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Fluorine-containing polymers. II. Polytetrafluoroethylene

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Fortschritte Der Hochpolymeren-Forschung

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Bibliography

  • Allan, A. J. G.: Wettability and friction of polytetrafluoroethylene film: effect of prebonding treatments. J. Polymer Sci. 24, 461–466 (1957).

    CAS  Google Scholar 

  • Plastics as solid lubricants and bearings. Lubrication Eng. 14, 211–215 (1958).

    CAS  Google Scholar 

  • F. M. Chapman: Frictional properties of TFE-fluorocarbon resins. Materials in Design Eng. 48, 106–108 (1958).

    Google Scholar 

  • R. Roberts: Wettability of perfluorocarbon polymer films: effect of roughness. J. Polymer Sci. 39, 1–8 (1959).

    CAS  Google Scholar 

  • Beecroft, R. I., and C. A. Swenson: Behavior of polytetrafluoroethylene (Teflon) under high pressures. J. Appl. Phys. 30, 1793–1798 (1959).

    Article  CAS  Google Scholar 

  • Bernett, M. K., and W. A. Zisman: Wetting of low-energy solids by aqueous solutions of highly fluorinated acids and salts. J. Phys. Chem. 63, 1911–1916 (1959).

    CAS  Google Scholar 

  • Berry, K. L., and J. H. Peterson: Tracer studies of oxidation-reduction polymerization and molecular weight of Teflon tetrafluoroethylene resin. J. Am. Chem. Soc. 73, 5195–5197 (1951).

    Article  CAS  Google Scholar 

  • Bowden, F. P.: Frictional properties of porous metal impregnated with plastic. Research (London) 3, 147–168 (1950).

    Google Scholar 

  • Friction on snow and ice. Proc. Roy. Soc. A 217, 462–478 (1953).

    Google Scholar 

  • Friction on snow and ice and the development of some fast-running skiis. Nature (London) 176, 946–947 (1955).

    Google Scholar 

  • Brandt, W.: Calculation of compressibilities of high polymers from the energy of interaction between chains. J. Chem. Phys. 26, 262–270 (1957).

    Article  CAS  Google Scholar 

  • Bridgman, P. W.: Rough compressions of 177 substances to 40,000 kg/cm2. Proc. Am. Acad. Arts Sci. 76, 71–74 (1948).

    CAS  Google Scholar 

  • Bro, M. I.: The stability of fluorine-containing polymers to amines. J. Appl. Polymer Sci. 1, 310–312 (1959).

    CAS  Google Scholar 

  • C. A. Sperati: End groups in tetrafluoroethylene polymers. J. Polymer Sci. 38, 289–205 (1959).

    CAS  Google Scholar 

  • Brodhun, C. G.: Dielectric breakdown of polymers under prolonged stress. Phys. Rev. 86, 653 (1952).

    CAS  Google Scholar 

  • Brunauer, S., P. H. Emmett and E. Teller: Adsorption of gases in multimole-cular layers. J. Am. Chem. Soc. 60, 309–319 (1938).

    Article  CAS  Google Scholar 

  • Bryant, W. M. D.: Free energies of formation of fluorocarbons and their radicals. Thermodynamics of formation and depolymerization of polytetrafluoroethylene. J. Polymer Sci., in press.

    Google Scholar 

  • Bunn, C. W., and E. R. Howells: Structures of molecules and crystals of fluorocarbons. Nature (London) 174, 549–551 (1954).

    CAS  Google Scholar 

  • A. J. Cobbold and R. P. Palmer: The fine structure of polytetrafluoroethylene. J. Polymer Sci. 28, 365–376 (1958).

    CAS  Google Scholar 

  • Chapiro, A.: Preparation of graft copolymers of polytetrafluoroethylene by radio-chemistry. J. Polymer Sci. 34, 481–501 (1959).

    CAS  Google Scholar 

  • Charlesby, A.: How radiation affects long-chain polymers. Nucleonics 12, 18–25 (1954).

