Skip to main content
SpringerLink
Log in

Relation between main- and normal-mode relaxation. A dielectric study on poly (propyleneoxide)

  • Chapter
  • First Online:
Application of Scattering Methods to the Dynamics of Polymer Systems

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 91))

Abstract

The relation between main- and normal-mode relaxation is studied on poly(propyleneoxide) of different molecular weights by dielectric measurements in a very large frequency range. The evaluation by a special technique shows a merging of α-relaxation and of normal-mode relaxation at an essential higher temperature than the Vogel temperature of the α-relaxation. This means the Rouse model is not applicable to the normal-mode relaxation near the glass transition temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Baur ME, Stockmayer WH (1965) J Chem Phys 43:4319

    Article  CAS  Google Scholar 

  2. Stockmayer WH, Burke JJ (1969) Macromolecules 2:647

    Article  CAS  Google Scholar 

  3. Alper T, Barlow A, Gray R (1976) Polymer 17:665

    Article  CAS  Google Scholar 

  4. Bakule R, Stoll B (1977) Colloid Polym Sci 255:1176

    Article  CAS  Google Scholar 

  5. Beevers MS, Elliot DA, Williams G (1979) Polymer 20:785

    Article  CAS  Google Scholar 

  6. Plazek DJ (1980) Polymer J (Japan) 12:43

    CAS  Google Scholar 

  7. Adachi K, Kotaka T (1984) Macromolecules 17:120

    Article  CAS  Google Scholar 

  8. Johari GP (1986) Polymer 27:866

    Article  CAS  Google Scholar 

  9. Boese D, Kremer F (1990) Macromolecules 23:829

    Article  CAS  Google Scholar 

  10. Vogel H (1921) Z Phys 22:645

    CAS  Google Scholar 

  11. Fulcher GS (1925) J Amer Chem Sco 8:339, 789

    CAS  Google Scholar 

  12. Ngai KL, Plazek PJ (1986) J Polym Sci Polym Phys Ed 24:619

    Article  CAS  Google Scholar 

  13. Ngai KL, Plazek DJ, Deo SS (1987) Macromolecules 20:3047

    Article  CAS  Google Scholar 

  14. Schlosser E, Schönhals A (1991) Polymer 32:2135

    Article  CAS  Google Scholar 

  15. Schlosser E, Schönhals A (1989) Colloid Polym Sci 267:963

    Article  CAS  Google Scholar 

  16. Schlosser E (1962) Plaste Kautschuk 9:582

    Google Scholar 

  17. Schlosser E, Horn G (1963) Z Exp Techn Physik 11:145

    Google Scholar 

  18. Havriliak S, Negami S (1966) J Polym Sci, Polym Symp 14:89

    Google Scholar 

  19. Heinrich G, Alig I, Donth E (1988) Polymer 29:1198

    Article  CAS  Google Scholar 

  20. Alig I, Donth E, Schenk W, Hörig S, Wohlfarth Ch (1988) Polymer 29:2081

    Article  CAS  Google Scholar 

  21. Fleicher G, Helmstedt M, Alig I (1990) Polym Comm 31:409

    Google Scholar 

  22. Schönhals A (1992) Macromolecules, to be submitted

    Google Scholar 

  23. Ngai KL, Schönhals A, Schlosser E (1992) Macromolecules, in press

    Google Scholar 

  24. Adam G, Gibbs JH (1965) J Chem Phys 43:139

    Article  CAS  Google Scholar 

  25. Donth E (1981) Glasübergang. Akademie-Verlag, Berlin

    Google Scholar 

  26. Fischer EW, Donth E, Steffen W (1992) Phys Rev Lett 68:2344

    Article  CAS  Google Scholar 

  27. Sillescu H (1991) Application of Scattering Methods to the Dynamics of Polymer Systems, 27th Europhysics Conf, Macromolecular Phys, Heraklion, Crete, Greece

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Zentrum für Makromolekulare Chemie, Rudower Chaussee 5, D-O-1199, Berlin, FRG

    E. Schlosser & A. Schönhals

Authors
  1. E. Schlosser
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Schönhals
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

B. Ewen E. W. Fischer G. Fytas

Rights and permissions

Reprints and permissions

Copyright information

© 1993 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

About this chapter

Cite this chapter

Schlosser, E., Schönhals, A. (1993). Relation between main- and normal-mode relaxation. A dielectric study on poly (propyleneoxide). In: Ewen, B., Fischer, E.W., Fytas, G. (eds) Application of Scattering Methods to the Dynamics of Polymer Systems. Progress in Colloid & Polymer Science, vol 91. Steinkopff. https://doi.org/10.1007/BFb0116484

Download citation

  • DOI: https://doi.org/10.1007/BFb0116484

  • Received:

  • Accepted:

  • Published:

  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-0952-8

  • Online ISBN: 978-3-7985-1678-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation