Abstract
A multiresidue method for determination of 15 organochlorine pesticides (OCPs), six polychlorinated biphenyls (PCBs), and seven organophosphorus pesticides (OPPs) is implemented for routine determinations of residues in honey. The method involves solid-phase extraction cleanup and determination by GC–ECD/NPD. Quantitation limits ranged from 0.1 to 0.6 μg kg−1 honey for OCPs and PCBs, and from 5.0 to 25.0 μg kg−1 honey for OPPs. Recoveries of OCPs ranged between 77.4 and 94.0%; for PCBs they were from 63.8 to 73.5%. Recovery assays for OPPs varied from 66.7 to 98.1%. The method was applied to the analysis of 111 honey samples from Aragón, Spain. The results obtained indicated a low level of contamination by pesticide residues and PCBs, which can contribute to ensuring the consumer has a safe wholesome supply of honey.
Similar content being viewed by others
References
Council Directive 2001/110/EC of 20 December 2001 relating to honey
Herrera A, Ariño A, Conchello P, Lázaro R, Bayarri S, Pérez-Arquillue C (1994) J Food Prot 57:441–444
Lázaro R, Herrera A, Ariño A, Conchello P, Bayarri S (1996) J Agric Food Chem 44:2742–2747
Martel AC, Zeggane S (2002) J Chromatogr A 954:173–180
Fernandez M, Pico Y, Mañes J (2002) Chromatographia 56:577–583
Fernandez MA, Simal J (1993) Analyst 118:1519–1522
Menkissoglu-Spiroudi U, Diamantidis GC, Georgiou VE, Thrasyvoulou AT (2000) J AOAC Int 83:178–182
Albero B, Sanchez-Brunete C, Tadeo JL (2001) J AOAC Int 84:1165–1171
Sanchez-Brunete C, Albero B, Miguel E, Tadeo JL (2002) J AOAC Int 85:128–133
Fernandez MA, Simal J (1991) Analyst 116:269–271
Tisipi D, Triantafyllou M, Hiskia A (1999) Analyst 124:473–475
Fong WG, Moye HA, Seiber JN, Toth JP (1999) In: Winefordner JD (ed) Pesticide residues in foods: methods, techniques, and regulations. Wiley, New York
Jimenez JJ, Bernal JL, del Nozal MJ, Martin MT, Mayorga AL (1998) J Chromatogr A 829:269–277
Jansson C (2000) J AOAC Int 83:714–719
Korta E, Bakkali A, Berruela LA, Gallo B, Vicente F (2001) J Chromatogr A 930:21–29
Sandau CD, Sjödin A, Davis MD, Barr JR, Maggi VL, Waterman AL, Preston KE, Preau JL, Barr DB, Needham LL, Patterson DG (2003) Anal Chem 75(1):71–77
Jimenez JJ, Bernal JL, del Nozal MJ, Toribio L, Martin MT (1998) J Chromatogr A 823:381–387
Analytical methods committee (1987) Analyst 112:199–204
Blasco C, Fernandez M, Pena A, Lino C, Silveira MI, Font G, Pico Y (2003) J Agric Food Chem 51:8132–8138
Blasco C, Fernandez M, Pico Y, Font G (2004) J Chromatogr A 1030:77–85
Acknowledgements
Funding by Spanish INIA (Project API99-018) and DGA (Project 229-111 and DGA/Grupo Consolidado de Investigación) is acknowledged.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Herrera, A., Pérez-Arquillué, C., Conchello, P. et al. Determination of pesticides and PCBs in honey by solid-phase extraction cleanup followed by gas chromatography with electron-capture and nitrogen–phosphorus detection. Anal Bioanal Chem 381, 695–701 (2005). https://doi.org/10.1007/s00216-004-2924-3
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00216-004-2924-3