Abstract
Different Fourier transform infrared microspectroscopic techniques, using attenuated total reflection (ATR) mode and single-element mercury–cadmium–telluride (MCT) detector (mapping) or multielement MCT detector (raster scanning), are compared with each other for the characterisation of inorganic compounds and organic substances in paint cross sections. All measurements have been performed on paint cross sections embedded in potassium bromide, a transparent salt in the mid-infrared region, in order to better identify the organic materials without the interference of the usual embedding resin. The limitations and advantages of the different techniques are presented in terms of spatial resolution, data quality and chemical information achieved. For all techniques, the chemical information obtained is found to be nearly identical. However, ATR mapping performed with a recently developed instrumentation shows the best results in terms of spectral quality and spatial resolution. In fact, thin organic layers (∼10 µm) have been not only identified but also accurately located. This paper also highlights the recent introduction of multielement detectors, which may represent a good compromise between mapping and imaging systems.
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References
Matteini M, Moles A (2003) Scienza e restauro, Metodi di indagine. Nardini Editore, Florence
Pinna D, Galleotti M, Mazzeo R (2009) Scientific examination for the investigation of paintings: a handbook for conservators-restorers. CentroDi, Firenze
Cotte M, Welcomme E, Sol VA, Salom M, Menu M, Walter P, Susini J (2007) Anal Chem 79:6988–6994
Keune K, Boon JJ (2004) Anal Chem 76:1374–1385
Bottiroli G, Gallone A, Masala B (2005) Bollettino d'arte volume speciale (Giotto nella Cappella degli Scrovegni), pp 83–105
Van’t Hul-Ehrnreich EH (1970) Stud Conserv 15:175–182
Baker MT, Von Endt DW (1988) Mater Issues Art Archaeol 123:71–76
Gillard RD, Hardman SM, Thomas RG, Watkinson DE (1994) Stud Conserv 39:187–192
Derrick MR, Stulik DC, Landry JM (1999) Infrared spectroscopy in conservation science. The Getty Conservation Institute, Los Angeles
Pilc J, White R (1995) Natl Gallery Tech Bull 16:73–84
Langley A, Burnstock A (1999) Proceedings of the 12th Triennial Meeting of ICOM Committee for Conservation. James & James, London
Reffner JA, Martoglio PA, Williams GP (1995) Rev Sci Instrum 66:1298–1302
Dumas P, Miller L (2003) Vib Spectrosc 32:3–21
Mazzeo R, Joseph E, Prati S, Millemaggi A (2007) Anal Chim Acta 599:107–117
Reffner JA, Martoglio PA (1995) In: Humecki HJ (ed) Practical guide to infrared microspectroscopy. Marcel Dekker, New York
Lewis LL, Sommer AJ (2000) Appl Spectrosc 54:324–330
Lewis LL, Sommer AJ (1999) Appl Spectrosc 53:375–380
Katon JE (1996) Micron 27:303–314
Bhargava R, Levin IW (2005) Spectrochemical analysis using infrared multichannel detector. Blackwell, Oxford
Treado PJ, Morris MD (1993) In: Morris MD (ed) Microscopic and spectroscopic imaging of the chemical state. Marcel Dekker, New York
Krishnan K, Powell JR, Hill SL (1995) In: Humecki HJ (ed) Practical guide to infrared microspectroscopy. Marcel Dekker, New York
Hartcock MA, Atkin SC (1988) In: Messerschmidt RG (ed) Infrared microspectroscopy. Theory and applications. Marcel Dekker, New York
Bhargava R, Wall BG, Koenig JL (2000) Appl Spectrosc 54:470–479
Ebizuka N, Wasaki M, Kobayashi Y, Sato S (1995) Appl Opt 34:7899–7906
Lewis EN, Treado PJ, Reeder RC, Story GM, Dowrey AE, Marco C, Levin IW (1995) Anal Chem 67:3377–3381
Burka EM, Curbelo R (2000) US patent 6141100
Chan KLA, Kazarian SG, Mavraki A, Williams DR (2005) Appl Spectrosc 59:149–155
