Abstract
The phosphorescence spectrum of [70]-fullerene in a glassy toluene matrix has been investigated at 77, 4.2 and 1.2 K. At 77 K, only one decay time (47.0 ms) has been observed while at 4.2 and 1.2 K two decay times (46.7, 5.6 ms and 46.6, 24.2 ms, respectively) were recorded. The zero field splitting parameters |D|=0.00489(25) cm−1 and |E|=0.00135(7) cm−1 were measured at 1.2 K using a pulsed ODMR technique.
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Krätschmer W., Lamb L.D., Fostiropoulos K., Huffman D.R.: Nature347, 354 (1990)
Krätschmer W., Fostiropoulos K., Huffman D.R.: Chem. Phys. Lett.170, 167 (1990)
Wang Y.: J. Phys. Chem.96, 764 (1992)
Kim D., Lee M.: J. Am. Chem. Soc.114, 4429 (1992)
Wasielewski M.R., O’Neil M.P., Lykke K.R., Pellin M.J., Gruen D.M.: J. Am. Chem. Soc.113, 2774 (1991)
Argentine S.M., Francis A.H., Chen C.-C., Lieber C.M., Siegel J.S.: J. Phys. Chem.98, 7350 (1994)
Argentine S.M., Kotz K.T. Francis A.H.: J. Am. Chem. Soc.117, 11762 (1995)
Sibley S.P., Argentine S.M., Francis A.H.: Chem. Phys. Lett.188, 187 (1992)
Palewska K., Sworakowski J., Chojnacki H., Meister E.C., Wild U.P.: J. Phys. Chem.97, 12167 (1993)
Scuseria G.E.: Chem. Phys. Lett.180, 451 (1991)
Baker J., Fowler P.W., Lazzeretti P., Malagoli M., Zanasi R.: Chem. Phys. Lett.184, 182 (1991)
Angerhofer A., von Schütz J.U., Widmann D., Müller W.H., ter Meer H.U., Sixl H.: Chem. Phys. Lett.217, 403 (1994)
Matsushita M., Frens A.M., Groenen E.J.J., Poluektov O.G., Schmidt J., Meijer G., Verheijen M.A.: Chem. Phys. Lett.214, 349 (1993)
Lane P.A., Swanson L.S., Shinar J., Engel J.P., Barton T.J., Wheelock J., Jones L.: Synth. Met.55–57, 3086 (1993)
Lane P.A., Swanson L.S., Ni Q.-X., Shinar J., Engel J.P., Barton T.J., Jones L.: Phys. Rev. Lett.68, 887 (1992)
Wei X., Jeglinski S., Paredes O., Vardeny Z.V., Moses D., Srdanov V.I., Stucky G.D., Khemani K.C., Wudl F.: Solid State Commun.85, 455 (1993)
Wei X., Vardeny Z.V., Moses D., Srdanov V.I., Wudl F.: Synth. Met.54, 273 (1993)
Levanon H., Meiklyar V., Michaeli S., Gamliel D.: J. Am. Chem. Soc.115, 8722 (1993)
Terazima M., Hirota N., Shinohara H., Saito Y.: Chem. Phys. Lett.195, 333 (1992)
Groenen E.J.J., Poluektov O.G., Matsushita M., Schmidt J., van der Waals J.H., Meijer G.: Chem. Phys. Lett.197, 314 (1992)
Bennati M., Grupp A., Mehring M., Dinse K.-P., Fink J.: Chem. Phys. Lett.200, 440 (1992)
Friedrich J.: Diplom thesis. Darmstadt: Technische Hochschule 1994.
Clarke R.H. (ed.): Triplet State ODMR Spectroscopy, p. 14 ff. New York: J. Wiley & Sons 1982.
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Saal, C., Weiden, N. & Dinse, K.P. Zero-field optical detected magnetic resonance of [70]-fullerene. Appl. Magn. Reson. 11, 335–350 (1996). https://doi.org/10.1007/BF03162064
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DOI: https://doi.org/10.1007/BF03162064