    CAS  Google Scholar 

  • Some radiation effects in long chain polymers. Plastics Institute Trans. 23, 133–138 (1955).

    CAS  Google Scholar 

  • Chen, W. K. W., R. B. Mesrobian, D. S. Ballantine, D. J. Metz and A. Glines: Studies of graft copolymers derived by ionizing radiation. J. Polymer Sci. 23, 903–913 (1957).

    CAS  Google Scholar 

  • Clark, E. S., and L. T. Muus: Unusual features in the crystal structure of polytetrafluoroethylene. Meeting of the American Chemical Society, New York, September 1957.

    Google Scholar 

  • --Intensity of bragg reflections and disorder in crystalline polymers. Meeting of the American Crystallographic Association, Milwaukee, Wisconsin, June 23, 1958.

    Google Scholar 

  • -The helical structure concept and synthetic polymers. Symposium on “Helices in macromolecular systems” at Polytechnic Institute of Brooklyn, May 16, 1959.

    Google Scholar 

  • Crescenzi, A. A., P. C. Hofstra, K. C. Sze, B. H. Foster and C. L. Claff: Development of a simplified disposable membrane oxygenator. 45th Annual Clinical Congress of the American College of Surgeons, Atlantic City, September 28, 1959.

    Google Scholar 

  • Doban, R. C., C. A. Sperati and B. W. Sandt: The physical properties of “Teflon” polytetrafluoroethylene. Soc. Plastics Engrs Journal 11, 17–21, 24, 30 (1955).

    CAS  Google Scholar 

  • -A. C. Knight, J. H. Peterson and C. A. Sperati: The molecular weight of polytetrafluoroethylene. Meeting of the American Chemical Society, Atlantic City, September 1956.

    Google Scholar 

  • -Method for the preparation of cementable fluorocarbon polymer surfaces. U. S. Patent 2,871,144 (Jan. 27, 1959) assigned to E. I. du Pont de Nemours & Co.

    Google Scholar 

  • Downing, F. B., A. F. Benning and R. C. McHarness: Octafluorocyclobutane and pyrolytic process for its production. U. S. Patent 2,384,821 (Sept. 18, 1945) U. S. Patent 2,387,247 (Oct. 23, 1945).

    Google Scholar 

  • Duus, H. C.: Thermochemical studies on fluorocarbons. Ind. Eng. Chem. 47, 1445–1449 (1955).

    Article  CAS  Google Scholar 

  • Dyment, J., and H. Ziebland: Tensile properties of plastics at low temperatures. J. Appl. Chem. (London) 8, 203–206 (1958).

    CAS  Google Scholar 

  • Ehrlich, P.: Dielectric properties of “Teflon” from room temperature to 314‡ C and from frequencies of 102 to 105 cps. J. Research Natl. Bur. Standards 51, 185–188 (1953).

    CAS  Google Scholar 

  • Elliott, E. M.: Polytetrafluoroethylene dispersions for metal finishing. Trans. Inst. Metal Finishing 33, 355–365 (1956).

    Google Scholar 

  • Fitzsimmons, V. G., and W. A. Zisman: Thin films of polytetrafluoroethylene resin (“Teflon”) as lubricants and preservative coatings for metals. NRL Report 4753. Naval Research Laboratory, Washington, D. C., June 15, 1956. See also Ind. Eng. Chem. 50, 781–784 (1958).

    Google Scholar 

  • Florin, R. E., L. A. Wall, D. W. Brown, L. A. Hymo and J. D. Michaelsen: Factors affecting the thermal stability of polytetrafluoroethylene. J. Research Natl. Bur. Standards 53, 121–130 (1954).

    CAS  Google Scholar 

  • Fowler, J. F., and F. T. Farmer: Conductivity induced in polytetrafluoroethylene by x-rays. Nature (London) 174, 136–137 (1954).

    CAS  Google Scholar 

  • Fox, H. W., and W. A. Zisman: The spreading of liquids on low energy surfaces. I. polytetrafluoroethylene. J. Colloid Sci. 5, 514–531 (1950).

