Skip to main content

Hemicellulases in the bleaching of chemical pulps

  • Chapter
  • First Online:
Biotechnology in the Pulp and Paper Industry

Part of the book series: Advances in Biochemical Engineering/Biotechnology ((ABE,volume 57))

Abstract

Hemicellulase-aided bleaching is the first full-scale biotechnical application in the pulp and paper industry which truly exploits the unique specificity and safety of biocatalysts. Hemicellulases are used to modify the structure of xylan and glucomannan in pulp fibers in order to enhance the chemical delignification. This technology can be combined with various types of kraft pulping processes and bleaching sequences. The aims of the enzymatic treatment depend on the actual mill conditions, and may be related to environmental demands, reduction of chemical costs, or maintenance or even improvement of product quality. The technology is applied on the mill scale in several countries. This review describes the principles of the enzyme-aided bleaching, the composition of the fiber substrates, the basic enzymology involved, and the present knowledge of the mechanisms of the action of enzymes, as well as the practical results and advantages obtained on the laboratory and industrial scale.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Viikari L, Ranua M, Kantelinen A, Sundquist J, Linko M (1986) Bleaching with enzymes. Proc 3rd Int Conf Biotechnology in the Pulp and Paper Industry, STFI, Stockholm, Sweden, p 67

    Google Scholar 

  2. Viikari L, Ranua M, Kantelinen A, Linko M, Sundquist J (1987) Application of enzymes in bleaching. Proc 4th Int Symp Wood and Pulping Chemistry, Paris, France, p 151

    Google Scholar 

  3. Puls J, Poutanen K, Körner H-U, Viikari L (1985) Appl Microbiol Biotechnol 22: 416

    Article  CAS  Google Scholar 

  4. Paice MG and Jurasek L (1984) J Wood Chem Technol 4: 187

    CAS  Google Scholar 

  5. Lavielle P, Koljonen M, Piiroinen P, Koponen R, Reid D, Fredriksson R (1992) Three large scale uses of xylanases in kraft pulp bleaching. Proc 4th Int Conf New Available Techniques and Current Trends, Eur Pulp and Paper Week, Bologna, Italy, p 203

    Google Scholar 

  6. Viikari L, Kantelinen A, Sundqvist J, Linko M (1994) FEMS Microb Rev 13: 335

    Article  CAS  Google Scholar 

  7. Paice MG, Bourbonnais R, Reid ID (1995) Tappi J 78: 161

    CAS  Google Scholar 

  8. Call HP, Mücke I (1995) Further improvements of the Laccase-Mediator-System (LMS) for enzymatic delignification (bleaching) and results from large scale trials. 1995 Int Non-Chlorine Bleaching Conf, Abstracts, Amelia Island, FL

    Google Scholar 

  9. Bajpai P, Bajpai PK (1992) Process Biochem 27: 319

    Article  CAS  Google Scholar 

  10. Onysko KA (1993) Biotech Adv 11: 179

    Article  CAS  Google Scholar 

  11. Denault C, Leduc C, Valade JL (1994) Tappi J 77: 125

    Google Scholar 

  12. Tolan JS (1992) The use of enzymes to enhance pulp bleaching. Proc TAPPI Pulping Conf, Book 1, Boston MA, p 13

    Google Scholar 

  13. Sjöström E (1993) Wood Chemistry, Fundamentals and Application, 2 edn, Academic Press Inc, San Diego, CA

    Google Scholar 

  14. Meier H (1985) Localization of Polysaccharides in Wood Cell Walls. In: Higuchi T (ed) Biosynthesis and Biodegradation of Wood Components, Academic Press, Orlando, FL p 43

