Skip to main content
Log in

Effect of precipitates on hydrogen transport and hydrogen embrittlement of aluminum alloys

  • Published:
Materials Science Aims and scope

Abstract

It is shown that aluminum, Al-Mg-Mn-Fe (Alustar), Al-Mg-Mn-Fe-Si-Cr (PA13), and Al-Zn-Mg-Mn-Fe-Si-Cr (Pa47) alloys are sensitive to hydrogen embrittlement in the course of the tests carried out at low strain rates in a 0.01 N NaOH solution. The stress-strain curves, time to failure, and the character of fracture surfaces of specimens tested in air and under the conditions of cathodic polarization are compared. The parameters of hydrogen transport and its entrapping by hydrogen traps are studied on the basis of the data of electrochemical measurements of hydrogen permeation and vacuum extraction. The morphology of inclusions is estimated by the method of numerical metallography and their chemical composition by the method of EDS analysis. Despite distinctions in the chemical and phase compositions of alloys, we observe the dependence of the sensitivity to hydrogen embrittlement on the parameters of hydrogen transport and its entrapping by irreversible traps and some other microstructural characteristics. Under the conditions of electrolytic hydrogenation, the PA13 alloy reveals hydrogen-enhanced plasticity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. V. M. A. Devanathan Z. Stachurski (1964) ArticleTitleThe mechanism of hydrogen evolution on iron in acid solutions by determination of permeation rates J. Electrochem. Soc. 111 619–623

    Google Scholar 

  2. R. M. Barrer (1941) Diffusion Through and in Solids Univ. Press Cambridge

    Google Scholar 

  3. G. M. Pressouyre I. M. Bernstein (1978) ArticleTitleA quantitative analysis of hydrogen trapping Metal. Trans. 9a 1571–1576

    Google Scholar 

  4. A. Turnbull (1995) ArticleTitleFactors affecting the reliability of hydrogen permeation measurement Mater. Sci. Forum 192 IssueID194 63–78

    Google Scholar 

  5. D. T. DeHoff F. N. Rhines (1973) Quantitative Microscopy McGraw-Hill New York

    Google Scholar 

  6. B. N. Arzamasov (1986) Materials Science Mashinostroenie Moscow

    Google Scholar 

  7. Z. Szklarska-Smialowska, “Susceptibility of steels to hydrogen trapping evaluated by potentiostatic double pulse technique,” in: Polish-Japanese Symp. on the Environmental Effects on High-Technology Materials, Warsaw-Chiba (1997), pp. 131–142.

  8. A. Turnbull M. W. Carroll D. H. Ferriss (1989) ArticleTitleAnalysis of hydrogen diffusion and trapping in a 13% chromium martensitic stainless steel Acta Metal. 37 IssueID7 2039–2046

    Google Scholar 

  9. M. A. Iino (1982) ArticleTitleMore generalized analysis of hydrogen tapping Acta Metal. 30 367–375

    Google Scholar 

  10. E. Lunarska A. Mikeladze (1997) ArticleTitleEffect of second phase particles on hydrogen embrittlement of iron alloys Int. J. Hydrogen Energy 22 IssueID2/3 131–139

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Published in Fizyko-Khimichna Mekhanika Materialiv, Vol. 40, No. 3, pp. 88–94, May–June, 2004.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lunarska, E., Chernyaeva, O. Effect of precipitates on hydrogen transport and hydrogen embrittlement of aluminum alloys. Mater Sci 40, 399–407 (2004). https://doi.org/10.1007/PL00022004

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/PL00022004

Keywords

Navigation