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Plasma chemistry of fluorocarbons as related to plasma etching and plasma polymerization

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Plasma Chemistry III

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 94))

Abstract

This chapter deals with the physical and chemical processes which take place in fluorocarbon plasmas. Emphasis is given to plasma diagnostic techniques which are well suited to investigate the neutral and ionized gas phase species as well as plasma-surface interactions. Special attention is given to a description of mechanisms which control plasma etching and plasma polymerization. Structural characterization techniques which work well with a variety of fluorocarbon thin films prepared in a plasma are given and key physical properties of such films are reviewed.

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References

  1. Plasma Diagnostics, Lochte-Holtgreven, W. (ed.)., New York, Elsevier, 1968

    Google Scholar 

  2. Plasma Diagnostic Techniques, Huddlestone, R. H., Leonard, S. S. L. (ed.)., New York, Academic Press, 1965

    Google Scholar 

  3. Podgornyi, I. M.: Topics in Plasma Diagnostics, New York, Plenum Press, 1971

    Google Scholar 

  4. Yamaguchi, S., Sawa, G., Ieda, M.: J. Appl. Phys. 48, 2363 (1977)

    CAS  Google Scholar 

  5. Harrison, A. G. et al.: Can. J. Chem. 44, 1967 (1966)

    CAS  Google Scholar 

  6. Schram, B. L. et al.: J. Chem. Phys. 44, 49 (1966)

    Article  CAS  Google Scholar 

  7. Kieffer, L. J.: Atomic Data 1, 19 (1969)

    Google Scholar 

  8. Winters, H. F.: J. Chem. Phys. 44, 1472 (1966)

    CAS  Google Scholar 

  9. Winters, H. F.: J. Chem. Phys. 63, 3462 (1975)

    Article  CAS  Google Scholar 

  10. Winters, H. F.: Chem. Phys. 36, 353 (1979)

    Article  CAS  Google Scholar 

  11. Blint, R. J., McMahon, T. B., Beauchamp, J. L.: J. Am. Chem. Soc. 96, 1269 (1974)

    Article  CAS  Google Scholar 

  12. Pabst, M. J. K., Tan, H. S., Franklin, J. L.: Int. J. Mass Spectrom. & Ion Phys. 20, 191 (1976)

    CAS  Google Scholar 

  13. Krause, J. R., Lampe, F. W.: J. Phys. Chem. 81, 281 (1977)

    Article  CAS  Google Scholar 

  14. Heckel, E., Hanrahan, R. J.: J. Chem. Phys. 62, 1027 (1975)

    Article  CAS  Google Scholar 

  15. Marcotte, D. E., Hanrahan, R. J.: J. Fluorine Chem. 2, 8 (1972/3)

    Google Scholar 

  16. Coburn, J. W., Chen, M.: J. Appl. Phys. 51, 3134 (1980)

    Article  CAS  Google Scholar 

  17. Schott, L.: In Ref. 1, p. 668

    Google Scholar 

  18. Swift, J. D., Schwar, M. J. R.: Electrical Probes for Plasma Diagnostics, New York, Elsevier, 1971

    Google Scholar 

  19. Chen, F. F.: In Ref. 2, p. 113

    Google Scholar 

  20. Chung, P. M., Talbot, L. Touryan, K. J.: Electric Probes in Stationary and Flowing Plasmas: Theory and Application, New York, Springer-Verlag, 1975

