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The wettability of polymer surfaces and the spreading of polymer liquids

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Polymer Physics

Part of the book series: Advances in Polymer Science ((POLYMER,volume 85))

Abstract

The wetting behavior of polymers is reviewed beginning with the thermodynamic conditions for contact angle equilibrium. The critical surface tension of polymers is discussed followed by some of the current theories of wettability, notably the theory of fractional polarity and theories of contact angle hysteresis. The nonequilibrium spontaneous and forced spreading of polymer liquids is reviewed from two points of view, the surface chemical perspective and the hydrodynamic perspective. There is a wide disperity between these two viewpoints that needs to be resolved inorder to establish the predictive relations that govern spreading behavior.

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11 References

  1. Young, T.: Phil. Trans. 1805, p. 65

    Google Scholar 

  2. Gibbs, J. W., in: “The Collected Works of J. Willard Gibbs, Vol. I, Thermodynamics”, Yale Univ. Press, New Haven, CT, 1928, p. 314

    Google Scholar 

  3. Johnson, R. E., Jr.: J. Phys. Chem., 63, 1655 (1959)

    Article  CAS  Google Scholar 

  4. Shafrin, E. G. and Zisman, W. A.: J. Phys. Chem. 64, 519 (1960)

    Article  CAS  Google Scholar 

  5. Fox, H. W. and Zisman, W. A.: J. Colloid Sci., 5, 514 (1950)

    Article  CAS  Google Scholar 

  6. Ellison, A. H., Fox, H. W., and Zisman, W. A.: J. Phys. Chem., 57, 622 (1953)

    Article  CAS  Google Scholar 

  7. Fox, H. W., Hare, E. F., and Zisman, W. A.: J. Phys. Chem., 59, 1097 (1955)

    Article  CAS  Google Scholar 

  8. Neumann, A. W. and Good, R. J.: “Surface Colloid Techniques”, Vol. 1, Plenum Press, N.Y. 1976

    Google Scholar 

  9. Langmuir, I.: J. Amer. Chem. Soc., 38, 2286 (1916)

    Google Scholar 

  10. Bascom, W. D. and Singleterry, C. R.: J. Phys. Chem. 65, 1683 (1961)

    Article  CAS  Google Scholar 

  11. Bascom, W. D., Halper, L. A., and Jarvis, N. L.: I & EC, Product Research and Development, 8, 118 (1969)

    CAS  Google Scholar 

  12. Dann, J. R.: J. Coll & Interfare Sci., 32, 302 (1970)

    Article  CAS  Google Scholar 

  13. Girifalco, L. A. and Good, R. J.: J. Phys. Chem. 61, 904 (1957)

    Article  CAS  Google Scholar 

  14. Fowkes, F. M.: “Contact Angle, Wettability and Adhesion”, Vol. 43, Adv. in Chem., Amer. Chem. Soc. Washington D.C., 1964, p. 99

    Google Scholar 

  15. Owens, D. K. and Wendt, R. C.: J. Appl. Polym. Sci., 13, 1741 (1969)

    Article  CAS  Google Scholar 

  16. Kaelble, D. H.: Physical Chemistry of Adhesion, Wiley — Interscience, N.Y. 1971

    Google Scholar 

  17. Wu, S.: J. Adhesion 5, 39 (1973)

    Article  CAS  Google Scholar 

  18. Wu, S.: “Polymer Interface and Adhesion”, Marcel Dekker Inc., NY 1982, p. 67

    Google Scholar 

  19. Petke, F. D. and Ray, R. B.: J. Colloid and Interface Science, 31, 216 (1969)

    Article  CAS  Google Scholar 

  20. Dupre', G.: “Theorie Mechanique de la Chaleur”, Paris 1969, p. 393

    Google Scholar 

  21. Wenzel, R. W.: Ind. Eng. Chem. 28, 988 (1936)

    Article  CAS  Google Scholar 

  22. Shuttleworth, R. and Bailey, G. L. T.: Discussion Faraday Soc., 3, 16 (1948)

    Article  Google Scholar 

  23. Johnson, R. E., Jr. and Dettre, R. H.: “Contact Angle, Wettability and Adhesion”, Vol. 43, Adv. Chem., Amer. Chem. Soc., 1964, p. 112 and p. 136

    Google Scholar 

  24. Cassie, A. B. D. and Baxter, S.: Trans. Faraday Soc., 40, 546 (1944)

    Article  CAS  Google Scholar 

  25. Good, R. J.: J. Amer. Chem. Soc., 74, 504 (1952)

    Google Scholar 

  26. Johnson, R. E., Jr. and Dettre, R. H.: J. Phys. Chem., 68, 1744 (1964)

    Article  CAS  Google Scholar 

  27. Johnson, R. E., Jr. and Dettre, R. H.: J. Phys. Chem., 69, 1507 (1965)

    Article  Google Scholar 

  28. Shepard, J. W. and Bartell, F. E.: J. Phys. Chem. 57, 458 (1953)

    Article  CAS  Google Scholar 

  29. deGennes, P. G.: Rev. Mod. Phys., 57, 827 (1985)

