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Cassiterite LA-MC-ICP-MS U/Pb and muscovite 40Ar/39Ar dating of tin deposits in the Tengchong-Lianghe tin district, NW Yunnan, China

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Abstract

The Tengchong-Lianghe tin district in northwestern Yunnan, China, is an important tin mineralization area in the Sanjiang Tethyan Metallogenic Domain. There are three N–S trending granite belts in the Tengchong-Lianghe area, with emplacement ages ranging from Early Cretaceous to Late Cretaceous and Early Cenozoic. Tin mineralization is spatially associated with these granitic rocks. However, the petrogenetic link between the tin deposits and the host granites is not clear because of the lack of age data for the tin mineralization. We investigate the possibility of direct dating of cassiterite from three typical tin deposits in the Tengchong-Lianghe tin district, using laser ablation multicollector inductively coupled plasma mass spectrometry (LA-MC-ICP-MS). In situ LA-MC-ICP-MS dating of seven cassiterite samples from the Lailishan (LLS-1 and LLS-2), Xiaolonghe (XLH, WDS, DSP, and HJS), and Tieyaoshan (TYS) tin deposits yielded well-defined 206Pb/207Pb–238U/207Pb isochron ages. To assess the accuracy of the in situ U/Pb dating of cassiterite, 40Ar/39Ar dating of coexisting muscovite (in samples LLS-1, DSP, and TYS) was also performed. The cassiterite in situ U/Pb ages (47.4 ± 2.0, 71.9 ± 2.3, and 119.3 ± 1.7 Ma, respectively) are in excellent agreement with the coexisting muscovite 40Ar/39Ar ages (48.4 ± 0.3, 71.9 ± 1.4, and 122.4 ± 0.7 Ma, respectively). The U/Pb ages of cassiterite combined with the 40Ar/39Ar ages of muscovite indicate that there are three tin mineralization events in this district: the Lailishan tin deposit at 47.4 ± 2.0 to 52 ± 2.7 Ma, the Xiaolonghe tin deposit at 71.6 ± 2.4 to 3.9 ± 2.0 Ma, and the Tieyaoshan tin deposit at 119.3 ± 1.7 to 122.5 ± 0.7 Ma. These ages are highly consistent with the zircon U/Pb ages of the host granites. It is su.ggested that the Cretaceous tin mineralization might have taken place in a subduction environment, while the Early Tertiary tin metallogenesis was in a postcollisional geodynamic setting.

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References

  • Andersen T (2002) Correction of common lead in U-Pb analyses that do not report Pb-204. Chem Geol 192:59–79

    Article  Google Scholar 

  • Bell K, Anglin CD, Franklin JM (1989) Sm-Nd and Rb-Sr isotope systematica of scheelites: possible implications for the age and genesis of vein-hosted gold deposits. Geology 17:500–504

    Article  Google Scholar 

  • Bi CS, Sheng XY, Xu QS (1992) New discovery of tin deposit related with Hercynian A-type granite in China. Sci China Ser B Chem 6:632–638 (in Chinese)

    Google Scholar 

  • Birch WD, Barron LM, Magee C, Sutherland FL (2007) Gold- and diamond-bearing White Hills Gravel, St Arnaud district, Victoria: age and provenance based on U-Pb dating of zircon and rutile. Aust J Earth Sci 54:609–628

    Article  Google Scholar 

  • Chen JC (1987) Chronology and emplacement ages of the granitic rocks in the western Yunnan. Yunnan Geol 6:101–113 (in Chinese)

    Google Scholar 

  • Cong F, Lin SL, Xie T, Li ZH, Zou GF, Liang T (2010) Rare earth element geochemistry and U-Pb age of zircons from granites in Tengchong-Lianghe area, Western Yunnan. J Jilin Univ (Earth Sci Ed) 40:573–580, in Chinese with English abstract

    Google Scholar 

  • Cox RA, Wilton DHC (2006) U-Pb dating of perovskite by LA-ICP-MS: an example from the Oka carbonatite, Quebec, Canada. Chem Geol 235:21–32

    Article  Google Scholar 

  • Cui YR, Zhou HY, Geng JZ, Li HK, Li HM (2012) In situ LA-MC-ICP-MS U-Pb isotopic dating of monazite. Acta Geosci Sin 33:865–876, in Chinese with English abstract