    Google Scholar 

  21. Clements, R. M.: J. Vac. Sci. Technol. 15, 193 (1978)

    Article  Google Scholar 

  22. Thomas, T. L., Battle, E. L.: J. Appl. Phys. 41, 3428 (1970)

    Google Scholar 

  23. Szusczewicz, E. P., Holmes, J. C.: J. Appl. Phys. 46, 5134 (1975)

    Google Scholar 

  24. Chang, J.-S.: J. Phys. D. 6, 1674 (1973)

    Article  Google Scholar 

  25. Barnes, B. T.: J. Appl. Phys. 33, 3319 (1962)

    Google Scholar 

  26. Coburn, J. W., Winters, H. F.: J. Appl. Phys. 50, 3189 (1979), and references in this article

    CAS  Google Scholar 

  27. Thornton, J. A.: J. Vac. Sci. Technol. 15, 188 (1978)

    CAS  Google Scholar 

  28. Koenig, H. R., Maissel, L. I.: IBM J. Res. Develop. 14, 168 (1970)

    Google Scholar 

  29. Coburn, J. W., Kay, E.: J. Appl. Phys. 43, 4965 (1972).

    Article  CAS  Google Scholar 

  30. Vossen, J. L.: J. Electrochem. Soc.: 126, p. 319 (1979)

    CAS  Google Scholar 

  31. Coburn, J. W.: unpublished

    Google Scholar 

  32. Chapman, B. N., Minkiewicz, V. J.: J. Vac. Sci. Technol. 15, 329 (1979)

    Google Scholar 

  33. Hasted, J. B.: Int. J. Mass Spectrom. & Ion Phys. 16, 3 (1975)

    CAS  Google Scholar 

  34. Helm, H. et al.: J. Phys. B 7, 170 (1974)

    Article  CAS  Google Scholar 

  35. Smith, D., Plumb, I. C.: J. Phys. D 6, 1431 (1973)

    CAS  Google Scholar 

  36. Franklin, J. L., Studniarz, S. A., Ghosh, P. K.: J. Appl. Phys. 39, 2052 (1968)

    Article  Google Scholar 

  37. Vasile, M. J., Smolinsky, G.: Int. J. Mass Spectrom. & Ion Phys. 12, 133 (1973)

    CAS  Google Scholar 

  38. Rowe, B., Int. J. Mass Spectrom. & Ion Phys. 16, 209 (1975)

    CAS  Google Scholar 

  39. Foner, S. N., Hudson, R. L.: J. Chem. Phys. 21, 1374 (1953)

    CAS  Google Scholar 

  40. Fite, W. L.: Int. J. Mass Spectrom. & Ion Phys. 16, 109 (1975)

    CAS  Google Scholar 

  41. Evans, H. E., Jennings, P. P.: Carbon 6, 236 (1968)

    Google Scholar 

  42. Smolinsky, G., Vasile, M. J.: Int. J. Mass Spectrom. & Ion Phys. 12, 147 (1973); 24, 311 (1977)

    CAS  Google Scholar 

  43. Vasile, M. J., Smolinsky, G.: ibid. 13, 381 (1974); 24, 11 (1977)

    CAS  Google Scholar 

  44. Vasile, M. J., Smolinsky, G.: J. Phys. Chem. 81, 2605 (1977)

    Article  CAS  Google Scholar 

  45. Kay, E., Coburn, J. W., Kruppa, G.: Vide 183, 89 (1976)

    Google Scholar 

  46. Coburn, J. W., Kay, E.: Proc. 7th Intern. Vac. Congr. & 3rd Intern. Conf. Solid Surfaces, Vienna 2, 1257 (1977)

    CAS  Google Scholar 

  47. Stirling, A. J., Westwood, W. D.: J. Appl. Phys. 41, 742 (1970)

    Article  CAS  Google Scholar 

  48. Greene, J. E., Sequeda-Osorio, F.: J. Vac. Sci. Technol. 10, 1144 (1973)

