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Molecular concepts, self-organisation and properties of polysoaps

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Polysoaps/Stabilizers/Nitrogen-15 NMR

Part of the book series: Advances in Polymer Science ((POLYMER,volume 124))

Abstract

The article reviews water-soluble polymers characterized by surfactant side chains, and related amphiphilic polymers. Various synthetic approaches are presented, and rules for useful molecular architectures are given. Models for the self-organization of such polymers in water are presented comparing them with the micellization of low molecular weight surfactants. Highlighting key properties of aqueous polysoap solutions such as viscosity, surface tension and solubilization power, some structure-property relationships are established. Further, the formation of mesophases and of superstructures in bulk is addressed. Finally, the functionalization of polysoaps, and potential applications are discussed.

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  1. Dépt. de Chimie, Université Catholique de Louvain, Place L. Pasteur 1, B-1348, Louvain-la-Neuve

    A. Laschewsky

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Laschewsky, A. (1995). Molecular concepts, self-organisation and properties of polysoaps. In: Polysoaps/Stabilizers/Nitrogen-15 NMR. Advances in Polymer Science, vol 124. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0025228

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