Abstract
Phenolics’ occurrence in surface water of the Dniester river basin (West Ukraine) with the definition of the natural background is studied. The main attention is given to the Upper Dniester basin and its tributary Stryj as the parts of the Sub-Carpathian oil- and gas province with the numerous objects of oil industry. The total amount of phenolics in water is studied. Phenolics’ concentrations from the first micrograms to the first milligrams per litre have been found in the surface water of the region. The natural background is defined as 0.012 mg l−1 for the areas out of the industrial influence. The anthropogenic part of phenolics is caused mainly by oil industry. The oil-producing objects provide the main phenolics’ releases in the region, due to the low protection level of mechanical facilities as well as to breach of technological norms on the oil-extracting objects. A man-made pollution of the basin water has a regional character and the natural self-purification processes seem to be insufficient for its neutralisation on the plains in particular.
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References
Alexsandrova LN (1980) Organic matter of soils and processes of its transformation. Nauka, Leningrad (in Russian)
Autenrieth RL, Bonner JS, Akgerman A, Okaygun M, McCreary EM (1991) Biodegradation of phenolic wastes. J Hazard Mater 28:29–53
Bars Ye A (1973) Study methods of investigation of organic substances of undergroundwaters of oil- and gas-bearing regions. Nedra, Moscow (in Russian)
Bespamyatnov GP, Krotov Yu A (1985) Maximum allowable concentrations of chemical substances in environment. Gidrometeoizdat, Leningrad 2 (in Russian)
Buszewski B, Buszewska T, Szumski M, Siepak J (2003) Simultaneous determination of phenols and polyaromatic hydrocarbons isolated from environmental samples by SFE–SPE–HPLC. Chem Anal 48:13–25
Chmarzynski A, Gajek K, Buszewski B (1999) Biological treatment of gas-works sewage. Polish J Environ Stud 8(1):25–29
Dluhy M, Rybarikowa D, Bales V (1996) Phenol degradation by bacteria. Part one: isolation and characterization of bacterial strain. Polish J Environ Stud 5(2):21–26
Dluhy M, Bales V (1996) Phenol degradation by bacteria. Part two: kinetic and growth study. Polish J Environ Stud 5(4):9–15
EPA (1996) Emergency planning and community right-to-know. Ed.: EPA, office of pollution and prevention of toxics. Washington DC, pp 313
EU (2000) Commission of the European Communities: Proposal for a list of priority substances in the field of water policy. Brussels, Ed.:COM. 2000/0035
Finkel’shtejn AI, Aref’jeva RP, Volkova TA (1987) Extraction spectraphotometric analyses of low concentrations of phenols in wastewater. Khimicheskaya promyshlenost’ i promyshlenost’ po proizvodstvu mineral’nych udobrenij, Seriya Okhrana okruzhayushchej sredy i ochistka promyshlennych vybrosov, vol 3, pp 22–23 (in Russian)
Gorbaten’kij GG, Zelenin AM, Chorik FP (1990) Ecosystem of the low Dniester under the increased anthropogenic effect. Shtiitsa, Kishinev, pp 260 (in Russian)
Instruction of Ministry of Environmental Protection (1991) Natural resources and forestry of Poland from 5 of November 1991, pos. 503. Dziennik Ustaw 116:1579–1583
Jarvis SN, Straube RC, Williams ALJ, Bartlett CLR (1985) Illness associated with contamination of drinking water supplies with phenol. Br Med J 290:1800–1802
Kahru A, Maloverjan A, Sillak H, Pollumaa L (2002) The toxicity and fate of phenolic pollutants in the contaminated soils associated with the oil-shale industry. Environ Sci Pollut Res 1:27–33
Kolodij VV, Shtogryn OD (1982) Organic substances in the undergroundwaters of Crimean-Blacksea oil- and gas-bearing region and their prospect importance. Naukova dumka, Kyiv (in Russian)