    Google Scholar 

  15. McDonough TJ (1995) Tappi J 78: 55

    CAS  Google Scholar 

  16. Malinen R, Fuhrmann A (1995) Paper Timber 77: 78

    Google Scholar 

  17. Süss HU, Eul W, Helmling O (1989) Das Papier 43: 318

    Google Scholar 

  18. Hamilton JK, Partlow EV, Thompson NS (1958) Tappi 41: 803

    CAS  Google Scholar 

  19. Croon I, Enström BF (1961) Tappi 44: 870

    CAS  Google Scholar 

  20. Teleman A, Harjunpää V, Tenkanen M, Buchert J, Hausalo T, Drakenberg T, Vuorinen T (1995) Carbohydr Res 272: 55

    Article  CAS  Google Scholar 

  21. Buchert J, Teleman A, Harjunpää V, Tenkanen M, Viikari L, Vuorinen T (1995) Tappi J 78: 125

    CAS  Google Scholar 

  22. Yllner S, Enström B (1956) Svensk Papperstidn 59: 229

    CAS  Google Scholar 

  23. Yllner S, Östberg K, Stockman L (1957) Svensk Papperstidn 60: 795

    CAS  Google Scholar 

  24. Rydholm SA (1965) Pulp processes. Interscience, New York, p 596

    Google Scholar 

  25. Mitikka M, Teeäär R, Tenkanen M, Laine J, Vuorinen T (1995) Sorption of xylans on cellulose fibers. Proc 8th Int Symp Wood and Pulping Chem, Vol III, Helsinki, p 231

    Google Scholar 

  26. Simonsson R (1971) Svensk Papperstidn 74: 691

    Google Scholar 

  27. Jansson J, Palenius I, Stenlund B, SÃ¥gfors, P-E (1975) Paperi ja Puu 57: 387

    Google Scholar 

  28. Laine J, Stenius P, Carlsson G, Ström G (1994) Cellulose 1: 145

    Article  CAS  Google Scholar 

  29. Heijnesson A, Simonson R, Westermark U (1995) Holzforschung 49: 313

    CAS  Google Scholar 

  30. Buchert J, Carlsson G, Viikari L, Ström G (1996) Holzforschung 50: 69

    CAS  Google Scholar 

  31. Suurnäkki A, Heijnesson A, Buchert J, Viikari L, Westermark U (1996) J Pulp Paper Sci 22:J43

    Google Scholar 

  32. Aurell R, Hartler N (1965) Svensk Papperstidn 68: 59

    CAS  Google Scholar 

  33. Casebier RL, Hamilton JL (1965) Tappi 48: 664

    CAS  Google Scholar 

  34. Luce JE (1964) Pulp Paper Mag Can 65: T419

    Google Scholar 

  35. Krause T (1967) Das Papier 21: 385

    CAS  Google Scholar 

  36. Gibblewhite RP, Brookes D (1976) Wood Sci Technol 10: 39

    Article  Google Scholar 

  37. Scott RW (1984) J Wood Chem Technol 4: 199

    CAS  Google Scholar 

  38. Bachner K, Fischer K, Bäucker E (1993) Das Papier 10A: V30

    Google Scholar 

  39. Annegren GE, Rydholm SA (1959) Svensk Papperstidn 62: 737

    Google Scholar 

  40. Kallmes O (1960) Tappi 43: 143

    CAS  Google Scholar 

  41. Koeppen A von (1964) Tappi 47: 589

    CAS  Google Scholar 

  42. Biely P (1985) Trends in Biotechnology 3: 286

    Article  CAS  Google Scholar 

  43. Poutanen K (1988) Characterization of xylanolytic enzymes for potential applications. PhD Thesis, Technical Research Centre of Finland, Publications 47, Espoo, Finland

    Google Scholar 

  44. Eriksson K-E, Blanchette RA, Ander P (1990) Microbial and Enzymatic Degradation of Wood and Wood Components. Timell TE (ed), Springer, Berlin Heidelberg New York

    Google Scholar 

  45. Wong KKY, Saddler JN (1992) Critical Revs Biotechnol 12: 413

    CAS  Google Scholar 

  46. Coughlan MP, Hazlewood GP (1993) Biotechnol Appl Biochem 17: 259

    CAS  Google Scholar 

  47. Wong KKY, Tan LUL, Saddler JN (1988) Microbiol Revs 52: 305

    CAS  Google Scholar 

  48. Viikari L, Tenkanen M, Buchert J, Rättö M, Bailey M, Siika-aho M, Linko M (1993) Hemicellulases for industrial applications. In: Saddler JN (ed) Bioconversion of Forest and Agricultural Plant Residues, CAB International, Wallingford, UK, p 131

