Skip to main content
Log in

Late Archean Cu-Au-Mo mineralization at Gameleira and Serra Verde, Carajàs Mineral Province, Brazil: constraints from Re-Os molybdenite ages

  • Letters
  • Published:
Mineralium Deposita Aims and scope Submit manuscript

Abstract

New Re-Os molybdenite ages provide constraints on the timing of Late Archean Cu-Au-Mo mineralization in the northern Carajás Mineral Province. Molybdenite from the Gameleira iron oxide Cu-Au-Mo deposit yielded an age of 2,614±14 Ma. This age overlaps within its analytical error with Re-Os ages of molybdenite from the Serra Verde Cu-Au-Mo vein deposit (2,609±13 Ma) and from the nearby small Garimpo Fernando gold mining operation (2,592±13 and 2,602±13 Ma), which is probably related to the latter. The geochronological data imply that the hydrothermal Cu-Au-Mo mineralization in these three deposits was epigenetic and coincides with a regional tectonic regime changing from dextral transtension and clastic sedimentation at 2.7–2.6 Ga to sinistral transpression and inversion at 2.6 Ga. Previously reported stable isotope and microthermometric data are compatible with a magmatic affiliation of the Cu-Au-Mo ores at Gameleira and Serra Verde. A genetic relationship of mineralization may therefore exist with 2.56–2.76 Ga Archean alkaline granitoids or with 2.6–2.7 calc-alkaline to tholeiitic volcanic-arc type magmatism.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  • Almada MCO, Villas RN (1999) O deposito Bahia: exemplo de depósito arqueano vulcanogênico de sulfetos de Cu ± Au tipo Besshi em Carajás, Pará. SBG, Simpósio de Geologia da Amazônia, Manaus, Boletim de Resumos Expandidos 6:98–101

  • Araújo OJB, Maia RGN (1991) Programa Grande Carajás, Serra dos Carajás, Folha SB.22-Z-A, Estado do Pará. DNPM/CPRM, Brasília, p 164

    Google Scholar 

  • Barra F, Ruiz J, Mathur R (2003) A Re-Os study of sulfide minerals from the Bagdad porphyry Cu-Mo deposit, northern Arizona, USA. Mineralium Deposita 38:585–596

    Article  CAS  Google Scholar 

  • Barros CEM, Sardinha AS, Barbosa JPO, Krimski R, Macambira MJB (2001) Pb-Pb and U-Pb zircon ages of Archean syntectonic granites of the Carajás metallogenic province, northern Brazil. III South American Symposium on Isotope Geology, Pucon, Chile, 21–24 October 2001, Compact Disc

  • Cordani U (1981) Comentários sobre as determinaçóes geocronológicas da região da Serra dos Carajás. Report,Universidade de São Paulo-Docegeo

  • Costa JBS, Araújo OJB, Santos A, Jorge-João XS, Macambira MJB, Lafon JM (1999) A Província Mineral de Carajás: Aspectos tectono-estruturrais, estratigraficos e geocronológicos. Boletim do Museu Paraense Emílio Goeldi 7:199–235

    Google Scholar 

  • Creaser RA, Selby D (2002) Re-Os molybdenite analysis: considerations for accurate and reproducible dates: abstracts of the 12th Annual V.M. Goldschmidt Conference. Geochem Cosmochim Acta 66:156

    Article  Google Scholar 

  • Dardenne MA, Ferreira Filho CF, Meirelles MR (1988) The role of shoshonitic and calc-alkaline suites in the tectonic evolution of the Carajás district, Brazil. J South Am Earth Sci 1:363–372

    Article  Google Scholar 

  • Dias GS, Macambira MJB, Dall’Agnol R, Soares ADV, Barros CEM (1996) Datação de zircões de sill de metagabro: comprovação da idade arqueana da Formação Águas Claras, Carajás, Pará. V Simposio de Geologia da Amazonia, Belém, SBG, Bulletin, Extended Abstracts, pp 376–379

  • Docegeo (1988) Revisão litoestratigráfica da Provincia Mineral de Carajás. 35. Congreso Brasileiro de Geologia, Belém, Anexo aos Anais, pp 11–54

  • Farias NF, Saueressig R (1982) Jazida de cobre Salobo 3A. I Simpósio de Geologia da Amazônia, Belém. SBG, Anais, pp 61–73

    Google Scholar 

  • Faure G (1986) Principles of isotope geology. Wiley, New York, p 589

    Google Scholar 

  • Galarza MA, Macambira MJB (2002) Geocronologia e evolução crustal da área do depósito de Cu-Au Gameleira, Província Mineral de Carajás (Pará), Brasil. Revista do Instituto de Geociências. USP, São Paulo 2:143–159