Korenman Ya I, Grusdev IV, Kondratenok BM (2001) Identification and determination of chlorophenols in potable water by a kinetic gas-chromatographic method. Russ J Anal Chem 6:507–511 (in Russian)
Kovalchuk I, Mikhnoviych A (2004) Features of the discharge in the river systems of the Dniester basin and relations of its components. In: Proceedings of the 3rd international scientific-practical conference. Resources of natural waters of the carpathian region, L’viv, Ukraine, pp 94–101 (in Ukrainian)
Krajnov SR, Shvets VM (1987) Geochemistry of undergroundwaters of domestic drinking supply. Nedra, Moscow (in Russian)
Lebedynets M, Sprynskyy M, Kowalkowski T, Buszewski B (2004) State of environment in the Dniester river basin (West Ukraine). Environ Sci Pollut Res 11:279–280
Levkivskyj SS, Khil’chevskyj VK, Obodovskyj OG (2000) Total hydrology. Phitocentr, Kyiv (in Ukrainian)
Licha T, Sauter M, (2002) Use of short chained alkylphenols (SCAP) in analysis of transport behaviour of oil contaminated groundwater. J Agric Mar Sci 7(2):29–38
Lipnizki F, Hausmanns S, Ten PK, Field RW, Laufenberg G (1999) Organophilic pervaporation: prospects and performance. Chem Eng J 73:113–129
Ministry of Ecology and National Resources of Ukraine (2000) National report about state of environment of Ukraine in 1999. Vydavnytstvo Rajevskogo, Kyiv (in Ukrainian)
Ministry of Health Protection of Ukraine (1996) Potable water. Hygienic requirements for water quality for central potable water-supply (in Ukrainian)
Santos VL, Linardi VR (2001) Phenol degradation by yeasts isolated from industrial effluents. J Gen Appl Microbiol 47:213–221
Sheikheldin SY, Cardwell TJ, Cattrall RW, de Castro MDL, Koler SD (2000) Determination of phenol in water by pervaporation-flow injection analysis. Anal Chem Acta 419:9–16
Shirenko L, Krylenkova N (2003) Current state of North-West Russia lakes: phenol-oxidizing bacteria and phenol balance, Abstracts of the 5th international conference on environmental future. Zurich, Switzerland. http://www.icef.eawag.ch/poster/shirenko.pdf
Shtogryn OD (1963) Undergroundwaters of Quaternary deposits of the Subcarpathian region. Academy of Sciences of URSR, Kyiv (in Ukrainian)
Slavinskaja GV (1991) Influence of chlorination on potable water quality. Khimija i Tekhnologija vody. 11:1013–1022 (in Russian)
Southworth GR, Herbes SE, Franco PJ, Giddings JM (1985) Persistence of phenols in aquatic microcosms receiving chronic inputs of coal-derived oil. Water Air Soil Pollut 24:283–296
Stetsyuk VM (1998) Review of ecological conditions of the upper and the middle Dniester. In: The Dniester study: 10 years of public ecological expedition “Dniester”. Politychna dumka, Kyiv (in Ukrainian)
Taylor P, Larter S, Jones M, Dale J, Horstad J (1997) The effect of oil-water-rock partitioning on the occurence of alkylphenols in petroleum systems. Geochem Cosmochim Acta 9:1899–1910
Tyagi RD, Tran FT, Chowdhury AK (1993) Biodegradation of petroleum refinery wastewater in a modified rotating biological contactor with polyurethane foam attached to the disks. Water Res 27:91–99
Veeresh GS, Kumar P, Mehrotra I (2005) Treatment of phenol and cresols in upflow anaerobic sludge blanket (UASB) process: a review. Water Res 39:154–170
Zenin AA, Belousova NV (1988) Hydrogeochemical dictionary. Gidrometeoizdat, Leningrad (in Russian)
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Sprynskyy, M., Lebedynets, M., Namieśnik, J. et al. Phenolics occurrence in surface water of the Dniester river basin (West Ukraine): natural background and industrial pollution. Environ Geol 53, 67–75 (2007). https://doi.org/10.1007/s00254-006-0619-0
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DOI: https://doi.org/10.1007/s00254-006-0619-0