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Very-high-field EPR and its applications

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Abstract

A kind of review of recent developments of the very-high-field EPR technique and applications is presented, the largest part of attention being attracted to studies of molecular structures and molecular and chemical dynamics of free radicals, biradicals and some paramagnetic complexes. The very recent results on thermal spin polarization effects on high-field/low-temperature EPR lineshape are overviewed. These effects are proved to provide a novel approach to study systems withS>1/2, particularly radical pairs, radical clusters and biradicals.

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Authors and Affiliations

  1. N.N. Semenov Institute of Chemical Physics, ul. Kosygina 4, 117977, Moscow, Russin Federation

    Ya. S. Lebedev

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  1. Ya. S. Lebedev
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Lecture presented on the occasion of the Zavoisky Award, Kazan

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Lebedev, Y.S. Very-high-field EPR and its applications. Appl. Magn. Reson. 7, 339–362 (1994). https://doi.org/10.1007/BF03162619

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