Skip to main content
Log in

PAH deposition to snow surface

Chemical analysis and interpretation of results

  • Research Articles
  • Published:
Environmental Science and Pollution Research Aims and scope Submit manuscript

Abstract

The urban snowpack effectively acts as a collection device for atmospheric-deposited PAHs. When these PAHs are flushed out in a short time interval along with springtime snowmelt, these cause shockloading to receiving waters. In order to assess the PAH deposition and accumulation in urban snowpacks, a deposition survey of PAH for the winter months of 1991–92 from the city of Sault Ste. Marie, Ontario, Canada was undertaken. The results of the survey are interpreted in view of prevailing meteorology and various emission sources in the study area. The relative PAH deposition levels (to BaP) are compared with relative source emission fingerprints to examine consistency in sampling and analysis.

While analyzing the PAH samples using the ASTM (1987) method, the problem of concentration levels being below the detection level was encountered. The ASTM method for PAH analysis was modified to enhance the detection limit of the PAHs by concentrating the PAH extract to very low volumes, on the order of 200–300 μL.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • ASTM (American Society for Testing materials (1987): Standard test method for polynuclear hydrocarbons in water. Vol.11.02, 239–245

    Google Scholar 

  • Beard, A.;Naikwadi, K.;Karasek, F.W. (1992): Comparison of extraction methods for PCDD and PCDF in flyash using gas chromatography—mass spectrometry analysis. Journal of Chromatography589, 265–270

    Article  CAS  Google Scholar 

  • Bjorseth, A. Bjorseth, O;Fjeldstad, E. (1978): PAH in the work atmosphere: determination in a coke plant. Scand. J. Work Environ. and Health4, 224–236

    Google Scholar 

  • Boom, A.;Marsalek, J. (1988): Accumulation of polycyclic aromatic hydrocarbons (PAHs) in an urban snowpack. Sci. Total Env.74, 133–148

    Article  CAS  Google Scholar 

  • Daisey, J. M.;Cheney, J. L.;Lioy, P.J. (1986): Profiles of organic particulate emissions from air pollution sources: status and needs for receptor source apportionment modelling. J. Air Pollution Control Association36, 17–33

    CAS  Google Scholar 

  • Ellis, J.B.;Revitt, M.;Gavens, A. (1985): Polyaromatic hydrocarbon distributed in sediments of an urban catchment. International J. Environ. Anal. Chem.21, 161–170

    Article  CAS  Google Scholar 

  • Hangebrauck, R.P.;Lehmden, D.J.;Meeker, J.E. (1967): Sources of polynuclear hydrocarbons. US dept. of Health, Education and Welfare Public health Service, Bureau of Disease Prevention and Environmental Control, Cincinnati, Ohio

    Google Scholar 

  • Kauss, P.B.;Hamdy, Y.S. (1991): Polycyclic aromatic hydrocarbons in surficial and cages mussels of the St. Marys River, 1985. Hydrobiologia219, 37–62

    CAS  Google Scholar 

  • Lygen, E.;Gjessing, E.;Berglind, L. (1984): Pollutant transport from a highly. Sci. Total Env. 33, 147–159

    Article  Google Scholar 

  • Marsalek, J. (1990): Pollutant accumulation in urban snowpack. In International Conference on Urban Hydrology under Wintry Conditions, March 19–21, Narvik, Norway

    Google Scholar 

  • Naikwadi, K.P.;Charbonneau, G.M.;Karasek, F.W. (1987): Separation and identification of organic compounds in air particulate extracts by high performance liquid chromatography and chromatography-mass spectrometry. J. of Chromatography398, 227–237

    Article  CAS  Google Scholar 

  • Pistikopoulos, P.;Masclet;Mouvier, G. (1990): A receptor model adapted to reactive species: polycyclic aromatic hydrocarbons; evaluation of source contribution in an open urban site-I. Particle compound. Atmospheric Environment24A, 1189–1197

    CAS  Google Scholar 

  • Ramdahl, T.;Alfheim, I.;Bjorseth, A. (1983): PAH emission from various sources and their evolution over the last decades. In Mobile Source Emissions including Polycyclic Aromatic Hydrocarbons,Rondie, D.;Cooke, M andHaroz R.K.D. Eds., Reidel Publishing Company, Dordrecht, Holland

    Google Scholar 

  • Schondorf, T.;Herrmann, R. (1987): Transport and chemodynamics of organic micropollutants and ions during snowmelt. Nordic Hydrology18, 259–278

    Google Scholar 

  • Sharma, M.;McBean, E.;Thomson, N.;Marsalek, J. (1994a): Source receptor modelling of PAHs using deposition levels in winter-long urban snowpack. ASCE, Journal of Environmental Engineering 120, 1248–1265

    Article  CAS  Google Scholar 

  • Sharma, M.;Marsalek, J.;McBean, E. (1994b): Migration Pathways and remediation of urban runoff for PAH control. Journal of Environmental Management41, 325–336

    Article  Google Scholar 

  • Walters, R.W.;Luthy, R.G. (1984): Liquid/suspended phase partitioning of polycyclic aromatic hydrocarbons in coal coking wastewaters. Water Research18, 795–809

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mukesh Sharma.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sharma, M., McBean, E.A. PAH deposition to snow surface. Environ Sci & Pollut Res 8, 11–18 (2001). https://doi.org/10.1007/BF02987290

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02987290

Keywords

Navigation