    Article  CAS  Google Scholar 

  • Furukawa, G. T., R. E. McCoskey and G. J. King: Calorimetric properties of polytetrafluoroethylene (“Teflon”) from 0‡ to 365‡ K. J. Research Natl. Bur. Standards 48, 273–278 (1952).

    Google Scholar 

  • Hals, L. T., T. S. Reid, and G. H. Smith: The preparation of terminally unsaturated perfluoroolefins by the decomposition of the salts of perfluoro acids. J. Am. Chem. Soc. 73, 4054 (1951).

    Article  Google Scholar 

  • Hanford, W. E., and R. M. Joyce: Polytetrafluoroethylene. J. Am. Chem. Soc. 68, 2082–2085 (1946).

    Article  CAS  Google Scholar 

  • Haszeldine, R. N.: The addition of free radicals to unsaturated systems. IV. the direction of radical addition to hexafluoropropene. J. Chem. Soc. 3559–3564 (1953).

    Google Scholar 

  • Hippel, A. R. von: Dielectric materials and applications. New York: Technology Press of MIT and John Wiley 1954.

    Google Scholar 

  • Hyndman, D., and G. F. Origlio: NMR absorption in “Teflon” fibers. J. Applied Physics 31, 1849–1852 (1960).

    Article  CAS  Google Scholar 

  • Illers, K. H., and E. Jenckel: Mechanische Relaxationserscheinungen in Polytetrafluoräthylen. Kolloid-Z. 160, 97–106 (1958).

    Article  CAS  Google Scholar 

  • James, D. D.: Molding and extrusion of “Teflon”. India Rubber World 124, 68–70 (1951).

    Google Scholar 

  • Kabin, S. P.: On the dynamic mechanical properties of polyethylene and polytetrafluoroethylene. Soviet Physics Technical Physics 1, 2542–2546 (1956).

    Google Scholar 

  • Kilian, H. G., and E. Jenckel: The melting and crystallization of some high-polymeric substances as observed by x-ray analysis. Z. Elektrochem. 63, 308–321 (1959).

    CAS  Google Scholar 

  • Kiyama, R., J. Osugi and S. Kusuhara: Studies on explosive reactions of tetra-fluoroethylene and acetylene with oxygen or air. Rev. Phys. Chem. Jap. 27, 22–41 (1957).

    CAS  Google Scholar 

  • Krum, F., and F. H. Muller: Vorbehandlung und dielektrisches Verhalten Hochpolymerer. Kolloid-Z. 164, 81–107 (1959).

    Article  Google Scholar 

  • Leksina, I. E., and S. I. Novikova: Thermal expansion of fluoroplast between −190 and 325‡ C. Sov. Phys. Solid State 1, 453–459 (1959).

    CAS  Google Scholar 

  • Lewis, E. E., and M. A. Naylor: Pyrolysis of polytetrafluoroethylene. J. Am. Chem. Soc. 69, 1968–1970 (1947).

    CAS  Google Scholar 

  • and C. M. Winchester: Rheology of lubricated polytetrafluoroethylene compositions — equipment and operating variables. Ind. and Eng. Chem. 45, 1123–1127 (1953).

    CAS  Google Scholar 

  • Liang, C. Y., and S. Krimm: Infrared spectra of high polymers III. polytetrafluoroethylene and polychlorotrifluoroethylene. J. Chem. Physics 25, 563–571 (1956).

    CAS  Google Scholar 

  • Locke, E. G., W. R. Brode and A. L. Henne: Fluorochloroethanes and fluoro-chloroethylenes. J. Am. Chem. Soc. 56, 1726–1728 (1934).

    Article  CAS  Google Scholar 

  • Lontz, J. F., and W. B. Happoldt jr.: “Teflon” tetrafluoroethylene resin dispersion. A new aqueous colloidal dispersion of polytetrafluoroethylene. Ind. and Eng. Chem. 44, 1800–1805 (1952).

