Abstract
A new type of dibenzoyl tartaric acid selective electrode has been developed. Three double-arm calix[4]arene derivatives were employed as the neutral ionophores. The poly(vinyl chloride) membrane electrode containing an amide derivative of calix[4]arene as the neutral carrier and a dibutyl phthalate as the plasticizer exhibited the highest sensitivity for dibenzoyl tartaric acid. The slope of linear portion was 27.8 mV per concertration decade. The electrode has a fast response and a long lifetime.
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Fundation item: Supported by National Natural Science Foundation of China(20072029)
Biography: Meng Ling-zhi(1947-), Professor, research direction: supramolecular and polymer chemistry.
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Ling-zhi, M., Gong-xiong, M., Yong-bing, H. et al. A new type of dibenzoyl tartaric acid selective electrode based on polymer membrane containing calix[4]arene ionophore. Wuhan Univ. J. of Nat. Sci. A 8, 113–116 (2003). https://doi.org/10.1007/BF02902078
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DOI: https://doi.org/10.1007/BF02902078