Skip to main content
Log in

Effect of surface treatments on natural cork: surface energy, adhesion, and acoustic insulation

  • Original
  • Published:
Wood Science and Technology Aims and scope Submit manuscript

Abstract

Cork is one of the finest natural materials with high acoustic insulation properties due to its porous structure. In addition, cork presents high water resistance due to its hydrophobic nature. In many applications, cork panels need to be bonded to other materials for manufacturing composite materials or agglomerated cork sheets. In this case, its lack of wettability becomes an important disadvantage. This paper aims to improve the wettability of cork by silanization, atmospheric plasma treatment, and vacuum plasma treatment. The processing conditions of the three treatments were optimized. The surface characterization was performed by surface energy, roughness, and attenuated total reflectance-Fourier transform infrared spectroscopy measurements. Pull-off adherence and peel tests were carried out to evaluate the performance of the treatments with an epoxy adhesive. Plasma treatment of cork plates could be a useful tool to enhance adhesion properties in the manufacturing process of cork sandwich panels or other applications where it could be joined to any material.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  • Abdallah FB, Cheikh RB, Baklouti M, Denchev Z, Cunha AM (2010) Effect of surface treatment in cork reinforced composites. J Polym Res 17:519–528

    Article  Google Scholar 

  • Abenojar J, Torregrosa-Coque R, Martínez MA, Martín-Martínez JM (2009) Surface modifications of polycarbonate (PC) and acrylonitrile butadiene styrene (ABS) copolymer by treatment with atmospheric plasma. Surf Coat Technol 203:2173–2180

    Article  CAS  Google Scholar 

  • Anjos O, Pereira H, Rosa ME (2011) Tensile properties of cork in axial stress and influence of porosity, density, quality and radial position in the plank. Eur J Wood Wood Prod 69:85–91

    Article  Google Scholar 

  • Arashiro EY, Demarquette NR (1999) Use of the pendant drop method to measure interfacial tension between molten polymers. Mater Res 2:23–32

    Article  CAS  Google Scholar 

  • Awaja F, Gilbert M, Kelly G, Fox B, Pigram PJ (2009) Adhesion of polymers. Prog Polym Sci 34:948–968

    Article  CAS  Google Scholar 

  • Barberis A, Dettori S, Filiggheddu MR (2003) Management problems in Mediterranean cork oak forests: post-fire recovery. J Arid Environ 54:565–569

    Article  Google Scholar 

  • Barbosa AQ, da Silva LFM, Öchsner A, Abenojar J, del Real JC (2012) Influence of the size and amount of cork particles on the impact toughness of a structural adhesive. J Adhes 88:452–470

    Article  CAS  Google Scholar 

  • Brochier Salon MC, Abdelmouleh M, Boufi S, Belgacem NM, Gandini A (2005) Silane adsorption onto cellulose fibers: hydrolysis and condensation reactions. J Colloid Interface Sci 289:249–261

    Article  Google Scholar 

  • Castro O, Silva JM, Devezas T, Silva A, Gil L (2010) Cork agglomerates as an ideal core material in lightweight structures. Mater Des 31:425–432

    Article  CAS  Google Scholar 

  • Chiang CH, Ishida H, Koenig JL (1980) The structure of γ-aminopropyltriethoxysilane on glass surfaces. J Colloid Interface Sci 74:396–404

    Article  CAS  Google Scholar 

  • Costa A, Pereira H, Oliveira A (2003) Variability of radial growth in cork oak adult trees under cork production. Forest Ecol Manag 175:239–246

    Article  Google Scholar 

  • Cumbre F, Lopes F, Pereira H (2000) The effect of water boiling on annual ring width and porosity of cork. Wood Fiber Sci 32:125–133

    CAS  Google Scholar 

  • del Real JC, Cano de Santayana M, Abenojar J, Martínez MA (2006) Adhesive bonding of aluminium with structural acrylic adhesives: durability in wet environments. J Adhes Sci Technol 20:1801–1818

    Article  Google Scholar 

  • del Real JC, Ballesteros Y, Chamochin R, Abenojar J, Molisani L (2011) Influence of surface preparation on the fracture behavior of acrylic adhesive/CFRP composite joints. J Adhes 87:366–381