    CAS  Google Scholar 

  • J. A. Jaffe, L. E. Robb and W. B. Happoldt jr.: “Teflon” tetrafluoroethylene resin dispersion-extrusion properties of lubricated resin from coagulated dispersion. Ind. and Eng. Chem. 44, 1805–1810 (1952).

    CAS  Google Scholar 

  • Lupton, J. M.: Effect of pressure on the specific volume of polymer melts. Meeting of the American Chemical Society, Chicago, September 1958.

    Google Scholar 

  • Madorsky, S. L., V. E. Hart, S. Strauss and V. A. Sedlak: Thermal degradation of tetrafluoroethylene and hydrofluoroethylene polymers. J. Research Natl. Bur. Standards 51, 327–333 (1953).

    CAS  Google Scholar 

  • Marx, P., and M. Dole: Specific heat of synthetic high polymers. V. A study of the order-disorder transition in polytetrafluoroethylene. J. Am. Chem. Soc. 77, 4771–4774 (1955).

    Article  CAS  Google Scholar 

  • Matsumae, K., M. Watanabe, A. Nishioka and T. Ichimiya: Viscosity and elasticity of gamma-irradiated polytetrafluoroethylene resin above the melting point. J. Polymer Sci. 28, 653–655 (1958).

    CAS  Google Scholar 

  • McCrum, N. G.: An internal friction study of polytetrafluoroethylene. J. Polymer Sci. 34, 355–369 (1959a).

    CAS  Google Scholar 

  • A study of internal friction in copolymers of tetrafluoroethylene and hexafluoro-propylene. Die Makromol. Chem. 34, 50–66 (1959b).

    Article  CAS  Google Scholar 

  • Torsion pendulum method for determining crystallinity and void content of tetrafluoroethylene resins. ASTM Bull. No. 242, 80–82 (1959c).

    CAS  Google Scholar 

  • McGeer, P. L., and H. C. Duus: Effect of pressure on the melting point of “Teflon” tetrafluoroethylene resin. J. Chem. Phys. 20, 1813–1814 (1952).

    Article  CAS  Google Scholar 

  • McGrew, F. C.: Some structural investigations on polytetrafluoroethylene. International Symposium on Fluorine Chemistry, Birmingham, England, July 17, 1959.

    Google Scholar 

  • Michaelsen, J. D., and L. A. Wall: Further studies on the pyrolysis of polytetrafluoroethylene in the presence of various gases. J. Research Natl. Bur. Standards 58, 327–331 (1957).

    CAS  Google Scholar 

  • Mikhailov, G. P., S. P. Kabin and A. L. Smolyanskii: Dielectric losses of polytetrafluoroethylene. J. Techn. Phys. (U.S.S.R.) 25, 2179–2182 (1955).

    CAS  Google Scholar 

  • Miyake, A.: On the rotational transition of linear high polymer crystals. Chem. High Polymers (Tokyo) 15, 153–159 (1958).

    CAS  Google Scholar 

  • Moynihan, R. E.: The molecular structure of perfluorocarbon polymer: IR studies on polytetrafluoroethylene. J. Am. Chem. Soc. 81, 1045–1050 (1959).

    Article  CAS  Google Scholar 

  • Nagamatsu, K., T. Yoshitomi and T. Takemoto: On the viscoelastic properties of crystalline polymers I. polytetrafluoroethylene. J. Colloid Sci. 13, 257–265 (1958).

    Article  CAS  Google Scholar 

  • Nelson, E. R., T. J. Kilduff and A. A. Benderly: Bonding of “Teflon”. Ind. Eng. Chem. 50, 329–330 (1958).

    Article  CAS  Google Scholar 

  • Neugebauer, C. A., and J. L. Margrave: The heats of formation of tetrafluoromethane and 1,1-difluoroethylene. J. Phys. Chem. 60, 1318–1321 (1956).

    Article  CAS  Google Scholar 

  • Nishioka, A., K. Matsumae, M. Watanabe, M. Tajima and M. Owaki: Effects of gamma radiation on some physical properties of polytetrafluoroethylene resin. J. Appl. Polymer Sci. 2, 114–119 (1959).

