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Mechanical and tribological properties of hot-pressed electrospun MWCNTs/carbon nanofibril composite fabrics

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Abstract

Mechanical and tribological properties of electrospun fiber fabrics are of paramount importance to their utility as components in a large number of applications. Post-spin heat treatment assisted with static pressure has been used to enhance the properties of electrospun fabrics and to activate its high surface energy. High-resolution transmission electron microscopy (HRTEM) showed a formation of graphitic structure of 9.5-nm crystallite sizes that has been calculated from Raman breathing modes. Hot-pressed multi-walled carbon nanotubes (MWCNTs)/carbon fabric with 130 ± 32-nm fibril diameters showed an outstanding flexibility and strength. Also, adding MWCNTs enhanced the fabric tensile strength (from 40 to 60 MPa) and lowered the fabric coefficient of friction (COF) (from 1.70 to 0.15) and its abrasive mass loss (0.2 mg has been achieved). The hot-pressed electrospun MWCNTs/carbon nanofibril composite fabrics can be considered as a good candidate, by controlling fabric MWCNT weight percent, for both journal bearing (COF below 0.4) and brake pad (COF from 0.4 to 0.7) applications.

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References

  1. Doshi J, Reneker DH (1995) Electrospinning process and applications of electrospun fibers. J Electrost 35:151–160

    Article  Google Scholar 

  2. Ali AA, Rutledge GC (2009) Hot-pressed electrospun PAN nano fibers: an idea for flexible carbon mat. J Mater Process Technol 209:4617–4620

    Article  Google Scholar 

  3. Ali AA (2014) A novel 3-D graphite structure from thermally stabilized electrospun MWCNTs/PAN nanofibril composite fabrics. Int J Adv Manuf Technol 70:1731–1738

    Article  Google Scholar 

  4. Khan WS et al (2013) Thermal conductivities of electrospun PAN and PVP nanocomposite fibers incorporated with MWCNTs and NiZn ferrite nanoparticles”. Int J Therm Sci 71:74–79

    Article  Google Scholar 

  5. Kima B-H et al (2013) Electrochemical behavior of activated carbon nanofiber-vanadiumpentoxide composites for double-layer capacitors. Electrochim Acta 109:859–865

    Article  Google Scholar 

  6. Kim Y-J et al (2013) Technological potential and issues of polyacrylonitrile based nanofiber non-woven separator for Li-ion rechargeable batteries. J Power Sources 244:196–206

    Article  Google Scholar 

  7. Zhang G, Zhang C, Nardin P, Li WY, Liao H, Coddet C (2008) Effects of sliding velocity and applied load on the tribological mechanism of amorphous poly-ether– ether–ketone (PEEK). Tribol Int 41:79–86

    Article  MATH  Google Scholar 

  8. Li L, Bellan LM, Craighead HG, Frey MW (2006) Formation and properties of nylon-6 and nylon-6/montmorillonite composite nanofibers. Polymer 47(17):6208–6217

    Article  Google Scholar 

  9. Pai CL, Boyce MC, Rutledge GC (2011) Mechanical properties of individual electrospun PA 6(3)T fibers and their variation with fiber diameter. Polymer 52(26):6126–6133

    Article  Google Scholar 

  10. Silberstein MN, Pai CL, Rutledge GC, Boyce MC (2012) Elastic-Plastic Behavior of NonWoven Mats. J Mech Phys Solids 60(2):295–318

    Article  MATH  Google Scholar 

  11. Wang X et al (2008) Enhanced mechanical performance of self-bundled electrospun fiber yarns via post-treatments. Macromol Rapid Commun 29(10):826–831

    Article  Google Scholar 

  12. Lai C, Zhong G et al (2011) Investigation of post-spinning stretching process on morphological, structural, and mechanical properties of electrospun polyacrylonitrile copolymer nanofibers. Polymer 52(2):519–528

    Article  MathSciNet  Google Scholar 

  13. Na H et al (2008) Effect of hot-press on electrospun poly(vinylidene fluoride) membranes. Polym Eng Sci 48(5):934–940

    Article  Google Scholar 

  14. Jeong L et al (2006) Time-resolved structural investigation of regenerated silk fibroin nanofibers treated with solvent vapor. Int J Biol Macromol 38(2):140–144

    Article  Google Scholar 

  15. Cho D, Zhmayev E, Joo YL (2011) Structural studies of electrospun nylon 6 fibers from solution and melt. Polymer 52:4600–4609

    Article  Google Scholar 

  16. Pai CL, Boyce MC, Rutledge GC (2009) On the morphology of porous and wrinkled fibres of polystyrene electrospun from dimethylformamide. Macromolecules 42(6):2102–2114

    Article  Google Scholar 

  17. Derler S, Schrade GU, Gerhardt LC (2007) Tribology of human skin and mechanical skin equivalents in contact with textiles. Wear 263:1112–1116

    Article  Google Scholar 

  18. Gerhardt LC, Mattle N, Schrade GU, Spencer ND, Derler S (2007) Skin Res Technol 14(1):77–88

    Google Scholar 

  19. Lin G-m et al (2012) Hybrid effect of nanoparticles with carbon fibers on the mechanical and wear properties of polymer composites. Compos Part B 43:44–49

    Article  Google Scholar 

  20. Matthew M, Rutledge GC et al (2012) Mechanical and tribological properties of electrospun PA 6(3) T fiber mats. Polymer 53:3017–3025

    Article  Google Scholar 

  21. Policandriotes T, Filip P (2011) Effects of selected nanoadditives on the friction and wear performance of carbon–carbon aircraft brake composites. Wear 271:2280–2289

    Article  Google Scholar 

  22. Chen IH, Wang CC, Chen CY (2010) Fabrication and structural characterization of polyacrylonitrile and carbon nanofibers containing plasma-modified carbon nanotubes by Electrospinning. J Phys Chem C 114(32):13532–13539

    Article  Google Scholar 

  23. Ali AA (2006) Self Assembled Ultra Fine Carbon Coils by Wet Electro-Spinning. Mater Lett 60:2858–2862

    Article  Google Scholar 

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Correspondence to Ashraf A. Ali.

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Ali, A.A., Eldesouky, A.R. & Zoalfakar, S.H. Mechanical and tribological properties of hot-pressed electrospun MWCNTs/carbon nanofibril composite fabrics. Int J Adv Manuf Technol 74, 983–993 (2014). https://doi.org/10.1007/s00170-014-6046-6

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  • DOI: https://doi.org/10.1007/s00170-014-6046-6

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