  • Hirata WK, Rigon JC, Kadekaru K, Cordeiro AAC, Meireles EM (1982) Geologia regional da Província Mineral de Carajás. 1. Simpósio de Geologia da Amazônia, Belém. SBG, Anais, pp 100–110

    Google Scholar 

  • Holdsworth RE, Pinheiro RVL (2000) The anatomy of shallow-crustal transpressional structures: insights from the Archean Carajás fault zone, Amazon, Brazil. J Struct Geol 22:1105–1123

    Article  Google Scholar 

  • Huhn SRB, Nascimiento JAS (1997) São os depósitos cupríferos de Carajás do tipo Cu-Au-U-ETR? Contribuições á Geologia da Amazônia, pp 144–160

  • Huhn SRB, Soares ADV, Medeiros Filho CA, Guedes SC, Moura, LGB, Rego JL, Cravo CH (2000a) Carajás Mineral Province, Pará State, north of Brazil. 31. International Geological Congress, Field Trip Guide, p 24

  • Huhn SRB, Soares ADV, Souza CIJ, Albuquerque MAC, Leal ED, Vieira EAP, Masotti FS, Brustolin V (2000b) The Cristalino copper-gold deposit, Serra dos Carajás, Pará. 31. International Geological Congress, Rio de Janeiro, Abstracts, Compact Disc

  • Kosler J, Simonetti A, Sylvester PJ, Cox RA, Tubrett MN, Wilton DHC (2003) Laser-ablation ICP-MS measurementsof Re/Os in molybdenite and implications for Re-Os geochronology. In: Jackson SE, Guenther D, Sylvester PJ (eds) Applications of laser- ablation ICP-MS analysis: a tribute to Henry P. Longerich. The Canadian Mineralogist 41, pp 307–320

  • Lindenmayer ZG (1990) Salobo Sequence, Carajás, Brazil: geology, geochemistry and metamorphism. Ph.D. thesis, University of Western Ontario, p 406

  • Lindenmayer ZG (1998) O depósito de Cu (Au-Ag-Mo) do Salobo, Serra dos Carajás, revisitado. In: Workshop Depósitos Minerais Brasileiros de Metais-Base. ADIMIB-CPGG-UFBA-CAPES-PADCT, Salvador, pp 29–37

  • Lindenmayer ZG, Fyfe WS (1994) The Salobo Cu (Au, Ag, Mo) deposit, Serra Dos Carajás, Brazil. In: 7th Congreso Geológico Chileno, Concepción, 1994, Actas, pp 840–842

  • Lindenmayer ZG, Pimentel MM, Ronchi LH, Althoff FJ, Laux JH, Araújo JC, Fleck A, Bortowski DC, Nowatzki AC (2001) Geologia do depósito de Cu-Au do Gameleira, Serra dos Carajás, Pará. In: Jost H, Brod JA, Quieroz ET (eds) Caracterização de Depósitos Auríferos Brasileiros, ADIMB-DNPM, Brasília, pp 79–139

  • Machado N, Lindenmayer ZG, Krogh TE, Lindenmayer D (1991) U-Pb geochronology of Archean magmatism and basement reactivation in the Carajás area, Amazon shield, Brazil. Precambrian Res 49:239–354

    Article  Google Scholar 

  • Marschik R, Fontboté L (2001) The Candelaria-Punta del Cobre iron oxide Cu-Au(-Zn-Ag) deposits, Chile. Econ Geol 96:1799–1826

    CAS  Google Scholar 

  • Marschik R, Leveille RA (2001) Iron oxide copper-gold deposits in South America: La Candelaria, Chile, and Sossego, Brazil. Geological Society of America Annual Meeting, Boston MS, 1–10 November 2001, Abstracts and Program, p A-2

  • Marschik R, Mathur RD, Spangenberg JE, Ruiz J, Leveille RA, de Almeida AJ (2001) The Serra Verde Cu-Mo-Au deposit, Carajás Mineral Province, Pará State, Brazil. Geological Society of America Annual Meeting, Boston, MS, 2001, Abstracts and Programs, p A418

  • Marschik R, Mathur RD, Ruiz J, Leveille, RA, de Almeida, AJ (2002) An Archean Re-Os molybdenite age for the Gameleira Cu-Au-Mo mineralization, Carajás Province, Brazil: Geological Society of America Annual Meeting, 27–30 October 2002, Abstracts and Program, Paper No. 152-7

  • Marschik R, Spangenberg JE, Leveille RA, de Almeida AJ (2003) The Sossego iron oxide Cu-Au deposit, Carajás, Brazil. In: Eliopoulos DG, et al (eds) Mineral exploration and sustainable development. Millpress, Rotterdam, pp 331–334

