Abstract
When a steam–ethanol vapor mixture condenses on a vertical flat plate, the form of the condensate film changes and many drops are created. This non-film condensation is called pseudo-dropwise or Marangoni condensation. This paper aims to study the main influencing factors on the Marangoni condensation of steam–ethanol vapor.The factors include the ethanol concentration, vapor pressure, vapor velocity and vapor-to-surface temperature difference. The experiments show that the heat transfer coefficient has a maximum value of approximately 42 kW/m2 K when the ethanol concentration is 1%. At the low concentrations of 0.5, 1, 5.1 and 9.8%, the condensation heat transfer is greater than for pure steam. In addition, the heat transfer for all vapor mixtures increases with both the rise of vapor pressure and vapor velocity.
Similar content being viewed by others
Abbreviations
- A :
-
area (m2)
- c :
-
ethanol mass fraction (mass %)
- F :
-
enhancement ratio of heat transfer
- h :
-
heat transfer coefficient (kW/m2 K)
- M :
-
molar mass (kg/mol)
- \({{\mathop M\limits^ \bullet}}\) :
-
mass flow rate (kg/s)
- \({{\mathop {M_{\rm V}}\limits^ \bullet}}\) :
-
mass flow rate of vapor \({{\mathop M\limits^ \bullet}_{\rm V} = v A_{{\sec}} \rho _{V}}\)
- \({{\mathop {M_{\rm L}}\limits^ \bullet}}\) :
-
mass flow rate of liquid \({{\mathop M \limits^ \bullet}_{{\rm L}} = q A_{{\rm sur}} /r}\)
- P :
-
pressure (kPa)
- q :
-
heat flux (kW/m2)
- r :
-
latent heat (kJ/kg)
- R :
-
thermal resistance (m2 K/kW)
- T :
-
temperature (K)
- \({{\mathop {T_{\rm {L}}}\limits^{\_\_}}}\) :
-
average temperature of condensation liquid \({{\mathop {T_{\rm {L}}}\limits^{\_\_}} = (T_{\rm {V}} + T_{\rm {{sur}}})/2}\)
- v :
-
velocity (m/s)
- x :
-
liquid mole fraction
- y :
-
vapor mole fraction
- δ:
-
thickness of block and distance between two thermocouples in block (m)
- λ:
-
heat conductivity (kW/mK)
- ν:
-
kinematic viscosity (m2/s)
- ρ:
-
density (kg/m3)
- ρV mix :
-
density of vapor mixture ρ mixV = ρ eV c + ρ sV (1 − c)
- σ:
-
surface tension, interfacial tension (N/m)
- avg:
-
average
- diff:
-
diffusion layer
- e:
-
ethanol
- w:
-
water
- V:
-
vapor
- L:
-
liquid
- sur:
-
surface
- i:
-
interfacial
- mix:
-
mixture
- sat:
-
saturation
- sec:
-
cross section
References
Scriven LE, Sternling CV (1960) The Marangoni effects. Nature 187:186–188
Mirkovich VV, Missen R W (1961) Non-Filmwise Condensation of Binary Vapors of Miscible Liquids. Can J Chem Eng 39:86–87
Mirkovich VV, Missen RW (1963) A study of the condensation of binary vapors of miscible liquids. Part 2: heat transfer coefficients for filmwise and non-filmwise condensation. Can J Chem Eng 41:73–78
Ford JD, Missen RW (1968) On the conditions for stability of falling films subject to surface tension disturbances; the condensation of binary vapors. Can J Chem Eng 48:309–312
Fujii T, Koyama S (1989) Gravity controlled condensation of an ethanol and water mixture on a horizontal tube. Trans JSME Ser B 55(509):210–217
Hijikata K, Nakabeppu O, Fukasaku Y (1992) Condensation characteristics of a water–ethanol binaryvapor mixture. Proc 29th Jpn Heat Transf Symp 742–743
Hijikata K, Fukasaku Y, Nakabeppu O (1996) Theoretical and experimental studies on the pseudo-dropwise condensation of a binary vapor mixture. J Heat Transfer 118:140–147
Utaka Y, Wang Shixue (2004) Characteristic curves and the promotion effect of ethanol addition on steam condensation heat transfer. Int J Heat Mass Transf 47:4507–4516
Wang Shixue, Utaka Y (2004) An effect of non-condensable gas mass fraction on condensation heat transfer for steam–ethanol vapor mixture. JSME Int J Ser B 47(2):162–167
Morrison JNA, Deans J (1997) Augmentation of steam condensation heat transfer by addition of ammonia. Int J Heat Mass Transf 40(4):765–772
Philpott C, Deans J (2004) The condensation of ammonia–water mixtures in a horizontal shell and tube condenser. J Heat Transf 126:527–534
Kim KJ, Lefsaker AM, Razani A, Stone A (2001) The effective use of heat transfer additives for steam condensation. Appl Therm Eng 21:1863–1874
He Yangpeng, Yan Junjie et al (2004) Research on Marangoni condensation heat transfer for water and ethanol mixture vapor. Chin J Eng Thermophys 25(1):77–80
Claudio AF, Valderrama JO (2004) Phase equilibrium modeling in binary mixtures found in wine and must distillation. J Food Eng 65:577–583
Fredenlund Aa, Jones R L, Prausnitz JM (1975) Group contribution estimation of activity coefficients in non-ideal liquid mixtures. AIChE J 27(5):1086–1099
Gmehling J (1978) Vapor–liquid equilibrium data collection: organic hydroxy compounds: alcohol and phenols. Chemistry data series, 1, Part 2a, Frankfurt
Moffat RJ (1982) Contributions to the theory of single-sample uncertainty analysis. J Fluids Eng Trans ASME 104(2):250–260
Acknowldgments
This project has been supported by National Natural Science Foundation of China through grants No.50476048 and No.50323001.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Yan, J., Yang, Y., Hu , S. et al. Effects of vapor pressure/velocity and concentration on condensation heat transfer for steam–ethanol vapor mixture. Heat Mass Transfer 44, 51–60 (2007). https://doi.org/10.1007/s00231-006-0216-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00231-006-0216-5