    Google Scholar 

  • Gulson BL, Jones MT (1992) Cassiterite: potential for direct dating of mineral deposits and a precise age for the Bushveld complex granites. Geology 20:355–358

    Article  Google Scholar 

  • Heinrich CA (1990) The chemistry of hydrothermal tin(-tungsten) ore deposition. Econ Geol 85:457–481

    Article  Google Scholar 

  • Horn I, Rudnick RL, McDonough WF (2000) Precise elemental and isotope ratio determination by simultaneous solution nebulization and laser ablation-ICP-MS: application to U-Pb geochronology. Chem Geol 164:281–301

    Article  Google Scholar 

  • Horstwood MSA, Foster GL, Parrish RR, Noble SR, Nowell GM (2003) Common-Pb corrected in situ U-Pb accessory mineral geochronology by LA-MC-ICP-MS. J Anal At Spectrom 18:837–846

    Article  Google Scholar 

  • Hou ZQ, Zaw K, Pan GT, Mo XX, Xu Q, Hu YZ, Li XZ (2007) Sanjiang Tethyan metallogenesis in SW China: tectonic setting, metallogenic epochs and deposit types. Ore Geol Rev 31:48–87

    Article  Google Scholar 

  • Jiang BA, Gong QJ, Zhang J, Ma N (2012) Late cretaceous aluminium A-type granites and its geological significance of Dasongpo Sn deposit, Tengchong, West Yunnan. Acta Petrol Sin 28:1477–1492, in Chinese with English abstract

    Google Scholar 

  • Kempe U, Belyatsky BV, Krymsky RS, Kremenetsky AA, Ivanov PA (2001) Sm-Nd and Sr isotope systematics of scheelite from the giant Au(-W) deposit Muruntau (Uzbekistan): implications for the age and sources of Au mineralization. Miner Deposita 36:379–392

    Article  Google Scholar 

  • Kooijman E, Mezger K, Berndt J (2010) Constraints on the U-Pb systematics of metamorphic rutile from in situ LA-ICP-MS analysis. Earth Planet Sci Lett 293:321–330

    Article  Google Scholar 

  • Lehmann B (1990) Metallogeny of tin. Springer, Berlin, 211 p

    Google Scholar 

  • Li QL, Li SG, Zheng YF, Li HM, Massonne HJ, Wang QC (2003) A high precision U-Pb age of metamorphic rutile in coesite-bearing eclogite from the Dabie Mountains in central China: a new constraint on the cooling history. Chem Geol 200:255–265

    Article  Google Scholar 

  • Li JW, Deng XD, Zhou MF, Lin YS, Zhao XF, Guo JL (2010) Laser ablation ICP-MS titanite U-Th-Pb dating of hydrothermal ore deposits: a case study of the Tonglushan Cu-Fe-Au skarn deposit, SE Hubei Province, China. Chem Geol 270:56–67

    Article  Google Scholar 

  • Li ZH, Lin SL, Cong F, Zou GF, Xie T (2012a) Early Cretaceous magmatism in Tengchong-Lianghe block, western Yunnan. Bull Mineral Petrol Geochem 31:590–598, in Chinese with English abstract

    Google Scholar 

  • Li ZH, Lin SL, Cong F, Zou GF, Xie T (2012b) U-Pb dating and Hf isotopic compositions of quartz diorite and monzonitic granite from the Tengchong-Lianghe block, western Yunnan, and its geological implications. Acta Geosci Sin 86:1047–1062, in Chinese with English abstract

    Google Scholar 

  • Li KW, Zhang Q, Wang DP, Cai Y, Liu YP (2013) LA-MC-ICP-MS U-Pb geochronology of cassiterite from the Bainiuchang polymetallic deposit, Yunnan Province, China. Acta Miner Sin 33:523–529, in Chinese with English abstract

    Google Scholar 

  • Liu GL, Qin DX, Fan ZG (2005) Tin resource and its sustainable developing in Yunnan Province. Conservation and Utilization of Mineral Resources, 2:9–13 (in Chinese)

    Google Scholar 

  • Liu YP, Li ZX, Li HM, Guo LG, Xu W, Ye L, Li CY, Pi DH (2007) U-Pb geochronology of cassiterite and zircon from the Dulong Sn-Zn deposit: evidence for cretaceous large-scale granitic magmatism and mineralization events in southeastern Yunnan province, China. Acta Petrol Sin 23:967–976, in Chinese with English abstract

