Abstract
Intercalated compounds of fluorinated graphite C2F·yR, where R is benzene, hexafluorobenzene, acetone, or germanium tetrachloride, are studied by X-ray photoelectron spectroscopy. The binding energies of the C1s and F1s inner levels indicate that the C-F chemical bond in fluorinated graphite differs dramatically from the covalent bond in graphite monofluoride. The binding energies of the inner levels in atoms of the graphite fluoride matrix and GeCl4 are analyzed and it is concluded that there is no chemical binding between the host matrix and the guest molecule.
Similar content being viewed by others
Reference
N. Watanabe, T. Nakajima, and H. Touhara,Graphite Fluorides. Studies in Inorganic Chemistry, Vol. 8, Elsevier, Amsterdam (1988).
P. Cadman, J. D. Scott, and J. M. Thomas,Carbon,15, 75–86 (1977).
I. Palchan, M. Crespin, H. Estrade-Szwarckopf, and B. Rousseau,Chem. Phys. Lett.,157, 321–327 (1989).
T. Mallouk and N. Bartlett,J. Chem. Soc., Chem. Commun., 103–105 (1983).
V. M. Paasonen, A. S. Nazarov, V. M. Grankin, and I.I. Yakovlev,Zh. Neorg. Khim.,35, 2205–2209 (1990).
A. M. Danilenko, V. M. Paasonen, O. G. Potapova, and I. I. Yakovlev,Abstracts of Papers from the 3rd International Seminar “Inclusion Compounds,” Novosibirsk (1989), p. 55.
I. P. Asanov, S. B. Érenburg, G. F. Khudorozhko, et al.,Abstracts of Papers from the 8th All-Union Symposium on the Chemistry of Inorganic Fluorides, Polevskoy (1987), p. 52.
V. M. Paasonen, S. B. Érenburg, A. S. Nazarov, and I. P. Asanov,Zh. Strukt. Khim.,39, 530–532 (1998).
N. F. Yudanov, A. S. Nazarov, and I.I. Yakovlev,Abstracts of Papers from the 6th All-Union Symposium on the Chemistry of Inorganic Fluorides, Novosibirsk (1981), p. 94.
Yu. I. Nikonorov and L. L. Gornostaev,Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk,9, 55–59 (1979).
V. M. Paasonen, A. S. Nazarov, and V. M. Grankin,Zh. Neorg. Khim.,43, 1452–1456 (1998).
P. L. Walker, Jr.,Chemistry and Physics of Carbon, Dekker, New York (1965).
G. R. Hennig,Prog. Inorg. Chem.,1, 125 (1959).
D. M. Cox, S. D. Cameron, A. Tuinman, et al.,J. Am. Chem. Soc.,116, 1115–1120 (1994).
L. G. Bulusheva, A. V. Okotrub, V. N. Mitkin, et al.,Zh. Strukt. Khim.,36, 630–635 (1995).
V. I. Nefedov,X-Ray Photoelectron Spectroscopy of Chemical Compounds. Handbook [in Russian], Khimiya, Moscow (1984).
A. V. Okotrub, L. G. Bulusheva, N. F. Yudanov, and I. P. Asanov,Zh. Neorg. Khim.,43, 129–137 (1998).
G. G. Furin, A. V. Zibarev, L. N. Mazalov, and V. D. Yumatov,Electronic Structure of Fluoroorganic Compounds [in Russian], Nauka, Novosibirsk (1988).
A. A. Bakke, H.-W. Chen, and W. L. Jolly,J. Electron. Spectrosc. Relat. Phenom.,20, 333–366 (1980).
C. D. Wagner and A. Joshi,ibid.,47, 283–313 (1988).
D. Briggs and M. P. Seah (eds),Practical Surface Analysis by Auger and X-Ray Photoelectron Spectroscopy, Wiley, New York (1983).
Author information
Authors and Affiliations
Additional information
Translated fromZhurnal Struktumoi Khimii, Vol. 39, No. 6, pp. 1127–1133, November–December, 1998.
Rights and permissions
About this article
Cite this article
Asanov, I.P., Paasonen, V.M., Mazalov, L.N. et al. X-ray photoelectron study of fluorinated graphite intercalation compounds. J Struct Chem 39, 928–932 (1998). https://doi.org/10.1007/BF02903607
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02903607