    Article  Google Scholar 

  • Díaz-Parralejo A, Díaz-Díez MA, Macías-García A, de la Rosa-Blanco P, Gómez Serrano V (2003) Bending strength of black and composite agglomerates of cork. Mater Lett 57:4004–4008

    Article  Google Scholar 

  • Encinas N, Díaz-Benito B, Abenojar J, Martínez MA (2010) Extreme durability of wettability changes on polyolefin surfaces by atmospheric pressure plasma torch. Surf Coat Technol 205:396–402

    Article  CAS  Google Scholar 

  • Encinas N, Abenojar J, Martínez MA (2012a) Development of improved polypropylene adhesive bonding by abrasion and atmospheric plasma surface modifications. Int J Adhes Adhes 33:1–6

    Article  CAS  Google Scholar 

  • Encinas N, Dillingham RG, Oakley BR, Abenojar J, Martínez MA, Pantoja M (2012b) Atmospheric pressure plasma hydrophilic modification of a silicone surface. J Adhes 88:321–336

    Article  CAS  Google Scholar 

  • Farag MM (2008) Quantitative methods of materials substitution: application to automotive components. Mater Des 29:374–378

    Article  CAS  Google Scholar 

  • Gibson LJ, Ashby MF (1997) Cellular solids—structure and properties, 2nd edn. Cambridge University Press, Cambridge

    Google Scholar 

  • Gibson LJ, Easterling KE, Ashby MF (1981) The structure and mechanics of cork. Proc R Soc Lond A 377:99–117

    Article  Google Scholar 

  • Gil L (1998) Cortiça: produção, tecnologia e aplicação (Cork: production, technology and application). INETI, Lisboa

    Google Scholar 

  • González-Adrados JR, García-Vallejo MC, Cáceres-Esteban MJ, García de Ceca JL, González-Hernández F, Calvo-Haro R (2012) Control by ATR-FTIR of surface treatment of cork stoppers and its effect on their mechanical performance. Wood Sci Technol 46:349–360

    Article  Google Scholar 

  • Graefe S, Leuschner Ch, Coners H, Hertel D (2011) Root functioning in tropical high-elevation forests: environmental vs. biological control of root water absorption. Environ Exp Bot 71:329–336

    Google Scholar 

  • Kulinich SA, Farzaneh M (2004) Hydrophobic properties of surfaces coated with fluoroalkylsiloxane and alkylsiloxane monolayers. Surf Sci 573:379–390

    Article  CAS  Google Scholar 

  • Lieberman MA, Lichtenberg AJ (1994) Principles of plasma discharges and materials processing. Wiley, New York

    Google Scholar 

  • Moreira RAS, de Melo FJQ, Dias Rodrigues JF (2010) Static and dynamic characterization of composition cork for sandwich beam cores. J Mater Sci 45:3350–3366

    Article  CAS  Google Scholar 

  • Nierop KGJ (2001) Temporal and vertical organic matter differentiation along a vegetation succession as revealed by pyrolysis and thermally assisted hydrolysis and methylation. J Anal Appl Pyrolysis 61:111–132

    Article  CAS  Google Scholar 

  • Novák I, Popelka A, Krupa I, Chodák I, Janigová I, Nedelčev T, Špírková M, Kleinová A (2012) High-density polyethylene functionalized by cold plasma and silanes. Vacuum 86:2089–2094

    Article  Google Scholar 

  • Owens DK, Wendt RC (1969) Estimation of the surface free energy of polymers. J Appl Polym Sci 13:1741–1746

    Article  CAS  Google Scholar 

  • Pantoja M, Martínez MA, Abenojar J, Velasco F, del Real JC (2010) Structural and mechanical characterization of γ-methacryloxypropyltrimethoxysilane (MPS) on Zn-electrocoated steel. J Adhes Sci Technol 24:1885–1901

    Article  CAS  Google Scholar 

  • Pereira H (1984) Produção e utilização da cortiça. Situação actual e perspectivas de desenvolvimento (Production and use of cork. Real state and future developments). Boletim do Instituto dos Produtos Florestais—Cortiça 545:99–112

  • Pereira H (1988) O que é a cortiça (What is cork?). Boletim do Instituto dos Produtos Florestais—Cortiça 600:15–18