    Google Scholar 

  • Ludwig KR (1997) Isoplot—a plotting and regression program for radiogenic-isotope data. USGS Open-file report, version 2:92

  • Ludwig KR (2001) Users manual for Isoplot/Ex: a geochronological toolkit for Microsoft Excel. Berkeley Geochronology Center Special Publication, 19 pp

  • Mao JW, Zhang ZC, Zhang ZH, Du AD (1999) Re-Os isotopic dating of molybdenites in the Xiaoliugou W (Mo) deposit in the northern Qilian mountains and its geological significance. Geochim Cosmochim Acta 63:1815–1818

    Article  Google Scholar 

  • Mao JW, Li XF, Chen W, Lan XM, Wei SL (2004) 40Ar/39Ar dating of tin ores and related granite in Furong tin ore field Hunan Province, and its geodynamic significance. Miner Depos 23:164–175, in Chinese with English abstract

    Google Scholar 

  • Mao JW, Wang YT, Lehmann B, Yu JJ, Ad D, Mei YX, Li YF, Zang WS, Stein HJ, Zhou TF (2006) Molybdenite Re–Os and albite 40Ar/39Ar dating of Cu–Au–Mo and magnetite porphyry systems in the Yangtze River valley and metallogenic implications. Ore Geol Rev 29:307–324

    Article  Google Scholar 

  • Mo XX, Niu YL, Dong GC, Zhao ZD, Hou ZQ, Zhou S, Ke S (2008) Contribution of syncollisional felsic magmatism to continental crust growth: A case study of the Paleogene Linzizong volcanic Succession in southern Tibet. Chem Geol 250:49–67

    Google Scholar 

  • Peng MS, He SM (1985) A spectroscopic study of cassiterite from different genesis. Chin Sci Bull 8:600–603 (in Chinese)

    Google Scholar 

  • Peng JT, Hu RZ, Burnard PG (2003) Samarium-neodymium isotope systematics of hydrothermal calcites from the Xikuangshan antimony deposit (Hunan, China): the potential of calcite as a geochronometer. Chem Geol 200:129–136

    Article  Google Scholar 

  • Peng JT, Hu RZ, Bi XW, Dai TM, Li ZL, Li XM, Shuang Y, Yuan SD, Liu SR (2007) 40Ar/39Ar isotopic dating of tin mineralization in Furong deposit of Hunan Province and its geological significance. Miner Depos 26:237–248, in Chinese with English abstract

    Google Scholar 

  • Schandl ES, Davis DW, Krogh TE (1990) Are the alteration halos of massive sulfide deposits syngenetic? Evidence from U-Pb dating of hydrothermal rutile at the Kidd Volcanic Center, Abitibi subprovince, Canada. Geology 18:505–508

    Article  Google Scholar 

  • Schmidberger SS, Heaman LM, Simonetti A, Creaser RA, Cookenboo HO (2005) Formation of Paleoproterozoic eclogitic mantle, Slave Province (Canada): insights from in-situ Hf and U-Pb isotopic analyses of mantle zircons. Earth Planet Sci Lett 240:621–633

    Article  Google Scholar 

  • Searle MP, Whitehouse MJ, Robb LJ, Ghani AA, Hutchison CS, Sone M, Ng SWP, Roselee MH, Chung SL, Oliver GJH (2012) Tectonic evolution of the Sibumasu-Indochina terrane collision zone in Thailand and Malaysia: constraints from new U-Pb zircon chronology of SE Asian tin granitoids. J Geol Soc Lond 169:489–500

    Article  Google Scholar 

  • Shi L, Tang LD, Zhao M, Zhang WP (1991) Types of primary tin ore deposit and metallogenic mechanism in Tengchong-Lianghe area. Yunnan Geol 10:191–322, in Chinese

    Google Scholar 

  • Shi RD, Yang JS, Xu ZQ, Qi XX (2008) The Bangong Lake ophiolite (NW Tibet) and its bearing on the tectonic evolution of the Bangong–Nujiang suture zone. J Asian Earth Sci 32:438–457

    Article  Google Scholar 

  • Simonetti A, Neal CR (2010) In-situ chemical, U-Pb dating, and Hf isotope investigation of megacrystic zircons, Malaita (Solomon Islands): evidence for multi-stage alkaline magmatic activity beneath the Ontong Java Plateau. Earth Planet Sci Lett 295:251–261

