Abstract
The respirometric BOD OxiTop method was used to monitor the biodegradation of different chain oils (mineral, rapeseed and tall oils) over 28 days in groundwater, as well as in standard conditions described by OECD 301 F. The aim of the study was to gather more information about the biodegradability of forestry oils in groundwater, as well as about the suitability of the automatic OxiTop method for biodegradation measurements. The BOD OxiTop method proved to be a precise and reliable technique for determining the biodegradations of different oils. Some comparative studies were also made using a traditional IR method in order to clarify the total oil concentrations. The results show that if biodegradation only is to be monitored, the OxiTop method is preferable. This is due to the influence of other reactions aside from biodegradation on total hydrocarbon concentrations when using the IR method.
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References
Lauhanen R, Kolppanen R, Takalo S, Kuokkanen T, Kola H, Välimäki I (2000) Effects of biodegradable oils on forest environment and forest machines. In: Proc Int Sci Conf—Forest Wood Tech vs Environ. Brno, Czech Republic, 20–22 Nov 2000, pp 203–206 (and references therein)
Takalo S, Lauhanen R (1994) Tall oil as a lubricant in forestry. In: Proc Soil, Tree, Machine Interactions—Interactive Workshop and Seminar. Feldafing, Federal Republic of Germany, 4–8 July 1994. EU, ECE, IUFRO Division P3.08, FAO, ILO. Paper 4p
CEC (1982) Test method CEC L-33-T-82: Biodegradability of two-stroke cycle outboard engine oils in water. Co-ordinating European Council, Leicester, UK
SFS (1980) SFS 3010: Determination of oil and grease in water. IR-method. Finnish Standards Association (SFS), Helsinki
Kuokkanen T, Vähäoja P, Välimäki I, Lauhanen R (2004) Int J Environ Anal Chem 84(9):677–689
Conzelmann F (1996) Melliand Textil 77(10):700–702
Mittenzwey R, Seidenstuecker T, Fritz H-G, Suessmuth R (1998) Starch/Staerke 50(10):438–443
Reuschenbach P, Pagga U, Strotmann U (2003) Water Res 37(7):1571–1582
Salminen J, Tuomi P, Suortti A-M, Jørgensen K (2004) Biodegradation 15(1):29–39
Gallego J, Loredo J, Vàsquez F, Sánchez J (2001) Biodegradation 12(5):325–335
Murygina V, Arinbarasov M, Kalyuzhnyi S (2000) Biodegradation 11(6):385–389
Cunningham J, Hopkins G, Lebron C, Reinhard M (2000) Biodegradation 11(2–3):159–170
Kirchmann H, Ewnetu W (1998) Biodegradation 9(2):151–156
Davis C, Cort T, Dai D, Illangasekare T, Munakata-Marr J (2003) Biodegradation 14(6):373–384
Hoffmann J, Řezníčèková I, Vaňòková S, Kupec J (1997) Int Biodeter Biodegr 39(4):327–332
Haus F, German J, Junter G-A (2001) Chemosphere 45:983–990
Haus F, Junter G-A, German J (2000) Biodegradation 11(6):365–369
Meredith W, Kelland S-J, Jones DM (2000) Org Geochem 31:1059–1073
OECD (1992) OECD guidelines for the testing of chemicals. Section 3: degradation and accumulation. Test 301: Ready biodegradability. Updated guideline, adopted 17 July 1992. OECD, Paris, France
Alexander M (1977) Transformation of hydrocarbons. In: Introduction to soil microbiology, 2nd edn. Wiley, New York, pp 203–222
Acknowledgements
The authors would like to thank to D.Sc. (Agr. and For.) Risto Lauhanen for many helpful discussions regarding forestry oils. Special thanks to M.Sc.(Chem.) Annukka Juntunen for the carbon content determinations. Pekka Vähäoja would also like to thank the Tauno Tönning Foundation and the Academy of Finland for financial support.
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Vähäoja, P., Kuokkanen, T., Välimäki, I. et al. Biodegradabilities of some chain oils in groundwater as determined by the respirometric BOD OxiTop method. Anal Bioanal Chem 381, 445–450 (2005). https://doi.org/10.1007/s00216-004-2887-4
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DOI: https://doi.org/10.1007/s00216-004-2887-4