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Efficient microwave-assisted synthesis of 3-benzothiazolo and 3-benzothiazolino coumarin derivatives catalyzed by heteropoly acids

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Abstract

Heteropoly acids are reported as efficient catalysts for the microwave-assisted synthesis of 3-benzothiazolo and 3-benzothiazolino coumarin from o-aminothiophenol derivatives with 3-acetly and 3-cyanochromen-2-one in good to excellent isolated yields (73–95%). This study suggests new techniques for the synthesis of chromene derivatives using an inexpensive and easily available catalyst, a simple procedure, short reaction time, and good to excellent yields of the products.

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Authors and Affiliations

  1. Chemistry Department, Zanjan University, P.O. Box 45195-313, Zanjan, Iran

    M. Khoobi, A. Ramazani & Z. Hojjati

  2. Department of Medicinal Chemistry, Faculty of Pharmacy, and Pharmaceutical Sciences Research Center, Tehran, University of Medical Sciences, Tehran, 14176, Iran

    A. R. Foroumadi & A. Shafiee

  3. Department of Chemistry, Chamran University, Ahvaz, 61357-4-3169, Iran

    H. Hamadi

Authors
  1. M. Khoobi
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  2. A. Ramazani
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  3. A. R. Foroumadi
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  4. H. Hamadi
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  5. Z. Hojjati
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  6. A. Shafiee
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Correspondence to A. Shafiee.

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Khoobi, M., Ramazani, A., Foroumadi, A.R. et al. Efficient microwave-assisted synthesis of 3-benzothiazolo and 3-benzothiazolino coumarin derivatives catalyzed by heteropoly acids. JICS 8, 1036–1042 (2011). https://doi.org/10.1007/BF03246560

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  • DOI: https://doi.org/10.1007/BF03246560

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