Abstract
Fundamental data on the rate of diffusion of boron in austenite and solubility of boron in the α and β phases of iron and steel have been obtained from deboronizing experiments and provide partial explanations for some of the phenomena observed in boron steels. The rate of diffusion of boron is about the same as carbon in austenite. The solubility of boron in austenite at normal heat-treating temperatures is less than 0.001 pet. A partial tentative Fe-B phase diagram in the important low boron concentration ranges and an equation representing the diffusion of boron in austenite are presented.
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H. Cornelius and F. Bollenrath: Einflusz von Kohlenstoff auf die Diffusion einiger Elements in Stahl. Archiv. Eisenhuttenwesen (September 1941) 15, p. 145.
T. D. Campbell and H. Fay: The Case Hardening of Steel by Boron and Nitrogen. Industrial and Engineering Chemistry (1924) 16, p. 719.
T. Kase: Cementation of Boron on Some Metals. Abstracted in Metals and Alloys (1938) 9, p. M.A. 661.
Cyril Wells, Walter Batz, and Robert F. Mehl: Diffusion Coefficient of Carbon in Austenite. Trans. AIME (1950) 188, p. 553; Journal of Metals (March 1950).
T. G. Digges, Carolyn R. Irish, and Nesbit L. Carwile: Effect of Boron on the Hardenability of High Purity Alloys and Commercial Steels. Journal of Research. National Bur. Standards (1948) 41, R.P. 1938, p. 545.
C. E. Birchenall: Volume Diffusion–An Empirical Survey. Atom Movements. (1951) p. 112. Cleveland. ASM.
C. Wells and R. F. Mehl: Rate of Diffusion of Carbon in Austenite. Trans. AIME (1940) 140, p. 279.
C. H. Corliss and B. F. Scribner: Spectrographs Determination of Boron in Steel. Journal of Research. National Bur. Standards (1946) 36, R.P. 1705, p. 351.
T. G. Digges and F. M. Reinhart: Influence of Boron on Some Properties of Experimental and Commercial Steels. Journal of Research. National Bur. Standards. (1947) 39, R.P. 1815, p. 67.
R. M. Parke: Boron-Iron Constitution Diagram. Metals Handbook (1948) p. 1175. Cleveland. ASM.
C. Wells: Chemical Techniques and Analysis of Diffusion Data. Atom Movements (1951) p. 26. Cleveland. ASM.
J. K. Stanley: The Diffusion and Solubility of Carbon in Alpha Iron. Trans. AIME (1949) 185, p. 752; Journal of Metals (October 1949).
M. Ezekial: Methods of Correlation Analysis (1941) Second Edition. New York. John Wiley and Sons.
G. W. Snedecor: Statistical Methods (1946) Fourth Edition. Ames, Iowa. The Iowa State College Press.
H. Arkin and R. R. Colton: An Outline of Statistical Methods (1939) Fourth Edition. New York. Barnes and Noble.
E. G. Olds and C. Wells: Statistical Methods for Evaluating the Quality of Certain Wrought Steel Products. Trans. ASM (1950) 42, p. 845.
M. C. Udy and P. C. Rosenthal: Boron in Certain Alloy Steels. Trans. AIME (1947) 172, p. 273; Metals Technology (October 1946).
R. A. Grange and T. M. Garvey: Factors Affecting the Hardenability of Boron-Treated Steels. Trans. ASM (1946) 37, p. 136.
G. D. Rahrer and C. D. Armstrong: The Effect of Carbon Content on the Hardenability of Boron Steels. Trans. ASM (1948) 40, p. 1099.
W. Crafts and J. L. Lamont: Effect of Some Elements on Hardenability. Trans. AIME (1944) 158, p. 157.
J. W. Spretnak and Rudolph Speiser: Grain and Grain-Boundary Compositions: Mechanism of Temper Brittleness. Trans. ASM (1951) 43, p. 734.
Yûnoshin Imai and Hikotaro Imai: The Research Inst, for Iron, Steel and Other Metals. Sci. Repts. Research Inst. Tohoku Univ. (April 1950) Series A, Vol. 2, No. 2 (in English). Sendai, Japan.
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Discussion on this paper, TP 3633E, may be sent, 2 copies, to AIME by April 1, 1954. Manuscript, April 15, 1953; revision, July 10, 1953. New York Meeting, February 1954.
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Busby, P.E., Warga, M.E. & Wells, C. Diffusion and Solubility of Boron in Iron and Steel. JOM 5, 1463–1468 (1953). https://doi.org/10.1007/BF03397637
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DOI: https://doi.org/10.1007/BF03397637