Ricci C, Bloxham S, Kazarian SG (2007) J Cult Herit 8:387–395
Spring M, Ricci C, Peggie DA, Kazarian SG (2008) Anal Bioanal Chem 392:37–45
Cotte M, Checroun E, Mazel V, Solé VA, Richardin P, Taniguchi Y, Walter P, Susini J (2009) e-PS 6:1–9
Kazarian SG, Chan KLA (2006) Biochim Biophys Acta 1758:858–867
Fredericks P, Rintoul L, Coates J (2004) chap No. 7. In: Cazes J, Ewing GW (eds) Ewing’s analytical instrumentation handbook. CRS Press, Boca Raton
Levin IW, Bhargava R (2005) Annu Rev Phys Chem 56:429–474
van der Weerd J, Heeren RMA, Boon JJ (2004) Stud Conserv 49:193–210
van Loon A, Keune K, Boon JJ (2005) In: Art’05—8th International Conference on the Non destructive Investigations and Microanalysis for the Diagnostic and Conservation of the Cultural and Environmental Heritage, Lecce
Lins A, Giannuzzi LA, Stevie FA, Price B, Tucker M, Gutman N (2001) MRS Proc 712:113–118
Boon JJ, Asahina S (2006) Microsc Microanal 12:1322–1323
Mazel V, Richardin P, Debois D, Touboul D, Cotte M, Brunelle A, Walter P, Laprévote O (2007) Anal Chem 79:9253–9260
Bruni S, Cariati F, Casadio F, Toniolo L (1999) Vib Spectrosc 20:15–25
van der Weerd J, Brammer H, Boon JJ, Heeren RMA (2002) Appl Spectrosc 56:276–283
Zieba-Palus J (1999) J Trace Microprobe Tech 17:299–308
Cotte M, Susini J, Solé VA, Taniguchi Y, Chillida J, Checroun E, Walter P (2008) J Anal At Spectrom 23:820–828
Gettens RJ, Kuhn H, Chase WT (1993) In: Roy A (ed) Artist's pigments: a handbook of their history and characteristics, vol 2. Oxford University Press, Oxford
Welcomme E, Walter P, Van Elslande E, Tsoucaris G (2006) Appl Phys A Mater Sci Process 83:551–556
Craddock PT (1996) In: Turner JS (ed) The dictionary of art. Grove's Dictionaries, New York
Lluveras A, Boularand S, Roqué J, Cotte M, Giráldez P, Vendrell-Saz M (2008) Appl Phys A 90:23–33
Thompson DV Jr (1954) Il libro dell’arte, the craftsman’s handbook of Cennino d’Andrea Cennini. Dover, New York
Tintori L (1982) Burlington Mag 124:94–95
Cesareo R, Castellano A, Buccolieri G, Quarta S, Marabelli M, Santopadre P (2002) In: Van Grieken R, Janssens K, Van't dack L, Meersman G (eds) Art’02—7th International Conference on Non-destructive Testings and Microanalysis for the Diagnostics and Conservation of the Cultural and Environmental Heritage, Antwerp
Cesareo R, Castellano A, Buccolieri G, Quarta S, Marabelli M, Santopadre P (2004) Il Giornale delle Prove non distruttive Monitoraggio Diagnostica 3:66–72
Cesareo R, Castellano A, Buccolieri G, Quarta S, Marabelli M, Santopadre P, Gigante E, Ridolfi S (2005) In: van Grieken R, Janssens K (eds) Cultural heritage conservation and environmental impact assessment by non-destructive testing and micro-analysis. A.A. Balkema, London
Marabelli M, Santopadre P (2005) Bollettino d'arte volume speciale (Giotto nella Cappella degli Scrovegni): 121–144
Gettens RJ, Stout GL (1966) Painting materials. A short encyclopedia. Dover, New York
Acknowledgment
This research has been partially carried out with the support of the European Union, within the VI Framework Programme (Contract: EU-ARTECH, RII3-CT-2004-506171). The authors also acknowledge the European Synchrotron Radiation Facility for providing synchrotron radiation facilities and would like to thank Dr. M. Cotte for assistance in using beamline ID21.
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Joseph, E., Prati, S., Sciutto, G. et al. Performance evaluation of mapping and linear imaging FTIR microspectroscopy for the characterisation of paint cross sections. Anal Bioanal Chem 396, 899–910 (2010). https://doi.org/10.1007/s00216-009-3269-8
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DOI: https://doi.org/10.1007/s00216-009-3269-8