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Synthesis and characterization of sulfonated poly(arylene ether) polyimide multiblock copolymers for proton exchange membranes

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Abstract

Novel multiblock copolymers, based on segmented sulfonated hydrophilic-hydrophobic blocks, were synthesized and investigated for their application as proton exchange membranes. A series of segmented sulfonated poly(arylene ether sulfone)-b-polyimide multiblock copolymers, with various block lengths, were synthesized via the coupling reaction between the terminal amine moieties on the hydrophilic blocks and naphthalene anhydride functionalized hydrophobic blocks. Successful imidization reactions required a mixed solvent system, comprised of NMP and m-cresol, in the presence of catalysts. Proton conductivity measurements revealed that the proton conductivity improved with increasing hydrophilic and hydrophobic block lengths. The morphological structure of the multiblock copolymers was investigated using tapping mode atomic force microscopy (TM-AFM). The AFM images of the copolymers demonstrated well-defined nanophase separated morphologies, with the changes in the block length having a pronounced effect on the phase separated morphologies of the system. The self diffusion coefficient of water, as measured by1H NMR, provided a better understanding of the transport process. Thus, the block copolymers showed higher values than Nafion, andcomparable proton conductivities in liquid water, as well as under partially hydrated conditions at 80°C. The new materials are strong candidates for use in PEM systems.

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References

  1. M. A. Hickner, H. Ghassemi, Y. S. Kim, B. Einsla, and J. E. McGrath,Chem. Rev.,104, 4587 (2004).

    Article  CAS  Google Scholar 

  2. F. Wang, M. Hickner, Y. S. Kim, T. A. Zawodzinski, and J. E. McGrath,J. Membrane Sci.,197, 231 (2002).

    Article  CAS  Google Scholar 

  3. A. Noshay and J. E. McGrath,Block copolymers overview and critical survey, Academic Press, 1977, p. 91.

  4. B. R. Einsla, Y. T. Hong, Y. S. Kim, F. Wang, N. Gunduz, and J. E. McGrath,J. Polym. Sci.; Part A: Polym. Chem.,42, 862 (2004).

    Article  CAS  Google Scholar 

  5. B. R. Einsla, Y. S. Kim, M. A. Hickner, Y. T. Hong, M. L. Hill, B. S. Pivovar, and J. E. McGrath,J. Membrane Sci.,255, 141 (2005).

    Article  CAS  Google Scholar 

  6. Z. Hu, Y. Yin, S. Chen, O. Yamada, K. Tanaka, H. Kita, and K.-I. Okamoto,J. Polym. Sci.; Part A: Polym. Chem.,44, 2862 (2006).

    Article  CAS  Google Scholar 

  7. A. L. Rusanov,Adv. Polym. Sci.,111, 115 (1994).

    Article  CAS  Google Scholar 

  8. C. Genies, R. Mercier, B. Sillion, R. Petiaud, N. Cornet, G. Gebel, and M. Pineri,Polymer,42, 5097 (2001).

    Article  CAS  Google Scholar 

  9. C. Genies, R. Mercier, B. Sillion, N. Cornet, G. Gebel, and M. Pineri,Polymer,42, 359 (2001).

    Article  CAS  Google Scholar 

  10. A. S. Badami, H.-S. Lee, Y. Li, A. Roy, H. Wang, and J. E. McGrath,Prepr. Pap., Am. Chem. Soc., Div. Fuel Chem.,51, 612 (2006).

    CAS  Google Scholar 

  11. A. Roy, H.-S. Lee, A. S. Badami, and J. E. McGrath,Prepr. Pap., Am. Chem. Soc., Div. Fuel Chem.,51, 660 (2006).

    CAS  Google Scholar 

  12. A. Roy, M. Hickner, X. Yu, Y. Li, T. Glass, and J. E. McGrath,J. Polym. Sci.; Part B: Polym. Phys.,44, 2226 (2006).

    Article  CAS  Google Scholar 

  13. M. Sankir, V. A. Bhanu, W. L. Harrison, H. Ghassemi, K. B. Wiles, T. E. Glass, A. E. Brink, M. H. Brink, and J. E. McGrath,J. Appl. Polym. Sci.,100, 4595 (2006).

    Article  CAS  Google Scholar 

  14. E. O. Stejskal and J. E. Tanner,J. Chem. Phys.,42, 288 (1965).

    Article  CAS  Google Scholar 

  15. X. Guo, J. Fang, T. Watari, K. Tanaka, H. Kita, and K.-I. Okamoto,Macromolecules,35, 6707 (2002).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Macromolecular Science and Engineering Program, Macromolecules and Interfaces Institute, Virginia Polytechnic Institute and State University, 24061, Blacksburg, VA, USA

    Hae-Seung Lee, Abhishek Roy, Anand S. Badami & James E. McGrath

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  1. Hae-Seung Lee
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  2. Abhishek Roy
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  3. Anand S. Badami
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  4. James E. McGrath
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Correspondence to James E. McGrath.

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Lee, HS., Roy, A., Badami, A.S. et al. Synthesis and characterization of sulfonated poly(arylene ether) polyimide multiblock copolymers for proton exchange membranes. Macromol. Res. 15, 160–166 (2007). https://doi.org/10.1007/BF03218768

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  • DOI: https://doi.org/10.1007/BF03218768

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