    Google Scholar 

  49. Henrissat B and Bairoch A (1993) Biochem J 293: 781

    CAS  Google Scholar 

  50. Biely P, Kluepfel D, Morosoli R, Shareck F (1993) Biochim Biophys Acta 1162: 246

    CAS  Google Scholar 

  51. Nishitani K, Nevins DJ (1991) J Biol Chem 266: 6539

    CAS  Google Scholar 

  52. Tuohy MG, Puls J, Clayssens M, Vrsanskas M, Coughlan MP (1993) Biochem J 290: 515

    CAS  Google Scholar 

  53. Okada H (1989) Adv Prot Des 12: 81

    CAS  Google Scholar 

  54. Campbell RL, Rose DR, Wakarchuk WW, To R, Sung W, Yaguchi M (1993) Comparison of the structures of the 20 kd xylanases from Trichoderma harzianum and Bacillus circulans. Proceedings of the Second TRICEL Symposium on Trichoderma Cellulases and Other Hydrolases, Foundation for Biotechnical and Industrial Fermentation Research, Helsinki, p 63

    Google Scholar 

  55. Törrönen A, Harkki A, Rouvinen J (1994) EMBO J 13: 2493

    Google Scholar 

  56. Törrönen A, Rouvinen J (1995) Biochemistry 34: 847

    Article  Google Scholar 

  57. Hazlewood GP, Gilbert HJ (1992) In: Visser J, Beldman G, Kusters-van Someren MA, Voragen AGJ (eds) Xylan and Xylanases. Elsevier, Amsterdam, p 259

    Google Scholar 

  58. Sakka K, Kojima Y, Kondo T, Karita S, Ohmiya K, Shimada K (1993) Biosci Biotech Biochem 57: 273

    CAS  Google Scholar 

  59. Winterhalter C, Liebl W (1995) Appl Environm Microbiol 61: 1810

    CAS  Google Scholar 

  60. Shareck F, Roy C, Yaguchi M, Morosoli R, Kluepfel D (1991) Gene 107: 75

    Article  CAS  Google Scholar 

  61. Irving D, Jung ED, Wilson DB (1994) Appl Environm Microbiol 60: 763

    Google Scholar 

  62. Honda H, Kudo T, Ikura Y, Horikoshi K (1985) Can J Microbiol 31: 538

    Article  CAS  Google Scholar 

  63. Nakamura S, Wakabayashi K, Nakai R, Aono R, Horikoshi K (1993) Appl Environm Microbiol 59: 2311

    CAS  Google Scholar 

  64. Bragger JM, Daniel RM, Coolbear T, Morgan HW (1989) Appl Microbiol Biotechnol 31: 556

    Article  CAS  Google Scholar 

  65. Simpson HD, Haufler UR, Daniel RM (1991) Biochem J 277: 413

    CAS  Google Scholar 

  66. Sunna A, Pils J, Antranikian A (1994) Characterization of the xylanolytic enzyme system of the thermophilic eubacterium Thermotoga thermarum, In: Proc 6th European Congress on Biotechnology, Elsevier, Amsterdam, p 267

    Google Scholar 

  67. Saul DJ, Williams LC, Reeves RA, Gibbs MD, Berqvist PL (1995) Appl Environm Microbiol 61: 4110

    CAS  Google Scholar 

  68. Berqvist P (1995) Hemicellulolytic enzymes from extremely thermophilic bacteria-applications of molecular genetics to pulp bleaching. Proceedings of the 8th International Symposium on Wood and Pulping Chemistry, vol I, Helsinki, p 263

    Google Scholar 

  69. McCleary BV (1991) Comparison of endolytic hydrolases that depolymerize 1,4-β-D-mannan, 1,5-α-L-arabinan and 1,4-β-D-galactan. In: Leatham GF, Himmel ME (eds) Enzymes in Biomass Conversion. ACS Symp Ser 460, American Chemical Society, Washington, p 437

    Google Scholar 

  70. Kusakabe I, Park GG, Kumita N, Yasui T, Murakami K (1988) Agr Biol Chem 52: 519

    CAS  Google Scholar 

  71. Stålbrand H, Saloheimo A, Vehmaanperä J, Henrissat B, Penttilä M (1995) Appl Environm Microbiol 61: 1090

    Google Scholar 

  72. Tenkanen M, Buchert J, Viikari L (1995) Enz Microbiol Technol 17: 499

    Article  CAS  Google Scholar 

  73. Morris DD, Reeves RA, Gibbs MD, Saul DJ, Berqvist PL (1995) Appl Environm Microbiol 61: 2262

    CAS  Google Scholar 

  74. Adams MWW, Kelly RM (1995) Chem Eng 73: 32

    CAS  Google Scholar 

  75. Horikoshi K (1991) Mannan degrading enzymes produced by Bacillus species AM-001. In: Leatham GF, Himmel ME (eds) Enzymes in Biomass Conversion. ACS Symp Ser 460, American Chemical Society, Washington, p 52