    Article  CAS  Google Scholar 

  30. Harkins, W. D.: “The Physical Chemistry of Surface Films”, Reinhold Pub. Co., NY, 1952, p. 41

    Google Scholar 

  31. Derjaguin, B. V. and Zorin, Z. M.: Proc. 2nd Inter. Congress Surface Activity (London) 2, 145 (1957)

    Google Scholar 

  32. Israelachvili, J. N.: “Intermolecular and Surface Forces”, Academic Press, N.Y., 1985 p. 130

    Google Scholar 

  33. Derjaguin, B. V., Karasev, V. V., Lavygin, I. A., Skarokhodov, I. I., and Khromoua, E. N.: Discuss. Faraday Soc., 1, 98 (1970)

    Article  Google Scholar 

  34. Scriven, L. E.: Discuss Faraday Soc., 1, 128 (1970)

    Article  Google Scholar 

  35. Bascom, W. D., Singleterry, C. R.: J. Colloid Interface Sci., 66, 559 (1978)

    Article  CAS  Google Scholar 

  36. Ivanov, I. B.: “Thin Liquid Films”, Dekker, N.Y. 1985

    Google Scholar 

  37. Scriven, L. E. and Sterling, C. V.: Nature, 187, 186 (1960)

    Article  Google Scholar 

  38. Bascom, W. D., Cottington, R. L. and Singleterry, C. R.: Adv. in Chem. 43, 355 (1964), Amer. Chem. Soc., Washington, D.C.

    Article  CAS  Google Scholar 

  39. Jeffreys, H.: Proc. Cambridge Phil. Soc., 26, 204 (1930)

    Article  Google Scholar 

  40. Fote, A. E., Dormant, L. M. and Feuerstein, S.: Lubrication Engineering, Oct 1976, p. 542

    Google Scholar 

  41. Cottington, R. L., Murphy, C. M. and Singleterry, C. R.: Adv. Chem., 43, 341, (1964), Amer. Chem. Soc., Washington, D.C.

    Article  CAS  Google Scholar 

  42. Cheever, G. D., in: “Interface Conversion for Polymer Coatings”, P. Weiss and G. D. Cheever, Eds., Elsevier, 1968, p. 152

    Google Scholar 

  43. Folkman, J. and Greenspan, H. P.: Biochem. Biophys. Acta, 417, 211 (1976)

    Google Scholar 

  44. Van Oene, H., Chang, Y. F., Newman, S.: J. Adhesion 1, 54 (1969)

    Article  Google Scholar 

  45. Schonhorn, H., Frisch, H. L. and Kwei, T. K.: J. App. Phys., 37, 4967 (1966)

    Article  CAS  Google Scholar 

  46. Lopez, J. Miller, C. A. and Ruckenstein, E.: J. Coll. Interface Sci. 56, 460 (1976)

    Article  CAS  Google Scholar 

  47. Ogarev, V. A., Timonina, T. N., Arslanov, V. V. and Trapeznikov, A. A.: J. Adhesion 6, 337 (1974)

    Article  CAS  Google Scholar 

  48. Lelah, M. D. and Marmur, A.: J. Coll. Interface Sci., 82, 518 (1981)

    Article  CAS  Google Scholar 

  49. Hansen, R. J. and Toong, T. Y.: J. Coll. Interface Sci., 37, 196 (1981)

    Article  Google Scholar 

  50. Ludviksson, V. and Lightfoot, E. N.: Inst. Chem. Eng., 14, 674 (1968)

    CAS  Google Scholar 

  51. Deryagin, B. V. and Levi, S. M.: “Film Coating Theory”, Focal Press, London, 1964

    Google Scholar 

  52. Huh, C. and Scriven, L. E.: J. Coll. Interface Sci., 35, 85 (1971)

    Article  CAS  Google Scholar 

  53. Bascom, W. D. and Cottington, R. L.: J. Adhesion 4, 193 (1972)

    Article  CAS  Google Scholar 

  54. Hoffman, R.: J. Coll. Interface Sci., 50, 228 (1975)

    Article  CAS  Google Scholar 

  55. Schwartz, A. M. and Tejada, S. B.: J. Coll. Interface Sci., 38, 359 (1972)

    Article  CAS  Google Scholar 

  56. Elliot, G. E. P. and Riddiford, A. C.: J. Coll. Interface Sci., 23, 389 (1967)

    Article  Google Scholar 

  57. Blake, T. D. and Haynes, J. M.: J. Coll. Interface Sci., 30, 421 (1969)

    Article  CAS  Google Scholar 

  58. Friz, G.: Z. Angew. Phys., 19 (4), 374 (1965)

    Google Scholar 

  59. Johnson, R. E., Jr., Dettre, R. H. and Brandreth, D. A.: J. Coll. Interface Sci., 62, 205 (1977)

    Article  CAS  Google Scholar 

  60. Andrade, J. D., Smith, L. M., and Gregonis, D. E., in “Surface and Interfacial Aspects of Biomedical Polymers”, Plenum Press, NY, 1985, p. 249

    Google Scholar 

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© 1988 Springer-Verlag

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Bascom, W.D. (1988). The wettability of polymer surfaces and the spreading of polymer liquids. In: Polymer Physics. Advances in Polymer Science, vol 85. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0024051

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