    CAS  Google Scholar 

  • M. Tajima, and M. Owaki: Melt fracture and crystallization of gamma irradiated polytetrafluoroethylene. J. Polymer Sci. 28, 617–619 (1958).

    CAS  Google Scholar 

  • and M. Watanabe: Viscosity and elasticity of polytetrafluoroethylene resin above the melting point. J. Polymer Sci. 24, 298–300 (1957).

    CAS  Google Scholar 

  • Pao, Y. H., and R. F. Bjorklund: Wave functions and energy eigenvalues for the polytetrafluoroethylene chain. J. Applied Physics 31, 1925–1934 (1960).

    Article  CAS  Google Scholar 

  • Pierce, R. H. H., jr., E. S. Clark, J. F. Whitney and W. M. D. Bryant: Crystal structure of polytetrafluoroethylene. Meeting of the American Chemical Society Atlantic City, September, 1956.

    Google Scholar 

  • Plunkett, R. J.: Tetrafluoroethylene polymers. U. S. Patent 2,230,654 (Feb. 4, 1941).

    Google Scholar 

  • Powles, J. G., and J. A. E. Kail: Nuclear magnetic resonance absorption in various polytetrafluoroethylenes. J. Polymer Sci. 31, 183–187 (1958).

    CAS  Google Scholar 

  • Purvis, R. J., and W. R., and W. R. Beck: Method of activating the surface of perfluorocarbon polymers and resultant article. U. S. Patent 2,789,063 (April 16, 1957) — assigned to Minnesota Mining and Mfg. Co.

    Google Scholar 

  • Quinn, F. A., jr., D. E. Roberts and R. N. Work: Volume-temperature relationships for the room temperature transition in “Teflon”. J. Appl. Physics 22, 1985–1086 (1951).

    Article  Google Scholar 

  • Rappaport, G.: Method of bonding a fluorinated synthetic resin to another material. U. S. Patent 2,809,130 (Oct. 8, 1957) — assigned to General Motors Corp.

    Google Scholar 

  • Renfrew, M. M., and E. E. Lewis: Polytetrafluoroethylene: heat-resistent, chemically inert plastic. Ind. Eng. Chem. 38, 870–877 (1946).

    Article  CAS  Google Scholar 

  • -Polymerization of tetrafluoroethylene with dibasic acid peroxide catalysts. U. S. Patent 2,534,058 (Dec. 12, 1950).

    Google Scholar 

  • Restaino, A. J., and W. N. Reed: Kinetics of the gamma-induced graft copoly-merization of vinyl acetate to “Teflon”. J. Polymer Sci. 36, 499–510 (1959).

    CAS  Google Scholar 

  • Rigby, H. A., and C. W. Bunn: A room-temperature transition in polytetrafluoroethylene. Nature (London) 164, 583 (1949).

    CAS  Google Scholar 

  • Riley, M. W.: Selection and design of fluorocarbon plastics. Materials and Methods Manual No. 138, 129–148 (June 1957).

    Google Scholar 

  • Roedel, M. J.: The molecular structure of polyethylene, I. chain branching in polyethylene during polymerization. J. Am. Chem. Soc. 75, 6110–6113 (1953).

    Article  CAS  Google Scholar 

  • Ruff, O., and O. Bretschneider: Die Bildung von Hexafluoräthan und Tetrafluoräthylen aus Tetrafluorkohlenstoff. Z. anorg. Chem. 210, 173–183 (1933).

    CAS  Google Scholar 

  • Ryan, J. W.: Radiation of polytetrafluorethylene. Modern Plastics 31, 152 (Oct. 1953).

    CAS  Google Scholar 

  • Ryland, A. L.: X-ray diffraction. J. Chem. Ed. 35, 80–83 (1958).

    CAS  Google Scholar 

  • Scott, R. L.: The anomalous behavior of fluorocarbon solutions. J. Phys. Chem. 62, 136–145 (1958).

    CAS  Google Scholar 

  • Shooter, K. V., and D. Tabor: The frictional properties of plastics. Proc. Phys. Soc. B 65, 661–671 (1952).