  • Mathur R, Marschik R, Ruiz J, Munizaga F, Leveille RA, Martin W (2002) Age of mineralization of the Candelaria iron oxide Cu-Au deposit, and the origin of the Chilean Iron Belt based on Re-Os isotopes. Econ Geol 97:59–71

    CAS  Google Scholar 

  • McCandless T, Ruiz J, Campbell AR (1993) Rhenium behaviour in molybdenite in hypogene and near-surface environments: implications for Re-Os geochronology. Geochem Cosmochim Acta 57:889–905

    Article  CAS  Google Scholar 

  • Mougeot R, Respaut JP, Briqueu L, Ledru P. Milesi JP, Macambira MJB, Huhn SB (1996) Geochronological constrains for the age of the Águas Claras Formation (Carajás Province, Pará, Brazil). 39. Congreso Brasileiro de Geologia, Salvador, Anais, pp 579–581

  • Olszewski WJ, Wirth KR, Gibbs AK, Gaudette HE (1989) The age, origin and tectonics of the Grão-Pará Group and associated rocks, Serra dos Carajás, Brazil. Precambrian Res 42:229–254

    Article  CAS  Google Scholar 

  • Pimentel MM, Lindenmayer ZG, Laux JH, Armstrong R, Araujo JC (2003) Geochronology and Nd isotope geochemistry of the Gameleira Cu-Au deposit, Serra dos Carajás, Brazil: 1.8–1.7 Ga hydrothermal alteration and mineralization. J South Am Earth Sci 15:803–813

    Article  Google Scholar 

  • Pinheiro RVL, Holdsworth RE (1997) The structure of the Carajás N-4 ironstone deposit and associated rocks: Relationship to Archean strike-slip tectonics and basement reactivation in the Amazon region. J South Am Earth Sci 10:305–320

    Article  Google Scholar 

  • Pinheiro RVL, Nogueira ACR, Costa JBS (1991) Superposiçao de transposiçao na Serra dos Carajás, Pará. 3. Simposio Nacional de Estudos Tectônicos, Rio Claro, Brazil, pp 45–52

  • Raith JG, Stein HJ (2000) Re-Os dating and sulfur isotope composition of molybdenite from tungsten deposits in western Namaqualand, South Africa: implications for ore genesis and the timing of metamorphism. Mineralium Deposita 35:741–753

    Article  CAS  Google Scholar 

  • Reis FN, Villas RN (1999) O depósito de sulfetos de Cu+Au de Serra Verde, Província Mineral de Carajás: Caracterização mineralógica, rochas encaixantes e evidências de metamorfismo. VI Simpósio de Geologia da Amazônia, Manaus, pp 106–109

  • Requia K, Fontboté L (2000) The Salobo iron oxide copper-gold deposit, Carajás, northern Brazil. In: Porter TM (ed) Hydrothermal iron-oxide copper-gold & related deposits: a global perspective. Australian Mineral Foundation, Adelaide, pp 225–236

    Google Scholar 

  • Requia K, Stein HJ, Fontboté L, Chiaradia M (2003) Re-Os and Pb-Pb geochronology of the Archean Salobo iron oxide copper-gold deposit, Carajás mineral province, northern Brazil. Mineralium Deposita 38:727–738

    Article  CAS  Google Scholar 

  • Ronchi LH, Lindenmayer ZG, Araújo JC (2000) The Gameleira Cu (Mo-Au) deposit: fluids and hydrothermal alteration (Carajás, Brazil). 31. International Geological Congress, Rio de Janeiro, Compact Disk

  • Ronzê PC, Soarez ADV, Santos MGS, Barreira CF (2000) The Alemão copper-gold (U-REE) deposit, Carajás, Brazil. In: Porter TM (ed) Hydrothermal iron-oxide copper-gold & related deposits: a global perspective. Australian Mineral Foundation, Adelaide, pp 191–202

    Google Scholar 

  • Selby D, Creaser RA (2001a) Late and Mid Cretaceous mineralization in the Northern Canadian Cordillera: constraints from Re-Os molybdenite dates. Econ Geol 96:1461–1467

    CAS  Google Scholar 

  • Selby D, Creaser RA (2001b) Re-Os geochronology and systematics in molybdenite from the Endako Porphyry Molybdenum Deposit, British Columbia, Canada. Econ Geol 96:197–204

    CAS  Google Scholar 

  • Smoliar M, Walker R, Morgan J (1996) Re-Os ages of group IIA, IIIA, IVA, and IVB Iron meteorites. Science 271:1099–1102

    CAS  Google Scholar 

  • Souza SRB, Macambira MJB, Scheller T (1996) Novos dados geocronológicos para os granitos deformados do Rio Itacaiúnas (Serra dos Carajás, PA): Implicações estratigráficas. V Simpósio de Geologia da Amazônia, Belém, pp 380–382