  • Pereira H (2007) Cork: biology, production and uses. Elsevier, Amsterdam

    Google Scholar 

  • Plueddemann EP (1991) Silane coupling agents, 2nd edn. Plenum Press, New York

    Book  Google Scholar 

  • Ponte-e-Sousa JCA de CC da, Neto-Vaz AM (2011) Cork and metals: a review. Wood Sci Technol 45:183–202

    Article  Google Scholar 

  • Pretsch E, Bühlmann P, Affolter C, Herrera A, Martínez R (2001) Determinación estructural de compuestos orgánicos (structure determination of organic compounds). Springer, Barcelona

    Google Scholar 

  • Puomi P, Fagerholm H (2001) Characterization of hot-dip galvanized (HDG) steel treated with bis-1,2-(triethoxysilyl)ethane and γ-aminopropyltriethoxysilane. J Adhes Sci Technol 15:869–888

    Article  CAS  Google Scholar 

  • Reis L, Silva A (2009) Mechanical behaviour of sandwich structures using natural cork agglomerates as core materials. J Sandw Struct Mater 11:487–500

    Article  Google Scholar 

  • Reis PNB, Ferreira JAM, Silva PAA (2011) Mechanical behaviour of composites filled by agro-waste materials. Fibers Polym 12:240–246

    Article  CAS  Google Scholar 

  • Rosa ME, Fortes MA (1991) Deformation and fracture of cork in tension. J Mater Sci 26:341–348

    Article  Google Scholar 

  • Santos JS, Rodrigues JD, Moreira RAS (2010) Application of cork compounds in sandwich structures for vibration damping. J Sandw Struct Mater 12:495–515

    Article  Google Scholar 

  • Silva SP, Sabino MA, Fernandes EM, Correlo VM, Boesel LF, Reis RL (2005) Cork: properties, capabilities and applications. Int Mater Rev 50:345–365

    Article  CAS  Google Scholar 

  • Stuart B (2004) Infrared spectroscopy: fundamentals and applications. Wiley, Hoboken, p 224

    Book  Google Scholar 

  • Svorcík V, Kolárová K, Slepicka P, Machová A, Novotná M, Hnatowicz V (2006) Modification of surface properties of high and low density polyethylene by Ar plasma discharge. Polym Degrad Stab 91:1219–1225

    Article  Google Scholar 

  • Tender C, Txier Ch, Tristant P, Desmaison J, Leprince P (2006) Atmospheric pressure plasmas: a review. Spectrochim Acta B 61:2–30

    Article  Google Scholar 

  • Tzur A (1986) Multi-layer intumescent-ablator endothermic fire retardant compositions. U.S. Pat 4632865

  • Van Ooij WJ, Zhu D, Stacy M, Seth A, Mugada T, Gandhi J, Puomi P (2005) Corrosion protection properties of organofunctional silanes—an overview. Tsinghua Sci Technol 10:639–664

    Article  Google Scholar 

  • Xie Y, Hill CAS, Xiao Z, Militz H, Mai C (2010) Silane coupling agents used for natural fiber/polymer composites: a review. Compos Part A Appl Sci 41:806–819

    Article  Google Scholar 

  • Yuan W, Van Ooij WJ (1997) Characterization of organofunctional silane films on zinc substrates. J Colloid Interface Sci 185:197–209

    Article  CAS  PubMed  Google Scholar 

  • Zabalza Bribián I, Valero Capilla A, Aranda Usón A (2011) Life cycle assessment of building materials: comparative analysis of energy and environmental impacts and evaluation of the eco-efficiency improvement potential. Build Environ 46:1133–1140

    Article  Google Scholar 

Download references

Acknowledgments

The authors wish to acknowledge financial support by the Portuguese Foundation for Science and Technology (through project PTDC/EME-TME/098752/2008) and the Spanish Ministry of Science and Innovation (through project MAT2011-29182-C02-02).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to J. Abenojar.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Abenojar, J., Barbosa, A.Q., Ballesteros, Y. et al. Effect of surface treatments on natural cork: surface energy, adhesion, and acoustic insulation. Wood Sci Technol 48, 207–224 (2014). https://doi.org/10.1007/s00226-013-0599-7

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00226-013-0599-7

Keywords

Navigation