    Article  Google Scholar 

  • and P. H. Thomas: Frictional properties of some plastics. Research (London) 2, 533–535 (1949).

    CAS  Google Scholar 

  • Siegle, J. C., L. T. Muus and T. P. Lin: Pyrolysis of polytetrafluoroethylene. Meeting of the American Chemical Society, Atlantic City, September 1956.

    Google Scholar 

  • Sinnott, K. M.: Paper in preparation.

    Google Scholar 

  • Slichter, W. P.: Nuclear magnetic resonance in some fluorine derivatives of polythene. J. Polymer Sci. 24, 173–188 (1957).

    CAS  Google Scholar 

  • Smith, J. A. S.: A nuclear resonance investigation of polytetrafluoroethylene. Discussions Faraday Soc. No. 19, 207–215 (1955).

    CAS  Google Scholar 

  • Snelling, G. R., and J. F. Lontz: Mechanism of lubricant extrusion of “Teflon” TFE-tetrafluoroethylene resins. J. Appl. Polymer Sci. 3, 257–265 (1960).

    Google Scholar 

  • Sperati, C. A., and J. L. McPherson: The effect of crystallinity and molecular weight on physical properties of polytetrafluoroethylene. Meeting of the American Chemical Society, Atlantiv City, September 1956.

    Google Scholar 

  • Starkweather, H. W., jr., and R. H. Boyd: The entropy of melting of some linear polymers. J. Phys. Chem. 64, 410–414 (1960).

    CAS  Google Scholar 

  • Heat capacity of chain polymers at low temperatures. J. Polymer Sci. 45, 525–527 (1960).

    CAS  Google Scholar 

  • Sugita, K., S. Nagao and Y. Toriyama: The corona resisting property of polytetrafluoroethylene. Brit. J. Appl. Phys. 7, 38 (1956).

    Article  Google Scholar 

  • Swenson, A. A.: Mechanical properties of “Teflon” at low temperatures. Rev. Sci. Instr. 25, 834 (1954).

    CAS  Google Scholar 

  • Teranishi, H.: Studies on the explosions under high pressures, IV. The explosions of tetrafluoroethylene mixed with oxygen or air. Rev. Phys. Chem. Japan 28, 9–23 (1958).

    CAS  Google Scholar 

  • Thomas, P. E., J. F. Lontz, C. A. Sperati and J. L. McPherson: Effects of fabrication on the properties of “Teflon” resins. Soc. Plastics Engrs. 12, (June 1956).

    Google Scholar 

  • Torkington, P., and H. W. Thompson: The infrared spectra of fluorination hydrocarbons I. Trans. Faraday Soc. 41, 236–246 (1945).

    CAS  Google Scholar 

  • Wall, L. A., and J. D. Michaelsen: Thermal decomposition of polytetrafluoroethylene in various gaseous atmospheres. J. Research Natl. Bur. Standards 56, 27–34 (1956).

    CAS  Google Scholar 

  • and R. E. Florin: Polytetrafluoroethylene — a radiation resistant polymer. J. Appl. Polymer Sci., 2, 251 (1959).

    CAS  Google Scholar 

  • Weir, C. E.: Compressibility of natural and synthetic high polymers at high pressures. J. Research Natl. Bur. Standards 46, 207–212 (1051).

    Google Scholar 

  • Transitions and phases of polytetrafluoroethylene (“Teflon”). J. Research Natl. Bur. Standards 50, 95–97 (1953).

    CAS  Google Scholar 

  • Wilson, C. W., and G. E. Pake: Nuclear magnetic relaxation in polytetrafluoroethylene and polythene. J. Chem. Phys. 27, 115–122 (1957).

    CAS  Google Scholar 

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Sperati, C.A., Starkweather, H.W. (1961). Fluorine-containing polymers. II. Polytetrafluoroethylene. In: Fortschritte Der Hochpolymeren-Forschung. Advances in Polymer Science, vol 2/4. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0050504

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