Abstract
A kinetic model of thermochemical transformation of solid organic fuels was constructed. The mathematical model describes the kinetics of drying, release and combustion of volatiles, and combustion and gasification of the nonvolatile (coke) residue at linear heating. The kinetic curves of burn-out of Irsha-Borodino brown coal at various heating rates and model parameters were calculated.
Similar content being viewed by others
REFERENCES
Pronin, M.S., Meshcheryakov, V.G., Kozlov, S.G., et al., Teploenergetika, 1996, no. 9, pp. 7–12.
Kotler, V.R., Teploenergetika, 1992, no. 2, pp. 72–76.
Polyakov, A.A. and Shlenskii, O.F., Khim. Tverd. Topl., 1994, no. 1, pp. 83–88.
Bykov, V.I., Vishnevskaya, T.M., and Tsirul’nichenko, N.M., Fiz. Goren. Vzryva, 1997, vol. 33, no.4, pp. 39–45.
Starchenko, A.V., Fiz. Goren. Vzryva, 1998, vol. 34, no.5, pp. 3–13.
Makarov, V.N. and Gerasimov, G.Ya., Fiz. Goren. Vzryva, 1999, vol. 35, no.2, pp. 23–29.
Denisov, E.T., Kinetika gomogennykh khimicheskikh reaktsii (Kinetics of Homogeneous Chemical Reactions), Moscow: Vysshaya Shkola, 1978.
Panchenkov, G.M. and Lebedev, V.P., Khimicheskaya kinetika i kataliz (Chemical Kinetics and Catalysis), Moscow: Khimiya, 1974, 2nd ed.
Boiko, E.A., Thermochim. Acta, 2000, vol. 348, pp. 97–104.
Osnovy prakticheskoi teorii goreniya (Principles of the Practical Combustion Theory), Pomerantsev, V.V., Ed., Leningrad: Energoatomizdat, 1986.
Vilenskii, T.V. and Khzmalyan, D.M., Dinamika goreniya pylevidnogo topliva (Dynamics of Combustion of Pulverized Fuel), Moscow: Energiya, 1978.
Shatil’, A.A., Topochnye protsessy i ustroistva (issledovaniya i raschet) (Combustion Processes and Devices (Studies and Calculation)), St. Petersburg: Tsentr. Kotloturb. Inst., 1997.
Babii, V.I. and Kuvaev, Yu.F., Gorenie ugol’noi pyli i raschet pyleugol’nogo fakela (Combustion of Coal Dust and Calculation of Coal-Dust Flare), Moscow: Energoatomizdat, 1986.
Boiko, E.A., Shishmarev, P.V., Didichin, D.G., and Zhadovets, E.M., Khim. Tverd. Topl., 2003, no. 4, pp. 70–78.
Varfolomeev, S.D. and Gurevich, K.G., Biokinetika (Bioengineering), Moscow: FAIR, 1999.
Eksperimental’nye metody khimicheskoi kinetiki (Experimental Methods of Chemical Kinetics), Emanuel’, N.M. and Sergeev, G.B., Eds., Moscow: Vysshaya Shkola, 1980.
Boiko, E.A., Zh. Prikl. Khim., 1998, vol. 71, no.10, pp. 1736–1741.
Boiko, E.A., Didichin, D.G., and Shishmarev, P.V., Zh. Prikl. Khim., 2003, vol. 76, no.4, pp. 605–610.
Yavorskii, I.A., Fiziko-khimicheskie osnovy goreniya tverdykh goryuchikh iskopaemykh topliv i grafitov (Physicochemical Principles of Combustion of Solid Fossil Fuels and Graphites), Novosibirsk: Nauka, 1973.
Warnatz, J., Maas, U., and Dibble, R.W., Combustion: Physical and Chemical Fundamentals, Modeling and Simulation, Experiments, Pollutant Formation, Berlin: Springer, 2001, 3rd ed.
Golovina, E.S., Fiz. Goren. Vzryva, 2002, vol. 38, no.4, pp. 25–34.
Muller, M. and Pachaly, R., in XXXII Kraftwerkstechnisches Kolloquium, Dresden, 2000, pp. 99–108.
Maiboroda, V.D., Gergalov, V.I., and Petryaev, E.P., Matematicheskoe modelirovanie khimicheskoi kinetiki (Mathematical Simulation of Chemical Kinetics), Minsk: Universitetskoe, 1989.
Emanuel’, N.M. and Knorre, D.G., Kurs khimicheskoi kinetiki (A Course of Chemical Kinetics), Moscow: Vysshaya Shkola, 1984, 4th ed.
Shemyakin, V.N., Mishina, K.I., and Kim, V.E., in Sbornik nauchnykh trudov po problemam teplo-i massoperenosa v topochnykh ustroistvakh, gazogeneratorakh i khimicheskikh reaktorakh (Coll. of Scientific Works on the Problems of Heat and Mass Transfer in Combustion Chambers, Gas Generators, and Chemical Reactors), Minsk, 1983, pp. 134–145.
Yablonskii, G.S. and Spivak, S.I., Matematicheskie modeli khimicheskoi kinetiki (Mathematical Models of Chemical Kinetics), Moscow: Znanie, 1977.
Author information
Authors and Affiliations
Additional information
Translated from Zhurnal Prikladnoi Khimii, Vol. 77, No. 9, 2004, pp. 1558–1567.
Original Russian Text Copyright © 2004 by Boiko, Pachkovskii.
Rights and permissions
About this article
Cite this article
Boiko, E.A., Pachkovskii, S.V. A kinetic model of thermochemical transformation of solid organic fuels. Russ J Appl Chem 77, 1547–1555 (2004). https://doi.org/10.1007/s11167-005-0070-0
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11167-005-0070-0