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Interrelation of phase and relaxation behavior in polymer blends and block copolymers with crystallizable components

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Relaxation in Polymers

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 80))

Abstract

Coupling of demixing and glass transition in polymer blends and block copolymers having the liquid-liquid separation curves with both the upper and the lower critial separation temperatures is discussed. Particularly, in the latter case a transition from liquid to glassy state at increased temperature was found. Crystallization kinetics and morphology of polymer blends and block copolymers under superposition of demixing and crystallization was studied, and their interaction and coupling was found manifested in formation of various non-equilibrium morphologies and abnormal increase of crystallization rate at the separation boundary. The morphology is determined by the ratio of demixing and crystallization rates.

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Authors and Affiliations

  1. Karpov Institute of Physical Chemistry, ul. Obukha 10, 103064, Moscow, USSR

    Yu. D. Shibanov & Yu. K. Godovsky

Authors
  1. Yu. D. Shibanov
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  2. Yu. K. Godovsky
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Editor information

M. Pietralla W. Pechhold

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© 1989 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Shibanov, Y.D., Godovsky, Y.K. (1989). Interrelation of phase and relaxation behavior in polymer blends and block copolymers with crystallizable components. In: Pietralla, M., Pechhold, W. (eds) Relaxation in Polymers. Progress in Colloid & Polymer Science, vol 80. Steinkopff. https://doi.org/10.1007/BFb0115422

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  • DOI: https://doi.org/10.1007/BFb0115422

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-0832-3

  • Online ISBN: 978-3-7985-1689-2

  • eBook Packages: Springer Book Archive

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