    Article  Google Scholar 

  • Simonetti A, Heaman LM, Chacko T, Banerjee NR (2006) In situ petrographic thin section U-Pb dating of zircon, monazite, and titanite using laser ablation-MC-ICP-MS. Int J Mass Spectrom 253:87–97

    Article  Google Scholar 

  • Smith M, Storey C, Jeffries T (2005) LA-ICPMS U-Pb dating of titanite: new constraints on multistage geological evolution of the Norrbotten mining district, Sweden. Miner Depos Res Meet Glob Chall 1:829–832

    Article  Google Scholar 

  • Steiger RH, Jäger E (1977) Subcommission on geochronology: convention on the use of decay constants in geo- and cosmochronology. Earth Planet Sci Lett 36:359–362

    Article  Google Scholar 

  • Stein HJ, Markey RJ, Morgan JW, Hannah JL, Schersten A (2001) The remarkable Re-Os chronometer in molybdenite: how and why it works. Terra Nova 13:479–486

    Article  Google Scholar 

  • Stemprok M (1990) Solubility of tin, tungsten and molybenum oxides in felsic magmas. Miner Deposita 25:205–212

    Article  Google Scholar 

  • Storey CD, Smith MP, Jeffries TE (2007) In situ LA-ICP-MS U-Pb dating of metavolcanics of Norrbotten, Sweden: records of extended geological histories in complex titanite grains. Chem Geol 240:163–181

    Article  Google Scholar 

  • Tang L (1992) Discussion to genetic type of Lailishan tin deposit in Tengchong-Lianghe region. Yunnan Geol 11:283–288, in Chinese

    Google Scholar 

  • Taylor JR, Wall VJ (1992) The behavior of tin in granitoid magmas. Econ Geol 87:403–420

    Article  Google Scholar 

  • Valeriano CD, Tupinamba M, Simonetti A, Heilbron M, Almeida JCH, Eirado LG (2011) U-Pb LA-MC-ICPMS geochronology of Cambro-Ordovician post-collisional granites of the Ribeira belt, southeast Brazil: terminal Brasiliano magmatism in central Gondwana supercontinent. J S Am Earth Sci 32:416–428

    Article  Google Scholar 

  • Wang F, Zhou XH, Zhang LC, Ying JF, Zhang YT, Wu FY, Zhu RX (2006) Late Mesozoic volcanism in the Great Xing’an range (NE China): timing and implications for the dynamic setting of NE Asia. Earth Planet Sci Lett 251:179–198

    Article  Google Scholar 

  • Willigers BJA, Baker JA, Krogstad EJ, Peate DW (2002) Precise and accurate in situ Pb-Pb dating of apatite, monazite, and sphene by laser ablation multiple-collector ICP-MS. Geochim Cosmochim Acta 66:1051–1066

    Article  Google Scholar 

  • Wu FY, Yang YH, Marks MAW, Liu ZC, Zhou Q, Ge WC, Yang JS, Zhao ZF, Mitchell RH, Markl G (2010) In situ U-Pb, Sr, Nd and Hf isotopic analysis of eudialyte by LA-(MC)-ICP-MS. Chem Geol 273:8–34

    Article  Google Scholar 

  • Xu H, Zhang MH, Zhu SZ (2010) An approach to geological features and genesis for the Lianghe tin deposit. Acta Geol Sin 30:206–209, in Chinese with English abstract

    Google Scholar 

  • Xu YG, Yang QJ, Lan JB, Luo ZY, Huang XL, Shi YR, Xie LW (2011) Temporal-spatial distribution and tectonic implications of the batholiths in the Gaoligong-Tengliang-Yingjiang area, western Yunnan: constraints from zircon U-Pb ages and Hf isotopes. J Asian Earth Sci 53:151–175

    Article  Google Scholar 

  • Yang QJ, Xu YG, Huang XL, Luo ZY, Shi YR (2009) Geochronology and geochemistry of granites in the Tengliang area, western Yunnan: tectonic implication. Acta Petrol Sin 25:1092–1104, in Chinese with English abstract

    Google Scholar 

  • Yin A, Harrison TM (2000) Geologic evolution of the Himalayan-Tibetan orogen. Annu Rev Earth Pl Sc 28:211–280

    Google Scholar 

  • Yuan SD, Peng JT, Hu RZ, Li HM, Shen NP, Zhang DL (2008) A precise U-Pb age on cassiterite from the Xianghualing tin-polymetallic deposit (Hunan, South China). Miner Deposita 43:375–382

    Article  Google Scholar 

  • Yuan SD, Peng JT, Hao S, Li HM, Geng JZ, Zhang DL (2011) In situ LA-MC-ICP-MS and ID-TIMS U-Pb geochronology of cassiterite in the giant Furong tin deposit, Hunan Province, South China: new constraints on the timing of tin-polymetallic mineralization. Ore Geol Rev 43:235–242

    Article  Google Scholar 

  • Yuan SD, Zhang DL, Shuang Y, Du AD, Qu WJ (2012) Re-Os dating of molybdenite from the Xintianling giant tungsten-molybdenum deposit in southern Hunan Province, China and its geological implications. Acta Petrol Sin 28:27–38, in Chinese with English abstract

    Google Scholar 

  • Zack T, Stockli DF, Luvizotto G, Barth MG, Belousova E, Wolfe MR, Hinton RW (2011) In situ U-Pb rutile dating by LA-ICP-MS: Pb-208 correction and prospects for geological applications. Contrib Mineral Petrol 162:515–530

    Article  Google Scholar 

  • Zaw K (1990) Geological, petrogical and geochemical characteristics of granitoid rocks in Burma: with special reference to the associated W-Sn mineralization and their tectonic setting. J SE Asian Earth Sci 4:293–335

    Article  Google Scholar 

  • Zhang SL (1986) Geological setting and ore types of the Tengchong tin ore belt in Yunnan province. Miner Depos 5:19–26, in Chinese

    Google Scholar 

  • Zhang LS, Schärer U (1996) Inherited Pb components in magmatic titanite and their consequence for the interpretation of U-Pb ages. Earth Planet Sci Lett 138:57–65

    Article  Google Scholar 

  • Zhang DL, Peng JT, Hu RZ, Yuan SD, Zheng DS (2011) The closure of U-Pb isotope system in cassiterite and its reliability for dating. Geol Rev 57:549–554, in Chinese with English abstract

    Google Scholar 

  • Zhou HY, Geng JZ, Cui YR, Li HK, Li HM (2012) In situ U-Pb dating of apatite using LA-MC-ICP-MS. Acta Geosci Sin 33:857–864, in Chinese with English abstract

    Google Scholar 

  • Zhou HY, Li HM (2008) The improvement of the rutile isotope dilution U-Pb dating methodology. Acta Petrologica et Mineralogica 27:77–80

    Google Scholar 

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Acknowledgments

This work was financially supported by the State Key Program of National Natural Science Foundation of China (41130423), the CAS/SAFEA International Partnership Program for Creative Research Teams (KZZD-EW-TZ-20), and the 12th Five-Year Plan Project of the State Key Laboratory of Ore Deposit Geochemistry, Chinese Academy of Sciences (SKLODG-ZY125-03). The Yunnan Tin Industry Co. Ltd. is gratefully acknowledged for their assistance during our fieldwork. Thanks are particularly extended to the reviewers and editor Bernd Lehmann for their constructive comments and suggestions which resulted in a major improvement of this manuscript.

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  1. State Key Laboratory of Ore Deposits Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, 550005, China

    Xiao-Cui Chen, Rui-Zhong Hu, Xian-Wu Bi, Jiang-Bo Lan, Cheng-Hai Zhao & Jing-Jing Zhu

  2. University of Chinese Academy of Sciences, Beijing, 100049, China

    Xiao-Cui Chen & Cheng-Hai Zhao

  3. Tianjin Institute of Geology and Mineral Resources, Tianjin, 300170, People’s Republic of China

    Hui-Min Li

  4. Institute of Geochemistry, Chinese Academy of Sciences, 46 Guanshui Road, Guiyang, 550002, People’s Republic of China

    Rui-Zhong Hu

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  1. Xiao-Cui Chen
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Chen, XC., Hu, RZ., Bi, XW. et al. Cassiterite LA-MC-ICP-MS U/Pb and muscovite 40Ar/39Ar dating of tin deposits in the Tengchong-Lianghe tin district, NW Yunnan, China. Miner Deposita 49, 843–860 (2014). https://doi.org/10.1007/s00126-014-0513-8

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