    Google Scholar 

  76. Margolles-Clark E, Tenkanen M, Söderlund H, Penttilä M (1996) European J Biochem (in press)

    Google Scholar 

  77. Stone JE, Scallan AM, Donefer E, Ahlgren E (1969) Adv Chem Ser 95: 219

    Article  CAS  Google Scholar 

  78. Grethlein HE (1985) Bio/Technol 1: 155

    Article  Google Scholar 

  79. Wong KKY, Deverell KF, Macie KL, Clark TA, Donaldson LA (1988) Biotechnol Bioeng 31: 447

    Article  CAS  Google Scholar 

  80. Page DH (1976) Wood Fiber 7: 246

    CAS  Google Scholar 

  81. Puls J, Poutanen K, Lin JJ (1990) Accessibility of hemicellulose in hardwood pulps to enzymes. In: Kirk KT, Chang H-M (eds) Biotechnology in Pulp and Paper Manufacture. Butterworth-Heinemann, Boston, p 183

    Google Scholar 

  82. Yamasaki T, Hosoya S, Chen C-L, Gratzl JS, Chang H-M (1981) Characterization of residual lignin in kraft pulp. Proc Int Symp Wood Pulp Chem, Stockholm, p 234

    Google Scholar 

  83. Iversen T, Wännström S (1986) Holzforschung 40: 19

    CAS  Google Scholar 

  84. Gellerstedt G, Lindfors E-L (1991) On the structure and reactivity of residual lignin in kraft pulp fibres. Proc Int Pulp Bleaching Conf, vol 1, SPCI, Stockholm, p 73

    Google Scholar 

  85. Stone JE, Scallan AM (1968) Pulp Paper Mag Can 69: T288

    Google Scholar 

  86. Kantelinen A, Hortling B, Sundqvist J, Linko M, Viikari M (1993) Holzforschung 47: 318

    CAS  Google Scholar 

  87. Yang JL, Eriksson K-EL (1992) Holzforschung 46: 481

    CAS  Google Scholar 

  88. Hortling B, Korhonen M, Buchert J, Sundqvist J, Viikari L (1994) Holzforschung 48: 441

    CAS  Google Scholar 

  89. Patel RN, Grabski AC, Jeffries TW (1993) Appl Microbiol Biotechnol 39: 405.

    Article  CAS  Google Scholar 

  90. Wong KKY, Clarke P, Nelson SL (1996) ACS Symp Ser 618, p 352

    Google Scholar 

  91. Suurnäkki A, Heijnesson A, Buchert J, Westermark U, Viikari L (1996) J Pulp Paper Sci 22: J91

    Google Scholar 

  92. Pedersen LS, Kihlgren P, Nielsen AM, Munk N, Holm HC, Choma PP (1992) Enzymatic bleach boosting of kraft pulp laboratory and mill scale experiences. Proc Tappi 1992 Pulping Conf, Book 1, Tappi Press, Atlanta, GA, p 31

    Google Scholar 

  93. Suurnäkki A, Kantelinen A, Buchert J, Viikari L (1994) Tappi J 77: 211

    Google Scholar 

  94. Allison R, Clark T, Suurnäkki A (1995) Effect of modified kraft pulping on enzyme-assisted bleaching. Proc 49th Appita Ann General Conf, Hobart, Tasmania, p 157

    Google Scholar 

  95. Suurnäkki A, Clark T, Allison R, Viikari L, Buchert J (1996) Tappi J 79: 111

    Google Scholar 

  96. Munk N, Nissen AM, Vollmond T, Lund H (1992) Bleach boosting with xylanases: recent research results. Proc 47th Appita Ann Gen Conf, Vol 1, Rotorua, New Zealand, p 257

    Google Scholar 

  97. Mora F, Ruel K, Comtat J, Joseleau J-P (1986) Holzforschung 40: 85

    Article  CAS  Google Scholar 

  98. Allison RW, Clark TA, Ellis MJ (1995) Appita 48: 201

    CAS  Google Scholar 

  99. De Jong E, Wong KKY, Windsor LR, Saddler JN (1996) Xylanase prebleaching of model pulps. In: Messner K, Srebotnik E (eds) Biotechnology in Pulp and Paper Industry-Advances in Applied and Fundamental Research, WUA Universitätsverlag, Vienna, p 127