    Article  Google Scholar 

  49. Bindley, T. F., Walker, S.: Trans. Faraday Soc. 58, 217 (1962)

    CAS  Google Scholar 

  50. Stille, J. K., Sung, R. L., Van der Kooi, J.: J. Org. Chem. 30, 3116 (1965)

    CAS  Google Scholar 

  51. Gilbert, R. ThéorÊt, A.: J. Phys. Chem. 80, 1017 (1976)

    CAS  Google Scholar 

  52. Degenkolb, E. O. et al.: Appl. Spectrosc. 30, 520 (1976)

    Article  CAS  Google Scholar 

  53. Harshbarger, W. R. et al.: Appl. Spectrosc. 31, 201 (1977)

    Article  CAS  Google Scholar 

  54. Mogab, C. J.: J. Electrochem. Soc. 124, 1262 (1977)

    CAS  Google Scholar 

  55. Mogab, C. J., Shankoff, T. A.: J. Electrochem. Soc. 124, 1766 (1977)

    CAS  Google Scholar 

  56. Mogab, C. J., Adams, A. C., Flamm, D. L.: J. Appl. Phys. 49, 3796 (1978)

    Article  CAS  Google Scholar 

  57. Curtis, B. J., Brunner, H. J.: J. Electrochem. Soc. 125, 829 (1978)

    CAS  Google Scholar 

  58. Oshima, M.: Japan J. Appl. Phys. 17, 1157 (1978)

    CAS  Google Scholar 

  59. Chuang, T., Kay, E.: To be published

    Google Scholar 

  60. Eernisse, E. P.: J. Vac. Sci. Technol. 12, 564 (1975)

    Article  CAS  Google Scholar 

  61. Coburn, J. W., Winters, H. F., Chuang, T. J.: J. Appl. Phys. 48, 3532 (1977)

    Article  CAS  Google Scholar 

  62. Raby, B. A.: J. Vac. Sci. Technol. 15, 205 (1978)

    Article  CAS  Google Scholar 

  63. Horiike, Y., Shibagaki, M.: Extended Abstr., Proc. 151st Electrochem. Soc. 77:1, 619 (1977)

    Google Scholar 

  64. Chuang, T. J.: Phys. Rev. Lett. 42, 815 (1979)

    Article  CAS  Google Scholar 

  65. Kay, E., Dilks, A., Hetzler, U.: Macromol. Sci.-Chem. A12(9), 1393 (1978)

    CAS  Google Scholar 

  66. Kay, E., Dilks, A.: ACS Symp. Ser.: 108 “Plasma Polymerization” by Shen, M., Bell, A. T., Amer. Chem. Soc., 1979

    Google Scholar 

  67. Lehmann, H. W., Krausbauer, L., Widmer, R.: J. Vac. Sci. Technol. 14, 281 (1977)

    Article  CAS  Google Scholar 

  68. Melliar-Smith, C. M.: J. Vac. Sci. Technol. 13, 1008 (1976)

    Article  CAS  Google Scholar 

  69. Chemical Dry Etching System CDE-IV, Tokuda Seisakusho, Ltd., Kawasaki, Japan

    Google Scholar 

  70. Bersin, R. L., Singleton, M.: USP 3, 879, 597

    Google Scholar 

  71. Reinberg, A. R., in: Etching (Rand, M. J., Hughes, A. R. (ed.)), Princeton, N. J., Electrochem. Soc. Symp. Ser. 1976, p. 91

    Google Scholar 

  72. Hosokawa, N., Matsuzaki, N., Asamaki, T.: Japan J. Appl. Phys. Supp. 2, Part 1, 435 (1974)

    Google Scholar 

  73. Schwartz, G. C., Zielinski, L. B., Schopen, T., in: Etching (Rand, M. J., Hughes, A. R. (ed.)), Princeton, N. J., Electrochem. Soc. Symp. Ser. 1976, p. 122

