Abstract
Unbleached and alkaline hydrogen peroxide bleached black spruce (picea mariana) stone groundwood samples were irradiated with a weak light source over a period of six days in an effort to probe the early photochemical events occurring during the light-induced brightness reversion. Samples withdrawn at daily intervals were subjected to oxyphosphorylation with trimethyl phosphite to labelortho-quinones and other chromophoric species with phosphorus. The solid-state31P NMR spectra of these samples revealed the rapid formation ofortho-quinones during the early phase of irradiation, followed by a dramatic reduction of these species at latter phases. The data suggests that during the early photochemistry,ortho-quinones are produced in high yield pulps, which subsequently react creating other more complex chromophores which do not possess the quinonic character.
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Argyropoulos, D.S., Heitner, C. & Schmidt, J.A. Observation of quinonoid groups during the light-induced yellowing of softwood mechanical pulp. Res. Chem. Intermed. 21, 263–274 (1995). https://doi.org/10.1007/BF03052257
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DOI: https://doi.org/10.1007/BF03052257