    Google Scholar 

  100. Suurnäkki A (1996) PhD Thesis, Technical Research Centre of Finland, Publications 267, Espoo, Finland

    Google Scholar 

  101. Saake B, Clark T, Puls J (1995) Holzforschung 49: 60

    CAS  Google Scholar 

  102. Suurnäkki A, Heijnesson A, Buchert J, Tenkanen M, Viikari L, Westermark U (1996) J Pulp Paper Sci 22: J78

    Google Scholar 

  103. Farrell RL, Viikari L, Senior DJ (1996) Enzyme treatments of pulp. In: Dence CW, Reeve DW (eds) Pulp Bleaching. Tappi Press, Atlanta, p 363

    Google Scholar 

  104. Gellestedt G, Li J-B (1995) Xylan degradation products from birch kraft pulp, Proc 8th International Symposium on Wood and Pulping Chemistry, Helsinki, p 533

    Google Scholar 

  105. Vuorinen T, Teleman A, Fagerström P, Buchert J, Tenkanen M (1996) Selective hydrolysis of hexenuronic acid groups and its application in ECF and TCF bleaching of kraft pulps, International Pulp Bleaching Conference, Book 1, Washington D.C., p 43

    Google Scholar 

  106. Buchert J, Salminen J, Siika-aho M, Viikari L (1993) Holzforschung 47: 473

    CAS  Google Scholar 

  107. Clark TA, McDonald AG, Senior DJ, Mayers PR (1990) Mannanase and xylanase treatment of softwood chemical pulps: effects on pulp properties and bleachability. In: Kirk KT, Chang H-M (eds) Biotechnology in the Pulp and Paper Manufacture. Butterworth-Heinemann, Boston, p 153

    Google Scholar 

  108. Bailey MJ, Biely P, Poutanen K (1992) J Biotechnol 23: 257

    Article  CAS  Google Scholar 

  109. Puls J, Poutanen K, Körner H-U, Viikari L (1985) Appl Microbiol Biotechnol 22: 416

    Article  CAS  Google Scholar 

  110. Buchert J, Siika-aho M, Pere J, Valkeajärvi A, Viikari L (1993) Biotechnol Techn 7: 785

    Article  CAS  Google Scholar 

  111. Kantelinen A, Suurnäkki A, Buchert J, Hortling B, Viikari L (1993) Enzymatic solubilization of xylans in kraft pulps. Proc 7th Int Symp Wood and Pulping Chemistry, vol 2, Beijing, China, p 626

    Google Scholar 

  112. Buchert J, Ranua M, Kantelinen A, Viikari L (1992) Appl Microbiol Biotechnol 37: 825

    Article  CAS  Google Scholar 

  113. Buchert J, Tenkanen M, Viikari L, Pitkänen M (1993) Tappi J 76: 131

    CAS  Google Scholar 

  114. Scallan AM (1982) Tappi J 66: 73

    Google Scholar 

  115. Buchert J, Viikari L (1995) Paper Timber 77: 582

    CAS  Google Scholar 

  116. Paice M, Bernier M, Jurasek L (1988) Biotechnol Bioeng 32: 235

    Article  CAS  Google Scholar 

  117. Kantelinen A, Rättö M, Sundqvist J, Ranua M, Viikari L, Linko M (1988) Hemicellulases and their potential role in bleaching. Proc 1988 Int Pulp Bleaching Conf, Tappi, Orlando, FL, p 1

    Google Scholar 

  118. Viikari L, Kantelinen A, Rättö M, Sundqvist J (1991) Enzymes in pulp and paper processing. In: Leatham GF, Himmel ME (eds) Enzymes in Biomass Conversion. ACS Symp Ser 460, American Chemical Society, Washington, p 12

    Google Scholar 

  119. Tenkanen M, Buchert J, Puls J, Poutanen K, Viikari L (1992) Two main xylanases of Trichoderma reesei and their use in pulp processing. In: Kuwahara M, Shimada M (eds) Biotechnology in Pulp and Paper Processing, Elsevier, Amsterdam, p 547