    Google Scholar 

  74. Bondur, J. A.: J. Vac. Sci. Technol. 13, 1023 (1976)

    Article  CAS  Google Scholar 

  75. Jacob, A.: USP 3,867,216

    Google Scholar 

  76. Horiike, Y., Shibagaki, M.: Suppl. Japan J. Appl. Phys. 15, 13 (1976)

    Google Scholar 

  77. Suzuki, K. et al.: ibid. 16, 1979 (1977)

    CAS  Google Scholar 

  78. Pitts, J. N., Sandoval, J. J., Atkinson, R.: Chem. Phys. Lett. 29, 31 (1974)

    Article  CAS  Google Scholar 

  79. Atkinson, R. et al.: J. Geophys. Res. 81, 5765 (1976)

    CAS  Google Scholar 

  80. Winters, H. F., Coburn, J. W., Kay, E.: J. Appl. Phys. 48, 4973 (1977)

    CAS  Google Scholar 

  81. Heinecke, R. A. H.: Solid-State Electron. 18, 1146 (1975)

    Article  CAS  Google Scholar 

  82. Ephrath, L. M.: J. Electrochem. Soc: 126, 1419 (1979)

    CAS  Google Scholar 

  83. Lehmann, H. W., Widmer, R.: Appl. Phys. Lett. 32, 163 (1978); Appl. Phys. Lett. 33, 367 (1978)

    Article  CAS  Google Scholar 

  84. Lehmann, H. W., Widmer, R.: J. Vac. Sci. Technol. 15, 319 (1978)

    Article  CAS  Google Scholar 

  85. Coburn, J. W.; Kay, E.: IBM J. Res. & Develop. 23, 33 (1979)

    CAS  Google Scholar 

  86. Bersin, R. L., Reichelderfer, R. F.: Solid State Technol. 20(4), 78 (1977)

    CAS  Google Scholar 

  87. Winters, H. F.: J. Appl. Phys. 49, 5165 (1978)

    Article  CAS  Google Scholar 

  88. Matsuo, S., Takehara, Y.: Japan J. Appl. Phys. 16, 175 (1977)

    Article  CAS  Google Scholar 

  89. Matsuo, S.: ibid. 17, 235 (1978)

    CAS  Google Scholar 

  90. Holland, L., Ojha, S. M.: Vacuum 26, 53, 233 (1976)

    CAS  Google Scholar 

  91. Holland, L.: J. Vac. Sci. Technol. 14, 5 (1977)

    Article  CAS  Google Scholar 

  92. Mauer, J. L. et al.: ibid. 15, 1734 (1978)

    CAS  Google Scholar 

  93. Hanak, J. J., Pellicane, J. P.: ibid. 13, 406 (1976)

    Article  CAS  Google Scholar 

  94. Cuomo, J. J., et al.: ibid. 15, 281 (1978)

    Article  CAS  Google Scholar 

  95. Schaible, P. M., Metzger, W. C., Anderson, J. P.: J. Vac. Sci. Technol. 15, 334 (1978)

    Article  CAS  Google Scholar 

  96. Millard, M. M., in: Techniques and Applications of Plasma Chemistry, (Hollahan, J. H., Bell, A. T. (Ed.)), John Wiley & Sons, New York, 1974

    Google Scholar 

  97. Shen, M. (Ed.): Plasma Chemistry of Polymers. Marcel Dekker, Inc., New York, 1976, and J. Macromol. Sci.-Chem. A10 (1976)

    Google Scholar 

  98. Clark, D. T., Dilks, A., Shuttleworth, D., in: Polymer Surfaces (Clark, D. T., Feast, W. J. (Ed.)), John-Wiley & Sons, London, in press

