ladder systems. J Am Chem Soc 128:10857–10867

    Article  Google Scholar 

  • Mentré O, Bouree F, Rodriguez-Carvajal J, Jazouli A, Khayat N, Ketatni M (2008a) Magnetic structure and analysis of the exchange interactions in BiMO(PO4) (M = Co, Ni). J Phys Condens Matter 20:415211

    Article  Google Scholar 

  • Mentré O, Koo H-J, Whangbo MH (2008b) Investigation of the vanadyl bond ordering and analysis of the spin exchange interactions in Pb2V3O9 and Pb2As2VO9. Chem Mater 20:6929–6938

    Article  Google Scholar 

  • Nadir S, Swinnea JS, Steinfink H (1999) Crystal structure and physical properties of BiCoPO5. J Solid State Chem 148:295–301

    Article  Google Scholar 

  • Pekov IV, Levitskiy VV, Krivovichev SV, Zolotarev AA, Bryzgalov IA, Zadov AE, Chukanov NV (2012) New nickel-uranium-arsenic mineral species from the oxidation zone of the Belorechenskoye deposit, Northern Caucasus, Russia: I. Rauchite, Ni(UO2)2(AsO4)2·10H2O, a member of the autunite group. Eur J Mineral 24:913–922

    Article  Google Scholar 

  • Pekov IV, Zelenski ME, Yapaskurt VO, Polekhovsky YS, Murashko MN (2013a) Starovaite, KCu5O(VO4)3, a new mineral from fumarole sublimates of the Tolbachik volcano, Kamchatka, Russia. Eur J Mineral 25:91–96

    Article  Google Scholar 

  • Pekov IV, Zubkova NV, Zelenski ME, Yapaskurt VO, Polekhovsky Y, Fadeeva OA, Pushcharovsky DYu (2013b) Yaroshevskite, Cu9O2(VO4)4Cl2, a new mineral from the Tolbachik volcano, Kamchatka, Russia. Mineral Mag 77:107–116

    Article  Google Scholar 

  • Pekov IV, Zubkova NV, Yapaskurt VO, Belakovskiy DI, Lykova IS, Vigasina MF, Sidorov EG, Dyu P (2014a) New arsenate minerals from the Arsenatnaya fumarole, volcano, Kamchatka, Russia. I. Yurmarinite, Na7(Fe3 +, Mg, Cu)4(AsO4)6. Mineral Mag 78:905–917

    Google Scholar 

  • Pekov IV, Zubkova NV, Goettlicher J, Yapaskurt VO, Chukanov NV, Lykova IS, Belakovskiy DI, Jensen MC, Leising JF, Nikischer AJ, Pushcharovsky DYu (2014b) Whitecapsite, a new hydrous iron and trivalent antimony arsenate mineral from the White Caps mine, Nevada, USA. Eur J Mineral 26:577–587

    Google Scholar 

  • Radosavljevic I, Evans JSO, Sleight AW (1999) Synthesis and structure of bismuth copper arsenate. J Alloy Compd 284:99–103

    Article  Google Scholar 

  • Radosavljevic I, Howard JAK, Sleight AW (2000) Synthesis and structure of two new bismuth cadmium vanadates, BiCdVO5 and BiCd2VO6, and structures of BiCa2AsO6 and BiMg2PO6. Int J Inorg Mater 2:543–550

    Article  Google Scholar 

  • Roberts AC, Burns PC, Gault RA, Criddle AJ, Feinglos MN, Stirling JAR (2001) Paganoite, NiBi3+As5+O5, a new mineral from Johanngeorgenstadt, Saxony, Germany: description and crystal structure. Eur J Mineral 13:167–175

    Article  Google Scholar 

  • Shuvalov RR, Vergasova LP, Semenova TF, Filatov SK, Krivovichev SV, Siidra OI, Rudashevsky NS (2013) Prewittite, KPb1.5Cu6Zn(SeO3)2O2Cl10, a new mineral from Tolbachik Fumaroles, Kamchatka Peninsula, Russia: description and crystal structure. Am Mineral 98:463–469

    Article  Google Scholar 

  • Starova GL, Vergasova LP, Filatov SK, Britvin SN, Anan’ev VV (2012) Lammerite-β, Cu3(AsO4)2, a new mineral from fumaroles of the Great Fissure Tolbachik eruption, Kamchatka Peninsula, Russia. Geol Ore Dep 54:565–569

    Article  Google Scholar 

  • Vergasova LP, Semenova TF, Krivovichev SV, Filatov SK, Zolotarev AA, Ananiev VV (2014) Nicksobolevite, Cu7(SeO3)2O2Cl6, a new complex copper oxoselenite chloride from Tolbachik fumaroles, Kamchatka peninsula, Russia. Eur J Mineral 26:439–449

    Article  Google Scholar 

  • Xun X, Uma S, Yokochi A, Sleight AW (2002a) Synthesis and structure of BiMnPO5. J Alloys Compd 338:51–53

    Article  Google Scholar 

  • Xun X, Yokochi A, Sleight AW (2002b) Synthesis and structure of BiMnVO5 and BiMnAsO5. J Solid State Chem 168:224–228

    Article  Google Scholar 

Download references

Acknowledgments

We are grateful to Cristian Biagioni and anonymous reviewer for the useful remarks. This work was supported by the Fonds Européeen de Développement Régional (FEDER), CNRS, Région Nord Pas-de-Calais, Russian President Grant MК-3756.2014.5 (O.I.S.), SPbSU internal grant 3.38.238.2015 (K.M.S.), and Russian Foundation for Basic Research (S.V.K., Grant # 14-05-00910). Ministère de l’Education Nationale de l’Enseignement Supérieur et de la Recherche is acknowledged for funding the X-ray diffractometers. This work was carried out under the framework of the Multi-InMaDe project supported by the ANR (Grant ANR 2011-JS-08 00301).

Author information

Authors and Affiliations

  1. UCCS, UMR 8181, Université Lille Nord de France, USTL, 59655, Villeneuve d’Ascq, France

    Almaz Aliev, Michael S. Kozin, Marie Colmont & Olivier Mentré

  2. Department of Crystallography, St. Petersburg State University, University Emb. 7/9, 199034, St. Petersburg, Russia

    Michael S. Kozin, Oleg I. Siidra & Sergey V. Krivovichev

Authors
  1. Almaz Aliev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Michael S. Kozin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Marie Colmont
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Oleg I. Siidra
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Sergey V. Krivovichev
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Olivier Mentré
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Sergey V. Krivovichev.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Aliev, A., Kozin, M.S., Colmont, M. et al. Synthesis, crystal structure, high-temperature behavior and magnetic properties of CoBiO(AsO4), a Co analogue of paganoite. Phys Chem Minerals 42, 663–670 (2015). https://doi.org/10.1007/s00269-015-0752-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00269-015-0752-y

Keywords

Search

Navigation