    Google Scholar 

  120. Tenkanen M, Puls J, Poutanen K (1992) Enzyme Microb Technol 14: 566

    Article  CAS  Google Scholar 

  121. Rättö M, Mathrani IM, Ahring B, Viikari L (1994) Appl Microbiol Biotechnol 41: 130

    Google Scholar 

  122. Clark TA, Steward D, Bruce M, McDonald A, Singh A, Senior D (1991) Appita 44: 389

    CAS  Google Scholar 

  123. Buchert J, Ranua M, Siika-aho M, Pere J, Viikari L (1994) Appl Microbiol Biotechnol 40: 941

    Article  CAS  Google Scholar 

  124. Buchert J, Kantelinen A, Suurnäkki A, Viikari L, Jansson J (1995) Holzforschung 49: 439

    Article  CAS  Google Scholar 

  125. Christov LP, Prior BA (1994) Appl Microbiol Biotechnol 42: 492

    CAS  Google Scholar 

  126. Koponen R (1991) Pulp Paper Int 33: 20

    Google Scholar 

  127. Ledoux P, Detroz R, deBuyl E, Shetty J, Troughton N, Presley JR (1993) Use of bacterial xylanase in chlorine-free bleaching sequences. Proc TAPPI pulping Conf, Atlanta, GA, p 1057

    Google Scholar 

  128. Yang JL, Lu G, Eriksson K-EL (1992) Tappi J 75: 95

    CAS  Google Scholar 

  129. Yang JL, Lu G, Eriksson K-EL (1993) Tappi J 76: 91

    CAS  Google Scholar 

  130. Yang JL, Cates DH, Law SE, Eriksson K-EL (1994) Tappi J 77: 243

    CAS  Google Scholar 

  131. Paice MG, Bernier R, Jurasek L (1988) Biotechnol Bioeng 32: 235

    Article  CAS  Google Scholar 

  132. Pere J, Siika-aho M, Buchert J, Viikari L (1995) Tappi J 78: 71

    CAS  Google Scholar 

  133. Werthemann DP, Tannar D, Koljonen M (1993) Enzymatic pre-bleaching of Pinus radiata pulp. Proc 47th Appita Ann Gen Conf, vol 1, Rotorua, New Zealand, p 249

    Google Scholar 

  134. Jäger A, Sinner M, Purkarthofer H, Esterbauer H, Ditzelmüller G (1992) Biobleaching with xylanase from thermophilic fungus. In: Kuwahara M, Shimida M (eds) Biotechnology in the Pulp and Paper Industry, UNI Publishers Co, Tokyo Japan, p 115

    Google Scholar 

  135. Scott BP, Young F, Paice MG (1993) Pulp Paper Canada 94: T75

    Google Scholar 

  136. Jean P, Hamilton J, Senior DJ (1994) Mill trial experiences with xylanase: AOX and chemical reductions. Proc 80th CPPA Ann Meeting, Montreal, Quebec, Canada, p 229

    Google Scholar 

  137. Dunlop-Jones N, Grönberg V (1994) Recent developments in the application of xylanase enzymes in elemental chlorine-free (ECF) and total chlorine-free (TCF) bleaching. Proc 80th CPPA Ann Meeting, Montreal, Quebec, Canada, p 191

    Google Scholar 

  138. Turner JC, Skerker PS, Burns BJ, Howard JC, Alonso MA, Andres JL (1992) Tappi J 75: 83

    CAS  Google Scholar 

  139. Senior DJ, Hamilton J, Bernier RL, du Manior JR (1992) Tappi J 75: 125

    CAS  Google Scholar 

  140. Eriksson K-E (1995) Svensk Papperstidn 98: 55

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

K. -E. L. Eriksson (Volume Editor)W. Babel H. W. Blanch Ch. L. Cooney S. -O. Enfors K. -E. L. Eriksson A. Fiechter A. M. Klibanov B. Mattiasson S. B. Primrose H. J. Rehm P. L. Rogers H. Sahm K. Schügerl G. T. Tsao K. Venkat J. Villadsen U. von Stockar C. Wandrey

Rights and permissions

Reprints and permissions

Copyright information

© 1997 Springer-Verlag 0223 0247 V 2

About this chapter

Cite this chapter

Suurnäkki, A., Tenkanen, M., Buchert, J., Viikari, L. (1997). Hemicellulases in the bleaching of chemical pulps. In: Eriksson, K.E.L., et al. Biotechnology in the Pulp and Paper Industry. Advances in Biochemical Engineering/Biotechnology, vol 57. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0102077

Download citation

  • DOI: https://doi.org/10.1007/BFb0102077

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-61868-3

  • Online ISBN: 978-3-540-70702-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics