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X-ray photoelectron study of fluorinated graphite intercalation compounds

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Abstract

Intercalated compounds of fluorinated graphite C2F·yR, where R is benzene, hexafluorobenzene, acetone, or germanium tetrachloride, are studied by X-ray photoelectron spectroscopy. The binding energies of the C1s and F1s inner levels indicate that the C-F chemical bond in fluorinated graphite differs dramatically from the covalent bond in graphite monofluoride. The binding energies of the inner levels in atoms of the graphite fluoride matrix and GeCl4 are analyzed and it is concluded that there is no chemical binding between the host matrix and the guest molecule.

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Translated fromZhurnal Struktumoi Khimii, Vol. 39, No. 6, pp. 1127–1133, November–December, 1998.

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Asanov, I.P., Paasonen, V.M., Mazalov, L.N. et al. X-ray photoelectron study of fluorinated graphite intercalation compounds. J Struct Chem 39, 928–932 (1998). https://doi.org/10.1007/BF02903607

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  • DOI: https://doi.org/10.1007/BF02903607

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