Abstract
The influence of inclusions and microstructure on magnetic properties was investigated in calcium(Ca)-treated non-oriented silicon steels. The total number density of inclusions was reduced due to the removal of low melt point and calcium sulfide (CaS)-bearing inclusions. Inclusions containing manganese sulfide (MnS) decreased, while those with aluminum nitride (AlN) increased. The segregation concentration of Mn, S, Al, and N during the solidification process was calculated based on a simple microsegregation model. The results showed that the Ca treatment modulated the precipitation characteristics of MnS and AlN. An increase in the grain size was observed accompanied by a reduced number density of precipitates. The density of γ-fiber texture increased, while that of the η-fiber texture decreased. The core loss and magnetic induction decreased by 10.06% and 3.50%, respectively. These results indicated that an appropriate Ca treatment during the refining process could effectively modify the inclusions and reduce the core loss.
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References
Z.Z. He, Y. Zhao, and H.W. Luo, Electrical Steel (Metallurgical Industry Press, Beijing, 2012), pp 279–355.
H.G. Kang, K.M. Lee, M.Y. Huh, J.S. Kim, J.T. Park, and O. Emgler, J. Magn. Magn. Mater. 323, 2248. (2011).
K.M. Lee, S.Y. Park, M.Y. Huh, J.S. Kim, and O. Engler, J. Magn. Magn. Mater. 354, 324. (2014).
P. Ghosh, R.R. Chromik, A.M. Knight, and S.G. Wakade, J. Magn. Magn. Mater. 356, 42. (2014).
Y. Oda, Y. Tanaka, A. Chino, and K. Yamada, J. Magn. Magn. Mater. 254, 361. (2003).
J.Y. Wang, Q. Ren, Y. Luo, and L.F. Zhang, J. Magn. Magn. Mater. 451, 454. (2018).
Y. Kurosaki, M. Shiozaki, K. Higashine, and M. Sumimoto, ISIJ Int. 39, 607. (1999).
H. Matsuoka, M. Motoyoshi and M. Makino, Continuously cast slabs for grain oriented electrical steel sheet and method for producing said steel sheet (U.S. Patent and Trademark Office, 1975), https://www.uspto.gov/. Accessed 8 April 1975.
K. Jenkins, and M. Lindenmo, J. Magn. Magn. Mater. 320, 2423. (2008).
X.S. Wang, Y.H. Sun, G.W. Li, H.H. Xiong, Z. Qiao, and K.K. Cai, Steelmaking 28, 48. (2012).
Y. Wan, W.Q. Chen, and S.J. Wu, Shanghai Met. 36, 7. (2014).
F. Zhang, L.D. Miao, and Z.Y. Zong, Baosteel Tech. Res. 7, 12. (2013).
Y.Y. Guo, K.K. Cai, Z.H. Luo, L.T. Liu, and Z.M. Liu, J. Univ. Sci. Technol. Beijing 27, 427. (2005).
Y. Wan, W.Q. Chen, and S.J. Wu, Special Steel 34, 64. (2013).
Q. Ren, W. Yang, and L. Cheng, J. Magn. Magn. Mater. 494, 165803. (2019).
H. Suito, and R. Inoue, ISIJ Int. 36, 528. (1996).
C.Y. Zhu, L.Y. Huang, X.Y. Luo, Y.L. Liu, Y. Wang, and G.Q. Li, J. Iron Steel Res. 32, 117. (2020).
X.H. Huang, Theory of Iron and Steel Metallurgy (Metallurgical Industry Press, Beijing, 2002), pp 111–811.
C.Y. Zhu, X.Y. Luo, G.Q. Lig, J.X. Feng, and Z.F. Yan, J. Chongqing Univ. Nat. Sci. Ed. 41, 35. (2018).
M. Hino, and K. Ito, Thermodynamic Data for Steelmaking (Tohoku University Press, Sendai, 2010), p 226.
Y.M. Won, and B.G. Thomas, Metall. Mater. Trans. A. 32, 1755. (2001).
J. Matsuno, Proc. Symp. Solidification Phenomena,Solidification Comm., ISIJ, Tokyo, 2 (1976).
Y. Ueshima, S. Mizoguchi, T. Matsumiya, and H. Kajioka, Matall. Trans. B. 17, 845. (1986).
K. Kim, H.N. Han, T. Yeo, Y. Lee, K.H. Oh, and D.N. Lee, Ironmaking Steelmaking 24, 249. (1997).
Z.Z. Liu, J. Wei, and K.K. Cai, ISIJ Int. 42, 958. (2007).
Y. Meng, and B. Thomas, Metall. Mater. Trans. B 34, 685. (2003).
F.J. Li, H.G. Li, and Y. Wu, J. Mater. Res. 32, 2307. (2017).
M. Shiozaki, and Y. Kurosaki, J. Mater. Eng. 11, 37. (1989).
H. Huneus, K. Günther, and T. Kochmann, J. Mater. Eng. Perform. 2, 199. (1993).
C. Gheorghies, and A. Doniga, J. Iron Steel Res. Int. 16, 78. (2009).
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The authors appreciate the financial support for this study from the National Natural Science Foundation of China (Grant No. 51674180).
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Liu, Y., Zhu, C., Huang, L. et al. Influence of Inclusions on Magnetic Properties of Al-Killed Non-oriented Silicon Steels. JOM 74, 2645–2655 (2022). https://doi.org/10.1007/s11837-022-05333-w
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DOI: https://doi.org/10.1007/s11837-022-05333-w