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The influence of thermal-hydro-mechanical processing on chemical characterization of Tsuga heterophylla

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Abstract

Viscoelastic thermal compression (VTC) is a type of thermal-hydro-mechanical (THM) processing that requires only a short processing time. THM processing causes some chemical transformations, the nature and extent of hydro-thermolysis depends on the special treatment conditions and the chemical nature of wood species. In the present study, the chemical transformations of the cell wall components and wood extractives during VTC treatment were investigated, and correlation between chemical characterizations and observed property changes was analyzed. For this purpose, the content of extractives and pH values were determined, and FTIR analysis was performed on extractable substances, extract-free wood, holocellulose, α-cellulose and lignin. Two temperatures and two steam exposure times were adopted to determine the influence of processing conditions on chemical characterization of Tsuga heterophylla. The results revealed that THM treatment caused a series of chemical reactions in extractives. Treatment temperature and conditioning time have significant influence on chemical changes of extractives. For all of the VTC treatments used in this study, no significant changes occurred in the lignin and α-cellulose components. The only significant chemical changes occurred in the hemicelluloses, which were primarily reduction of carbonyl and acetyl functional groups. This study also confirmed that the chemical transformation of wood correlates with property changes of VTC wood.

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Acknowledgments

The authors are grateful for the funding support from the State Scholarship Fund from China Scholarship Council (CSC) and Oregon Built Environment and Sustainable Technology Center, Oregon State University (Corvallis, OR, USA). Technical assistance from Chuan Li, Darrell Lowe, Jesse Paris and Adam Scouse is appreciated.

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Authors and Affiliations

  1. College of Mechanical and Electronic Engineering, Northwest A&F University, Yangling, 712100, China

    Hongling Liu, Jin Shang & Kangquan Guo

  2. Department of Wood Science and Engineering, Oregon State University, Corvallis, OR, 97331, USA

    Hongling Liu

  3. College of Food Science and Engineering, Northwest A&F University, Yangling, 712100, China

    Xianqing Chen

  4. Jeld-Wen Chair of Wood-based Composites Science, Department of Wood Science and Engineering, Oregon State University, Corvallis, OR, 97331, USA

    Frederick A. Kamke

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  1. Hongling Liu
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  2. Jin Shang
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  4. Frederick A. Kamke
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  5. Kangquan Guo
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Correspondence to Kangquan Guo.

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Liu, H., Shang, J., Chen, X. et al. The influence of thermal-hydro-mechanical processing on chemical characterization of Tsuga heterophylla . Wood Sci Technol 48, 373–392 (2014). https://doi.org/10.1007/s00226-013-0608-x

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