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Nature and profile distribution of iron and aluminum in relation to pedogenic processes in some soils developed under tropical environment in India

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Environmental Geology

Abstract

Different extractants were used to determine various forms of Fe and Al in three soil profiles developed under a tropical environment in India. The average contents of Fe and Al, extracted by different extracting reagents were found to be in descending order, as follows:

$$ {\text{Al}}_{{{\text{dith}}}} > {\text{Al}}_{{{\text{oxa}}}} > {\text{Al}}_{{{\text{pyr}}}} {\text{ and Fe}}_{{{\text{dith}}}} > {\text{Fe}}_{{{\text{oxa}}}} > {\text{Fe}}_{{{\text{pyr}}}} $$

Analysis of pyrophosphate (pyr), oxalate (oxa) and dithionate (dith) extractable Fe and Al showed that with increasing soil age, the crystalline Fe and Al oxides increased at the expense of the poorly crystalline forms. The mean content of amorphous Fe and Al, crystalline Fe and Al and their ratio values in the three different soil series estimated the degree of soil development and were found to be in the following descending order: Ghoradanga >Kanchanpur >Lachimpur. Correlation between different forms of Fe and Al and selected soil properties were examined. Multiple regression equations were formulated to show the relation among soil properties and different forms of Fe and Al.

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References

  • Agriculture Canada (1984) Analytical methods manual. In: Sheldrick BH (ed) Land Resource Research Institute, Ottawa, LLRI Contribution, pp 84–90

  • Borggard OK (1988) Phase identification by selective dissolution technique. In: Stucki SW, Goodman BA, Schwertmann U (eds) Iron in Soils and Clay Minerals. D. Reidel, Boston, MA, pp 93–98

  • Canada Soil Survey Committee, Subcommittee on Methods of Analysis (1978) Manual of soil sampling and methods of analysis. In: McKeague JA (ed) Canadian Society of Soil Science, Ottawa, On, pp 98–106

  • Chatterjee RK, Raghumohan NG (1982) Micromorphology of some typical soils occurring in a sequence of increasing drainage. Indian Agriculturist 26:19–28

    Google Scholar 

  • Chen JF, He Q (1985) Chemical distinction of oxide mineral in soil colloid. In: Hseung Y (ed) Methods of soil Colloid Research. Science Press, Beijing, pp 241 (in Chinese)

  • Dolui AK, Chakraborty N (1998) Differentiation of forms of extractable aluminum in relation to pedogenic processes in two alfisols and an entisols. Int J Trop Agric 16:257–66

    CAS  Google Scholar 

  • Dolui AK, Bera R (2001) Relation between iron forms and pedogenic processes in some alfisols of Orissa, India. Agrochimica XLV(5–6):161–170

  • Dolui AK, Mazumdar A (2003). Relation between forms of aluminium and pedogenic processes in some alfisols of Bihar and West Bengal. Crop Res. 25(1):69–77

    Google Scholar 

  • Dolui AK, Chandran P, Nayek AK (1987) Comparative studies on different forms of aluminum using various extractants in relation to pedogenic processes in soil profiles. J Indian Soc Soil Sci 35:103–08

    CAS  Google Scholar 

  • Dolui AK, Chandran P, Nayek AK (1988) Nature and profile distribution of iron in some soil series of Jalpaiguri district, West Bengal. Proc Nat Aca Sci India 58(A):1

    CAS  Google Scholar 

  • Driscoll CJ, van Breeman N, Mulder J (1985) Aluminum chemistry in a forested spodosol. Soil Sci Soc Am J 49:437–44

    CAS  Google Scholar 

  • Farmer VC, Russell JD Berrow ML (1980) Imogolite and protoimogolite allophane in spodic horizon: evidence for a mobile aluminum silicate complex in podzol formation. J Soil Sci 31:673–84

    CAS  Google Scholar 

  • Howkes HE, Webb J (1962) Geochemistry of mineral exploration. Harper and Row, New York

  • Jackson ML (1973) Soil chemical analysis. Prentice – Hall of India Pvt. Ltd., New Delhi

  • Jersak JM, McColl JG, Hetzel JF (1992) Changes in extractability of iron, aluminum and silicon and dispersibility by storage of Carlifornia forest soils. Commun Soil Sci Plant Anal 23:993–1018

    CAS  Google Scholar 

  • Kodama H, Ross GJ (1991) Iron dissolution methods used to remove and characterize inorganic compounds in soils. Soil Sci Soc Am J 55:1180–87

    CAS  Google Scholar 

  • Loveland PJ, Digby D (1984) The extraction of Fe and Al by 0.1 M pyrophosphate solutions: A comparison of some techniques. J Soil Sci 35:243

    CAS  Google Scholar 

  • Mahaney WC, Fahey BD (1988) Extractable Fe and Al in late Pleistocene and Holocene paleosols in Niwot Ridge, Colorado Front Range. Catena 15:17–26

    Article  CAS  Google Scholar 

  • Mahaney WC, Hancock, RGV, Sanmugadas K (1991) Extractable Fe-Al and geochemistry of late Pleistocene Paleosol in the Dalijia Shan, Western China. J Southeast Asian Earth Sci 6:75–82

    Article  Google Scholar 

  • McKeague JA, Day JH (1966) Dithionite and oxalate extractable Fe and Al as aids in differentiating various classes of soils. Canadian J Soil Science 46:13–22

    CAS  Google Scholar 

  • McKeague JA, Brydon JE, Miles NM (1971) Differentiation of forms of extractable iron and aluminum in soils. Soil Sci Soc Am Proc 35:33–38

    CAS  Google Scholar 

  • Mehra OP, Jackson ML (1960) Iron oxide removal from soils and clays by a dithionite citrate system buffered with sodium bicarbonate. Clays and Clay Miner 7:317–27

    Google Scholar 

  • Norrish K, Rossier H (1983) Mineral phosphate. In: Soils – An Australian Viewpoint. CSIRO Melbourne/Academic Press, London, pp 265–361

  • Page F, DeKimpe CR (1989) Dissolution decomposes ferrugineux et alumineux des horizons B podzoliques de sols due Quebec par le dithionite-citrate-carbonate. I’oxalate le pyrophosphate et le tetraborate. Can J Soil Sci 69:451–59

    CAS  Google Scholar 

  • Parfitt, RL, Childs CW (1988) Estimation of forms of Fe and Al: A review and analysis of contrasting soils by dissolution and Moessbauer methods. Aust J Soil Res 26:121–44

    CAS  Google Scholar 

  • Parker CA, Goddard AP (1950) The reaction of Al ions with Alizarin –3-sulphonate with particular reference to the effect of addition of calcium ions. Anal Chem Acta 4:517–35

    Article  CAS  Google Scholar 

  • U.S. Department of Agriculture, Soil Survey Staff (1996) Keys to soil taxonomy, 7th edn. Washington, DC

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Bera, R., Seal, A., Banerjee, M. et al. Nature and profile distribution of iron and aluminum in relation to pedogenic processes in some soils developed under tropical environment in India. Env Geol 47, 241–245 (2005). https://doi.org/10.1007/s00254-004-1149-2

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