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Diagnostic Raman spectroscopy for the forensic detection of biomaterials and the preservation of cultural heritage

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Abstract

This paper reviews the contributions of analytical Raman spectroscopy to the non-destructive characterisation of biological materials of relevance to forensic science investigations, including the sourcing of resins and the identification of the biodegradation of art and archaeological artefacts. The advantages of Raman spectroscopy for non-destructive analysis are well-appreciated; however, the ability to record molecular information about organic and inorganic species present in a heterogeneous specimen at the same time, the insensitivity of the Raman scattering process to water and hydroxyl groups, which removes the necessity for sample desiccation, and the ease of illumination for samples of very small and very large sizes and unusual shapes are also apparent. Several examples are used to illustrate the application of Raman spectroscopic techniques to the characterisation of forensic biomaterials and for the preservation of cultural heritage through case studies in the following areas: wall-paintings and rock art, human and animal tissues and skeletal remains, fabrics, resins and ivories.

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References

  1. Edwards HGM, Chalmers JM (eds) (2005) Raman spectroscopy in art history and archaeology. Royal Society of Chemistry, London, UK

  2. Edwards HGM (1999) In: Lindon JC, Tranter GE, Holmes JL (eds) Encyclopaedia of spectroscopy and spectrometry. Academic, London, UK, pp 2–17

  3. Ciliberto E, Spoto G (eds) (2004) Modern analytical methods in art and archaeology (Chemical Analysis Series). Wiley, Chichester, UK

  4. Edwards HGM (2004) Analyst 129:870–879

    CAS  PubMed  Google Scholar 

  5. Edwards HGM (2004) In: Pye K, Croft D (eds) Forensic geoscience: principles, techniques and applications (Geological Society Special Publication 232). Geological Society of London, Bath, UK, pp 159–170

  6. Ellery A, Wynn-Williams DD, Parnell J, Edwards HGM, Dickensheets D (2004) J Raman Spectrosc 35:441–457

    Article  CAS  Google Scholar 

  7. Edwards HGM (2004) Orig Life Evol Biosph 34:3–11

    CAS  PubMed  Google Scholar 

  8. Edwards HGM, Newton EM, Dickensheets DL, Williams DD (2003) Spectrochim Acta A 59:2277–2290

    Google Scholar 

  9. Day JS, Edwards HGM, Dobrowski SA, Voice AM (2004) Spectrochim Acta A 60:563–568

    Google Scholar 

  10. Day JS, Edwards HGM, Dobrowski SA, Voice AM (2004) Spectrochim Acta A 60:1725–1730

    Google Scholar 

  11. Davy H (1815) Philos Trans R Soc Lond 105:97–114

    Google Scholar 

  12. David AR (1978) Mysteries of the mummies: the story of the Manchester University investigations. Book Club Associates, London

    Google Scholar 

  13. Eccles H, Rackham B (1922) Analysed specimens of Egyptian porcelain. Victoria and Albert Museum, London

    Google Scholar 

  14. Jorge Villar SE, Edwards HGM (2004) Vib Spectrosc (accepted for publication)

  15. Jorge Villar SE, Edwards HGM (2004) Int J Astrobiol 3:165–171

    Google Scholar 

  16. Petersen S, Faurskov Nielsen O, Christensen DH, Edwards HGM, Farwell DW, David AR, Lambert P, Hart Hansen JP, Wulf HC (2003) J Raman Spectrosc 34:375–339

    CAS  Google Scholar 

  17. Edwards HGM, Wilson AS, Farwell DW, Janaway RC (1999) J Raman Spectrosc 30:378–383

    Google Scholar 

  18. Edwards HGM, Hassan NFN, Wilson AS (2004) Analyst 129:956–962

    CAS  PubMed  Google Scholar 

  19. Edwards HGM, Farwell DW, Heron CP, Croft H, David AR (1999) J Raman Spectrosc 30:139–146

    CAS  Google Scholar 

  20. de Faria DLA, Edwards HGM, Afonso MC, Brody RH, Morais JL (2004) Spectrochim Acta A 60:1505–1513

    Google Scholar 

  21. Edwards HGM, Farwell DW, de Faria DLA, Monteiro AMF, Afonso MC, de Blasis P, Eggers S (2001) J Raman Spectrosc 32:17–22

    CAS  Google Scholar 

  22. Edwards HGM, de Oliveria LFC, Prendergast HDV (2004) Analyst 129:134–138

    CAS  PubMed  Google Scholar 

  23. Edwards HGM, Sibley MG, Derham B, Heron CB (2004) J Raman Spectrosc 35:746–753

    CAS  Google Scholar 

  24. Edwards HGM (2002) Spectroscopy 17:16–40

    CAS  Google Scholar 

  25. Edwards HGM, Farwell DW, Rull Perez F, Villar SEJ (1999) J Raman Spectrosc 30:307–312

    Google Scholar 

  26. Newton EM, Farwell DW, Edwards HGM (1999) Analyst 124:1323–1326

    Article  Google Scholar 

  27. Clark RJH (1995) Chem Soc Rev 24:187

    CAS  Google Scholar 

  28. Burgio L, Clark RJH (2000) Spectrochim Acta A 57:1491

    Google Scholar 

  29. Bouchard M, Smith DC (2005) In: Edwards HGM, Chalmers JM (eds) Raman spectroscopy in archaeology and art history. Royal Society of Chemistry, Cambridge

  30. Edwards HGM (1997) J Raman Spectrosc 28:691–696

    Article  Google Scholar 

  31. Brody RH, Edwards HGM, Pollard AM (2001) Anal Chim Acta 427:223–232

    CAS  Google Scholar 

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Authors and Affiliations

  1. Chemical and Forensic Sciences, School of Pharmacy, University of Bradford, Bradford BD7 1DP, West Yorkshire, UK

    Howell G. M. Edwards & Tasnim Munshi

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  1. Howell G. M. Edwards
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  2. Tasnim Munshi
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Correspondence to Howell G. M. Edwards.

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Edwards, H.G.M., Munshi, T. Diagnostic Raman spectroscopy for the forensic detection of biomaterials and the preservation of cultural heritage. Anal Bioanal Chem 382, 1398–1406 (2005). https://doi.org/10.1007/s00216-005-3271-8

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  • DOI: https://doi.org/10.1007/s00216-005-3271-8

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