Abstract
When analytes containing color are irradiated with a pulsed UV laser in the ion source of a mass spectrometer, molecules such as dyes or pigments absorb energy, resulting in their desorption and ionization. This method, laser desorption mass spectrometry (LDMS), has been used successfully to analyze colorants of forensic interest in a wide variety of materials. Here, we present and interpret the most complex of such spectra obtained to date from a sample of fingernail polish. Interpretation of the spectrum provides a unique opportunity to characterize the laser desorption mass spectra of some unexpected inorganic materials found in cosmetics, such as “broken glass”, cyanide compounds, and heavy metals. Also, the possibility of a useful forensic database of LDMS spectra of fingernail polishes is considered.
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Acknowledgments
The authors thank the National Institute of Justice for providing financial support for this work. Work presented here was supported under Award 2005-IJ-CX-K064 from the Office of Justice Programs, National Institute of Justice, Department of Justice. Points of view in this document are those of the authors and do not necessarily represent the official position of the U.S. Department of Justice.
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O’Neill, E., Harrington, D. & Allison, J. Interpretation of laser desorption mass spectra of unexpected inorganic species found in a cosmetic sample of forensic interest: fingernail polish. Anal Bioanal Chem 394, 2029–2038 (2009). https://doi.org/10.1007/s00216-009-2760-6
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DOI: https://doi.org/10.1007/s00216-009-2760-6