    Google Scholar 

  99. Yasuda, H., in: Thin Film Processes (Vossen, J. L., Kern, W. (Ed.)), Academic Press, New York, 1978

    Google Scholar 

  100. Tien, P. K., Smolinsky, G., Martin, R. J.: Appl. Opt. 11, 637 (1972)

    CAS  Google Scholar 

  101. Wydeven, T., Kubadhi, R.: Appl. Opt. 15, 132 (1976)

    CAS  Google Scholar 

  102. For example, Yasuda, H.: Appl. Pol. Symp. 22, 241 (1973)

    Google Scholar 

  103. Stancell, A. F., Spencer, A. T.: J. Appl. Pol. Sci. 16, 1505 (1972)

    Article  CAS  Google Scholar 

  104. Dubois, J. C., Gazard, M., Zann, A.: J. Appl. Phys. 47, 1270 (1976)

    Article  CAS  Google Scholar 

  105. Sprokel, G. J.: Mol. Cryst. Liq. Cryst. 42, 223 (1977)

    Google Scholar 

  106. Bui, H., Carchano, H., Sanchez, D.: Thin Solid Films 13, 207 (1972)

    Article  Google Scholar 

  107. Ozawa, P. J.: IEEE Trans. Parts. Mater. Package PMP-5 112 (1969)

    Google Scholar 

  108. Yasuda, H., Hsu, T. S.: J. Pol. Sci., Pol. Chem. Edn. 15, 2411 (1977)

    CAS  Google Scholar 

  109. Kay, E., Coburn, J. W., Kruppa, G.: VIDE 183, 89 (1976)

    Google Scholar 

  110. Biederman, M., Ojha, S. M., Holland, L.: Thin Solid Films 41, 329 (1977)

    Article  CAS  Google Scholar 

  111. Kobayashi, H., Bell, A. T., Shen, M.: Macromolecules 7, 277 (1974)

    CAS  Google Scholar 

  112. Dacey, J. R., Littler, J. G. F.: Can. J. Chem. 47, 3871 (1969)

    CAS  Google Scholar 

  113. Maserangelo, S. V. R.: J. Amer. Chem. Soc. 84, 1122 (1962)

    Google Scholar 

  114. Rice, D. W., O'Kane, D. F.: J. Electrochem. Soc. 123, 1308 (1976)

    CAS  Google Scholar 

  115. Clark, D. T., Dilks, A.: J. Pol. Sci., Pol. Chem. Edn. 16, 911 (1978), and references therein

    CAS  Google Scholar 

  116. Seeger, M. et al.: J. Polym. Sci., Polymer Chem. Edn. 15, 1403 (1977)

    CAS  Google Scholar 

  117. Fyfe, C. A. et al.: Macromolecules 12, 757 (1979)

    Article  CAS  Google Scholar 

  118. O'Kane, D. F., Rice, D. W.: J. Macromol. Sci.-Chem. A10, 567 (1976)

    Google Scholar 

  119. Millard, M. M., Windle, J. J., Pavlath, A. E.: J. Appl. Pol. Sci. 17, 2501 (1973)

    Article  CAS  Google Scholar 

  120. Millard, M. M., Pavlath, A. E.: J. Macromol. Sci.-Chem. A10, 579 (1976)

    CAS  Google Scholar 

  121. Millard, M. M., in: Characterization of Metal & Polymer Surfaces, Vol. 2. (Lee, L. M. (ed.)), Academic Press, New York, 1977

    Google Scholar 

  122. Diaz, A. et al.: J. Amer. Chem. Soc. 99, 6780 (1977)

    CAS  Google Scholar 

  123. Hetzler, U.:, Kay, E.: J. Appl. Phys. 49, 5617 (1978)

    Article  CAS  Google Scholar 

  124. Tibbit, J. M., Bell, A. T., Shen, M.: J. Macromol. Sci.-Chem. A10, 519 (1976)

    Google Scholar 

  125. Kay, E., Dilks, A., Seybold, D.: J. Appl. Phys. 1980 in press.

    Google Scholar 

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Stanislav Vepřek Mundiyath Venugopalan

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Kay, E., Coburn, J., Dilks, A. (1980). Plasma chemistry of fluorocarbons as related to plasma etching and plasma polymerization. In: Vepřek, S., Venugopalan, M. (eds) Plasma Chemistry III. Topics in Current Chemistry, vol 94. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0048585

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  • DOI: https://doi.org/10.1007/BFb0048585

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