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Thermal, solution and structural studies of a 3D Ag(I) coordination polymer with various Ag-Ag bonds, [Ag3(μ-Hbtc)(μ-H2btc)]n

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Abstract

[Ag3(μ-Hbtc)(μ-H2btc)]n (H3btc = 1,3,5-benzenetricarboxylic acid) (1), a new rarely reported Ag(I) three-dimensional coordination polymer with several Ag-Ag bonds, has been synthesized, characterized by elemental analysis and IR spectroscopy and its structure determined by single-crystal X-ray diffraction. The thermal stability of compound 1 was studied by thermal gravimetric and differential thermal analyses. The single crystal X-ray analysis of compound 1 shows that the complex consists of [Ag3(μ-Hbtc)(μ-H2btc)] subunits containing four different Ag environments. The results of studies of the stoichiometry and complex formation in methanol solution supported their solid state stoichiometry.

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  1. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14115-175, Tehran, Islamic Republic of Iran

    K. Akhbari & A. Morsali

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  1. K. Akhbari
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Akhbari, K., Morsali, A. Thermal, solution and structural studies of a 3D Ag(I) coordination polymer with various Ag-Ag bonds, [Ag3(μ-Hbtc)(μ-H2btc)]n . JICS 5, 48–56 (2008). https://doi.org/10.1007/BF03245814

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