  • Stein HJ, Morgan JW, Markey RJ, Hannah JL (1998) An introduction to Re-Os: what’s in it for the mineral industry? SEG Newslett 32(1):8–15

    Google Scholar 

  • Stein HJ, Markey RJ, Morgan JW, Hannah JL, Scherstén A (2001) The remarkable Re–Os chronometer in molybdenite: how and why it works. Terra Nova 13:479–486

    Article  CAS  Google Scholar 

  • Stein HJ, Scherstén A, Hannah JL, Markey RJ (2003) Sub-grain scale decoupling of re and 187Os and assessment of laser ablation ICP-MS spot dating in molybdenite. Geochem Cosmochim Acta 67:3673–3686

    Article  CAS  Google Scholar 

  • Suzuki K, Kagi H, Nara M, Takano B, Nozaki Y (2000) Experimental alteration of molybdenite: evaluation of the Re-Os system, infrared spectroscopic profile and polytype. Geochem Cosmochim Acta 64:223–232

    Article  CAS  Google Scholar 

  • Tallarico FHB, Oliveira CG, Figueiredo BR (2000) The Igarapé Bahia Cu-Au mineralization. Carajás Province, Revista Brasileira de Geociências 30:230–233

    Google Scholar 

  • Tazava E, de Oliveira CG (2000) The Igarapé Bahia Au-Cu-(REE-U) deposit, Carajás Mineral Province, Northern Brazil. In: Porter TM (ed) Hydrothermal iron-oxide copper-gold & related deposits: a global perspective. Australian Mineral Foundation, Adelaide, pp 203–212

    Google Scholar 

  • Teixeira JBG, Eggler DH (1994) Petrology, geochemistry, and tectonic setting of Archean basaltic and dioritic rocks from the N4 Iron Deposit, Serra dos Carajás, Pará, Brazil. Acta Geologica Leopoldensia 40:71–114

    Google Scholar 

  • Torrealday HI, Hitzman MW, Stein HJ, Markey RJ, Armstrong R, Broughton D (2000) Re-Os and U-Pb dating of the vein-hosted mineralization at the Kansanshi copper deposit, northern Zambia. Econ Geol 95:1165–1170

    CAS  Google Scholar 

  • Trendall AF, Basei MAS, De Laeter JR, Nelson DR (1998) SHRIMP zircon U-Pb constraints on the age of the Carajás formation, Grão Pará Group, Amazon craton. J South Am Earth Sci 11:265–277

    Article  Google Scholar 

  • Villas RN, Santos MD (2001) Gold deposits of the Carajás mineral province: deposit types and metallogenesis. Mineralium Deposita 36:300–331

    Article  Google Scholar 

  • Watanabe Y, Stein HJ (2000) Re-Os ages for the Erdenet and Tsagaan Suvarga porphyry Cu-Mo deposits, Mongolia, and tectonic implications. Econ Geol 95:1537–1542

    CAS  Google Scholar 

  • Winter CJ (1994) Geology and base metal mineralization associated with Archean iron formation in the Pojuca Corpo Quatro Deposit, Carajas, Brazil. Ph.D. thesis, University of Southampton, p 214

  • Wirth KR, Gibbs AK, Olszewski W (1986) The geology and geochemistry of the Grão Pará Group, Serra dos Carajás, Pará, Brazil. Revista Brasileira de Geosciências 16:195–200

    Google Scholar 

  • Xiong Y, Wood SA (2000) Experimental quantification of hydrothermal solubitity of platinum-group elements with special reference to porphyry copper environments. J Mineral Petrol 68:1–28

    Google Scholar 

Download references

Acknowledgements

We thank DOCEGEO/CVRD and the owners of Serra Verde mine, and Garimpo Fernando for access to their properties and the samples. We particularly wish to thank L. Saboia, Mr. Murano, S. Guedes, and Mr. Muraia for their assistance. Thanks are also due to Phelps Dodge do Brasil Mineração Ltda. for the logistic support. Funding by the Deutsche Forschungsgemeinschaft for R. Marschik is gratefully acknowledged. This paper benefited greatly from constructive comments and suggestions by B. Lehmann, F. Tornos, and an anonymous reviewer.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Robert Marschik.

Additional information

Editorial handling: F. Tornos

Rights and permissions

Reprints and permissions

About this article

Cite this article

Marschik, R., Mathur, R., Ruiz, J. et al. Late Archean Cu-Au-Mo mineralization at Gameleira and Serra Verde, Carajàs Mineral Province, Brazil: constraints from Re-Os molybdenite ages. Miner Deposita 39, 983–991 (2005). https://doi.org/10.1007/s00126-004-0450-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00126-004-0450-z

Keywords

Navigation